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Start Over Author "Chiseko Sakuma" Publication Type Academic Journals
2 results on '"Chiseko Sakuma"'

1. Stereoselective iodine atom transfer [3 + 2] cycloaddition reaction with alkenes using unsymmetrical allylated active methine radicals

Author

Osamu Kitagawa, Shinsaku Miyaji, Chiseko Sakuma, and Takeo Taguchi

Subjects
Chemical reactions -- Analysis, Propane -- Research, Cyclic compounds -- Research, Radicals (Chemistry) -- Research, Olefins -- Research, Biological sciences, Chemistry
Abstract

An unsymmetrical allylated active methine radical species that provides functionalized cyclopentane derivatives, through iodine atom transfer [3+2] cycloaddition reaction with alkenes, is accomplished as a result of the treatment of 1-diethylphosphonyl- or 1-phenyl-sulfonyl-2-(iodomethyl)cyclopropane-1-carboxylate with Et3B.

Published
2004

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