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Abstract: Cyanobacteria are regarded as very eco‐friendly microreactors for the production of various biomolecules such as polysaccharides by fixing not only carbon but also nitrogen in water. Cyanobacterial polysaccharides having various functional groups such as hydroxyls, carboxyls, sulfates, etc. have the ability to interact with metals or inorganics, to create bionanocomposites. Sacran, a supergiant cyanobacterial anionic polysaccharide extracted from the extracellular matrix of Aphanothece sacrum which is mass‐cultivated in freshwater, is mainly used to create functional bionanocomposites. Gel‐type bionanocomposites of sacran with various metal cations are formed and showed photoresponsive functions. Metal recovery is performed from the sacran bionanocomposite gels. Sacran chains are complexed with multi‐wall carbon nanotubes (MWCNT) to give viscose dispersion from which MWCNT bionanocomposites can be collected by electrophoresis. The MWCNT/sacran dispersion retains the capability of adsorbing various metal ions to form hardened hydrogel beads. Finally, natural inorganic sepiolite can be used for sacran bionanocomposites which show an efficient neodymium ion adsorption ability. Thus, cyanobacterial polysaccharides are useful for preparing eco‐friendly and functional bionanocomposites with various hard materials. [ABSTRACT FROM AUTHOR]

Uniaxial orientation is highly desirable for fabricating advanced soft materials. Liquid crystal (LC) polymer deposition was strategically manipulated at the air-LC interface, by controlling the drying temperature and initial concentration of aqueous solution of xanthan gum in a limited space. Interface-assisted orientation led to membrane-like depositions bridging the millimeter-scale gap between the substrates both, vertically and horizontally. The applicability of this approach lies in synchronization of the molecular orientation beyond their individual LC domains into the condensed state. Cross-polarized microscopy and SEM analysis correlated the orientation of the deposited polymer with the controlled mobility of xanthan gum LC domains at the evaporative interface. Subsequently, a phase diagram was prepared for the variety of oriented structures, depending upon the drying conditions. The deposited membrane behaved as an oriented hydrogel showing reversible anisotropic swelling/deswelling only along its thickness. [ABSTRACT FROM AUTHOR]