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Highlights • Mass fraction difference as the driving force for the mass transfer. • New variable to fit experimental data for absorption chillers. • Linear relation of cooling capacity to mass fraction difference. • Less deviation compared to characteristic temperature function. Abstract Absorption chillers are considered as heat transfer devices and hence most commonly modeled as heat transfer processes. The absorption of the refrigerant vapor though inherently involves mass transfer into the absorbent, which in comparison to the heat transfer usually is a slow transport process. Modeling absorption chillers, however, usually does not include this mass transfer process. This in fact neglects the dominant process in absorption chillers which is addressed in the present paper. [ABSTRACT FROM AUTHOR]

A comparison of absorption and desorption is conducted using a detailed model describing heat and mass transfer. First, the influences of various assumptions have been evaluated. Second, typical conditions for both absorption chillers and heat transformers have been defined. The performance of absorption and desorption processes have been analysed for a flow length of 0.1 m. In an absorption chiller, during desorption, the viscosity is lowered and the mass diffusivity is increased. These circumstances cause a 46% higher transfer rate as compared to absorption. Thus, the overall performance of the process is determined by the absorber component. In a heat transformer, during absorption at an elevated pressure and temperature level, the viscosity is lower and mass diffusivity is higher as compared to desorption. Therefore, the transfer rate of during absorption is 10% higher as compared to desorption. Hence, the desorber performance is somewhat more influential to the overall system performance. [ABSTRACT FROM AUTHOR]

Abstract: Since the late seventies of the 20th century, several analytical models for combined heat and mass transfer in laminar falling film absorption have been proposed. Nevertheless the analytical solutions obtained with the Fourier method for the coupled process are complex and for short flow length a certain instability occurs which have been explained with the inconsistency of the initial and boundary conditions. Therefore boundary layer models have been justified in order to solve the transfer problem for short flow length. Moreover a linear approximation of the phase equilibrium is required. The analytical solutions for heat and mass transfer presented in this paper are obtained by using the Laplace transform to solve the partial differential equations for an isothermal as well as impermeable wall. An originally unknown constant temperature and mass fraction boundary condition at the interface are set. The temperature and mass fraction profile across the film are obtained formally independently. In order to determine the yet unknown interface temperature and mass fraction the phase equilibrium and the interface energy balance are applied, using averaged gradients with regard to the streamwise coordinate. The interface temperature and mass fraction obtained with this procedure are interpreted and treated as mean values. From the known evolution of the mean interface temperature and mass fraction, the local values are derived by inverting the first mean value theorem for integration. The results show very good agreement to the established analytical solutions. The solving procedure does not depend on the input parameters such as the Lewis number for instance, which is needed in order to determine the eigenvalues within the Fourier method. Moreover arbitrary correlations for the phase equilibrium are applicable. The present solution is mathematically stable and offer explicit expressions in order to calculate the mean heat and mass fluxes directly. Therefore this solution is favourable to implement entire absorption process simulation, yet describing the coupled heat and mass transfer process comprehensively. [Copyright &y& Elsevier]

Abstract: This paper is the second paper out of two which present the development of a dynamic model for single-effect LiBr/water absorption chillers. The first part describes the model in detail with respect to the heat and mass balances as well as the dynamic terms. This second part presents a more detailed investigation of the model performance, including performance analysis, sensitivity checks and a comparison to experimental data. General model functionality is demonstrated. A sensitivity analysis gives results which agree very well to fundamental expectations: it shows that an increase in both external and internal thermal mass results in a slower response to the step change but also in smaller heat flow oscillations during the transient period. Also, the thermal mass has been found to influence the heat flow transients more significantly if allocated internally. The time shift in the solution cycle has been found to influence both the time to reach steady-state and the transients and oscillations of the heat flow. A smaller time shift leads to significantly faster response. A comparison with experimental data shows that the dynamic agreement between experiment and simulation is very good with dynamic temperature deviations between 10 and 25s. The total time to achieve a new steady-state in hot water temperature after a 10K input temperature step amounts to approximately 15min. Compared to this, the present dynamic deviations are in the magnitude of approximately 1–3%. [Copyright &y& Elsevier]

Abstract: An important drawback of solid sorption systems which are operated in batch mode against liquid sorption systems is the imperfect heat exchange between loaded and unloaded adsorbent, as compared to the almost perfect counter-flow solution heat exchanger. We will discuss a simple hardware solution for a significant improvement. We divide the batch reactors into several compartments, not with respect to the refrigerant side, but with respect to the heat transfer medium (heat exchanger loop). If these compartments have individual and arbitrary heat exchange possibilities with each other the efficiency of heat recovery can be improved from a co-flow characteristic to a cross-flow characteristic. We want to stress that this is different from a multi-bed or multistage arrangement. The method is explained, and an algorithm for deriving the exchange efficiency is given. Although this paper is only meant for outlining the basic mechanism, a proposition for realisation of the external hydronic circuit is given in addition. [Copyright &y& Elsevier]

This study presents an experimental investigation of the heat transfer occurring during reflux condensation of refrigerant R134a in an inclined micro-fin tube (0.008 m OD, 0.5 m length). The experiments were carried out at a system pressure of 0.74 MPa and at inclination angles of 30°, 38°, 45°, 60° and 90° from the horizontal. The experiments indicated that the inclination angle has a significant effect on heat transfer during reflux condensation. The maximum reflux heat transfer coefficient was found at 30° inclination angle. At this arrangement, the heat transfer increased by a factor of 2.45 compared to the vertical case. A comparison with previous studies suggests that the heat transfer in a micro-fin tube is 2.2 times better than that in a plain tube, and 1.34 times better than that in a plain rectangular channel both at 30° inclination. [ABSTRACT FROM AUTHOR]

Abstract: We present a model describing simultaneous heat and mass transfer of an absorbing or desorbing laminar liquid film flowing over a vertical isothermal plate. We start with a formulation which is comparable to established models by using simplifying assumptions such as homogeneous velocity and constant film thickness. In contrast to those, we allow for effects like change in properties and differential heat of solution within the bulk of the film. Additionally, enthalpy transport due to interdiffusion is accounted for. The impact of the considered effects are discussed and compared. The numerical solution is obtained by utilising a Newton–Raphson scheme to solve the finite difference formulation of the governing equations. Since the temperature gradients adjacent to wall and phase boundary are expected to be large, we discretise the equations on an irregular grid. The results of the model agree very well with established analytical models. It is found that the influence of released differential heat of solution within the bulk is relatively small. However, the impact on the temperature distribution is in the same order of magnitude as the one of a change in properties. Moreover, when comparing desorption with absorption under equivalent conditions, the mass transfer rate during absorption is higher than during desorption. [Copyright &y& Elsevier]

Abstract: Heat transfer during reflux condensation in a narrow tube (0.007m inner diameter, 0.5m length) and a rectangular channel (0.007m hydraulic diameter, 0.5m length) was investigated. The basic mechanism of this process, i.e. removing high boiling point components from a stream of a more volatile fluid or even from inert gases, is still not sufficiently understood. The study presents experimental results with the zeotropic mixture of R134a and R123 at a constant composition of the incoming vapour of 50mol%. The results show that both, gas side heat and mass transfer resistances and the resistances in the liquid film influence the condensation process. Channel inclination is less important in mixture condensation than in pure fluid condensation but not negligible, and increasing vapour mass flow enhances mixture condensation. Contrary to pure fluid results heat transfer in the rectangular channel with the same hydraulic diameter is much smaller than in the tube at the same vapour mass flow rate. [Copyright &y& Elsevier]

In earlier work, a novel open absorption cycle was proposed, capable of producing both cooling and dehumidification for air conditioning, utilizing low-grade heat. The system, referred to as DER (Dehumidifier-Evaporator-Regenerator), uses ambient air in conjunction with an absorbent solution; the air is dehumidified and then employed to produce chilled water in an evaporative cooler. Alternatively, a portion of the dehumidified air may be used directly for air conditioning purposes. The system thus has the potential to provide both cooling and dehumidification in variable ratios, as required by the load. Computer simulations and theoretical investigations were carried out to analyze and predict the performance of the system. The objective of the present study has been to construct a laboratory system to test the concept, identify problems and carry out preliminary design optimization. The characteristic performance of individual components, analyzed theoretically in the simulation, was studied experimentally. Measurements have provided much-needed realistic data about heat and mass transfer coefficients. The performance of the system has been studied under varying operating conditions. The paper describes the operation of the experimental system and presents the measured data and the resulting transfer coefficients. [ABSTRACT FROM AUTHOR]