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采用等转化率法研究了2， 4， 6-三（羟基苯甲基氨基）-均三嗪(MFP)与双酚A型环氧树脂(DGEBA)在等温和非等温条件下的固化反应行为，两种条件下MFP/DGEBA固化反应的表观活化能（Eα）均随转化率(α)增加呈先减后增的趋势（α= 0.25时取得最小值）.由于仲胺基和酚羟基对环氧基反应的不等活性，非等温固化反应时两种反应先后发生，形成Triazine-NCH2-CH(OH)-结构后，再形成ArO-CH2-CH(OH)-结构并产生交联，前后两阶段Eα分别为69.8、86.8 kJ • mol-1.对等温固化反应，由于起始反应温度高，仲胺基和酚羟基几乎同步与环氧基发生反应，两者的相互催化作用使反应前期Eα相对较低（59.1 kJ • mol-1），固化反应速度较快，引起体系粘度迅速增大，扩散控制反应提前，从而造成反应后期Eα（89.7 kJ • mol-1）相对较大.

合成了一种含氮固化剂2，4，6-三（羟基苯基亚甲基胺）-均三嗪(MFP)和两种结构不同的含磷环氧树脂(FD、ED), 经红外光谱、核磁共振和元素分析等表征，证实了其化学结构.用MFP固化FD和ED制得了新型无卤阻燃的环氧树脂.用DSC测定了固化物玻璃化转变温度（Tg)，用TGA表征了其热性能，UL-94垂直燃烧试验表征了其阻燃性能.结果表明，所得含磷氮的无卤阻燃环氧树脂具有较高的玻璃化转变温度，优良的热稳定性，初始分解温度高达300 ℃以上，在850 ℃下的残炭率达到了27%以上，阻燃性能均达到了 UL-94 V-0级.

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As an abundant, nontoxic and inexpensive one-carbon (C1) feedstock, carbon dioxide (CO2) has been used as the monomer for preparing a variety of polymers via copolymerization process, such as polycarbonates, poly(urethane)s and polyureas that are linear chain structure. Due to the limit in designing multi-functionalized comonomers, using CO2 to synthesize polymers with different architectures, such as hyperbranched polymers (HBPs), is rarely reported. Recently, Qin and Tang et al. have reported a successful synthesis of CO2-based hyperbranched poly(alkynoate)s (hb-PAs) via threecomponent polymerization of CO2, multi-functionalized alkyne and dihalides under mild conditions. The resultant polymer possessed two types of ethynyl groups with different reactivities towards the same types of amines, so it could undergo siteselective, multi-step functionalizations. Taking advantage of this facile and efficient site-selective functionalization strategy, they prepared a hyperbranched polyprodrug amphiphile with high drug loading content, an artificial light-harvesting system with high energy transfer efficiency and pure white light-emitting polymeric materials. This work provides a new method to convert CO2 into multifunctional HBPs that are platform polymers for diverse functionalizations. [ABSTRACT FROM AUTHOR]