20 results on '"Estrela, Teodoro"'
Search Results
2. Adapting participatory processes in temporary rivers management
- Author
-
Soria, Maria, Bonada, Núria, Ballester, Alba, Verkaik, Iraima, Jordà-Capdevila, Dídac, Solà, Carolina, Munné, Antoni, Jiménez-Argudo, Sara-María, Fortuño, Pau, Gallart, Francesc, Vinyoles, Dolors, Llorens, Pilar, Latron, Jérôme, Estrela, Teodoro, Prat, Narcís, and Cid, Núria
- Published
- 2021
- Full Text
- View/download PDF
3. Desalination in Spain and the Role of Solar Photovoltaic Energy.
- Author
-
Martínez-Medina, Miquel Àngel, Pérez-Martín, Miguel Ángel, and Estrela, Teodoro
- Subjects
SOLAR energy ,SALINE water conversion ,WATER shortages ,REVERSE osmosis in saline water conversion ,WATER supply ,ENERGY industries - Abstract
Water scarcity will increase in the world in the coming decades due to climate change, especially in areas that currently already have water scarcity, such as the Mediterranean area. In these areas, to guarantee water resources, systems' sustainability is necessary to improve demand management and the development of non-conventional resources, such as treated wastewater reuse or seawater desalination. These non-conventional resources are highly energy-consuming; so, reducing energy costs is a key element in developing their use in different sectors, including agriculture. Combining photovoltaic solar energy with seawater desalination by reverse osmosis will reduce the cost of producing water to below 0.36 EUR/m
3 ; so, this resource can be attractive for agriculture, as demonstrated in this work. The arrangement of bifacial solar modules in horizontal single-axis tracking systems increases the energy amount generated from the sun in one hour or more, improving the facility's efficiency and reducing the desalinated water cost. The greater distance between the solar module lines, with a ground coverage ratio (GCR) = 0.3, makes for a better environmental integration of the facility and allows the development of agrovoltaic strategies, such as native flora planting and pollinator colonization. [ABSTRACT FROM AUTHOR]- Published
- 2024
- Full Text
- View/download PDF
4. Introduction to section 3.
- Author
-
Estrela, Teodoro
- Subjects
- *
FLOOD risk , *SUSTAINABILITY , *TRANSBOUNDARY waters , *WATER management , *CLIMATE change adaptation , *EMERGENCY management , *GROUNDWATER management , *ENVIRONMENTAL protection - Abstract
This article discusses the impact of climate change on water resources in river basins and the need for sustainable water management. It addresses water-related risks such as droughts and floods and emphasizes the importance of risk management and integrated water resource management. The article also highlights the development of adaptation plans and the use of nature-based solutions. It discusses the risks of water scarcity and water quality, as well as the need for restoration policies in rivers. The article concludes by mentioning river basin management plans that focus on environmental protection and equitable allocation of water resources. Additionally, the document discusses various aspects of water management, including water allocation, environmental protection, investment programs, governance, stakeholder participation, and transboundary cooperation. It emphasizes the importance of well-designed water allocation regimes and river basin management plans in achieving economic, ecological, and socio-cultural value. The document also highlights the need for increased investment in the water sector, particularly in the face of climate change. It discusses the role of water governance in designing and implementing water policies and the importance of transboundary cooperation in sharing water resources. The document concludes by emphasizing the challenges and future perspectives of sustainable water management, including adaptation to climate change, increasing water security, and improving efficiency. [Extracted from the article]
- Published
- 2024
- Full Text
- View/download PDF
5. A review of water scarcity and drought indexes in water resources planning and management
- Author
-
Pedro-Monzonís, María, Solera, Abel, Ferrer, Javier, Estrela, Teodoro, and Paredes-Arquiola, Javier
- Published
- 2015
- Full Text
- View/download PDF
6. Water Accounts and Water Stress Indexes in the European Context of Water Planning: The Jucar River Basin
- Author
-
Pedro-Monzonís, María, Ferrer, Javier, Solera, Abel, Estrela, Teodoro, and Paredes-Arquiola, Javier
- Published
- 2014
- Full Text
- View/download PDF
7. Modeling Water Resources and River-Aquifer Interaction in the Júcar River Basin, Spain
- Author
-
Pérez-Martín, Miguel A., Estrela, Teodoro, Andreu, Joaquín, and Ferrer, Javier
- Published
- 2014
- Full Text
- View/download PDF
8. Management Alternatives of Aquifer Storage, Distribution, and Simulation in Conjunctive Use.
- Author
-
Sahuquillo, Andrés, Cassiraga, Eduardo, Gómez-Hernández, J. Jaime, Andreu, Joaquín, Pulido-Velazquez, Manuel, Pulido-Velazquez, David, Álvarez-Villa, Oscar D., and Estrela, Teodoro
- Subjects
AQUIFERS ,WATERLOGGING (Soils) ,WATER supply ,SOIL salinization ,WATER levels ,GROUNDWATER flow ,GROUNDWATER recharge ,SALTWATER encroachment - Abstract
Aquifers are ubiquitous, and their water is easy to obtain with low extraction costs. On many occasions, these characteristics lead to overexploitation due to important water level declines, reduction of river base flows, enhanced seawater intrusion, and wetland affection. The forecasted increase in water demands and global warming will impact the future availability of water resources. Conjunctive use of surface and subsurface waters can help in mitigating these impacts. There are two main conjunctive use strategies: artificial recharge (AR) and alternate conjunctive use (ACU). AR stores waters that are not to be used directly in aquifers. ACU utilizes groundwater in dry periods, while surface waters are preferred in wet ones; this allows the increase of water supply with lower dam storage, economic gains, and environmental advantages. Efficient conjunctive use can prevent soil salinization and waterlogging problems in semiarid countries due to excessive recharge from irrigation return flows or other origins. Groundwater is a neglected and generally misused resource to maintain environmental conditions. When considering the solution to a water resources problem, groundwater should always be part of the design as an alternative or a complementary resource. Aquifers have large inertia, and changes in their volumes are only noticeable after years of observations. Unfortunately, groundwater observation networks are much poorer than surface ones, something that should be changed if groundwater is to come to the rescue in these times of climate change. Human and material resources should be made available to monitor, control, analyze, and forecast groundwater. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
9. Drought Management Plans in the European Union. The Case of Spain
- Author
-
Estrela, Teodoro and Vargas, Elisa
- Published
- 2012
- Full Text
- View/download PDF
10. Development of a hybrid model to interpolate monthly precipitation maps incorporating the orographic influence.
- Author
-
Álvarez‐Rodríguez, Javier, Llasat, María‐Carmen, and Estrela, Teodoro
- Subjects
RAINFALL ,METEOROLOGICAL precipitation ,PRECIPITATION anomalies ,KRIGING ,NATURAL resources ,INFORMATION resources ,REGRESSION analysis - Abstract
This paper proposes an interpolation model for monthly rainfall in large areas of complex orography. It has been implemented in the Iberian Peninsula (continental territories of Spain and Portugal), Balearic and Canary Islands covering a territory of almost 600.000 km2. To do this a data set that comprises a total number of 11,822 monthly precipitation series has been created (11,042 provided by the Spanish Meteorological Agency and 780 provided by the National Water Resources Information System of the Portuguese Water Institute). The data set covers the period from October 1940 until September 2005. The interpolation model has been based on the assumption of two different components on monthly precipitation. The first component reflects local and seasonal characteristics and 24 different mean monthly precipitation maps (12) and SDs maps (12) compose it. It considers the varying influence of physiographic variables such as altitude and orientation. The second precipitation component reflects the synoptic pattern that dominated each month of the series and it is composed by series of anomalies of monthly precipitation (780). Anomalies have been interpolated by means of ordinary kriging once local spatial continuity was assumed. Gridded maps of each variable have been developed at 200 m resolution following a hybrid methodology that implements two different interpolation techniques. The first technique applies a regression analysis to derive maps depending on altitude and orientation; the second one is a weighting technique to consider the non‐linearity of the precipitation/altitude dependence. Cross validation has been applied to estimate the goodness of both techniques. Results show an average annual precipitation of 655 mm/year. Although this figure is only 4% less than the estimate of MAGRAMA (2004), regional and local differences are highlighted when the spatial distribution is considered. The model constitutes a comprehensive implementation considering the availability of historical records and the need of avoiding slow calculations in large territories. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
11. Measures required to reach the nitrate objectives in groundwater based on a long-term nitrate model for large river basins (Júcar, Spain).
- Author
-
Pérez-Martín, Miguel A., Estrela, Teodoro, and del-Amo, Patricia
- Subjects
- *
GROUNDWATER pollution , *NITRATES , *WATERSHEDS , *GROUNDWATER recharge , *BODIES of water - Abstract
Nitrate pollution, primarily in groundwater (GW), has been one of major water pollution problems in Europe over the last 30 years. Specially, Mediterranean areas (semi-arid zones) are more vulnerable to nitrate pollution, as in these areas a small excess of nitrogen produce higher nitrate concentrations than in more humid countries because the aquifer recharge is minor. A large number of GW bodies in the Júcar River Basin District (RBD) (43.000 km 2 ), located in Spain, has nitrate concentrations above 50 mg/L. The Water Framework Directive (WFD) sets out the goal of good status for the water bodies of the European Union, which also implies compliance with the Nitrates Directive. The River Basin Authorities (RBAs) must define the measures needed to reach the environmental objectives in the River Basin Management Plans (RBMPs), considering the long time-lag of aquifers is decisive in the measures effectiveness. By means of nitrogen cycle simulation in the river basin district and with the help of the monthly distributed PATRICAL model, the Júcar RBA has defined the measures to be applied and the exemptions to reach the objectives in GW in relation to nitrate pollution. Both, model and methodology are useful for other river basins to define measures. The total nitrogen inputs in the Júcar RBD amounts to 180,000 tN/year, which represents a nitrogen surplus of 80,000 tN/year and a pressure of 58.5 kgN/year/ha-crop. Around 3/4 of GW bodies have currently the good status while the remaining of GW bodies could reach the good status during following hydrological planning cycles through the implementation of modernized irrigation systems that include fertigation -the use of fertilizers in the water for irrigation. The implementation of this scenario involves increasing efficiency in fertilizer application, in order to reduce nitrogen losses from slightly under a half to < 1/3. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
12. The EU WFD and the river basin management plans in Spain.
- Author
-
Estrela, Teodoro
- Subjects
- *
DELEGATED legislation , *WATER management , *WATERSHED management , *ENVIRONMENTAL protection - Abstract
The European water framework directive (WFD) 2000/60/EC, establishes a framework for community action in the field of water policy, introducing a new perspective from a modern view of water policy to all Member States of the European Union, with important consequences for future water management. This paper reviews the status of the implementation of the EU water framework directive in Spain focusing on river basin management plans, which are an essential tool established by the EU water framework directive to reach the environmental objectives in the European Union water bodies. Spain has a long tradition in water resources planning and current plans, the main aim of which is to allocate water resources to water uses. These plans are being revised and extended to include water protection requirements derived from the EU water framework directive. Recently, specific and related plans, such as drought management plans, have been approved. [ABSTRACT FROM AUTHOR]
- Published
- 2011
- Full Text
- View/download PDF
13. A Proposal to Classify and Assess Ecological Status in Mediterranean Temporary Rivers: Research Insights to Solve Management Needs.
- Author
-
Munné, Antoni, Bonada, Núria, Cid, Núria, Gallart, Francesc, Solà, Carolina, Bardina, Mònica, Rovira, Albert, Sierra, Clara, Soria, Maria, Fortuño, Pau, Llorens, Pilar, Latron, Jérôme, Estrela, Teodoro, Fidalgo, Arancha, Serrano, Inmaculada, Jiménez, Sara, Vega, Rosa, Prat, Narcís, Feio, Maria João, and Neto, Joao M.
- Subjects
WATERSHEDS ,WATER use ,EPHEMERAL streams ,RIVER conservation ,BIOLOGICAL monitoring ,DIATOMS - Abstract
The biomonitoring methods implemented by water authorities are mostly developed for perennial rivers, and do not apply to temporary rivers (TRs). We propose a new classification for TRs to better assess their ecological status. It arises from the LIFE+ TRivers project, which was conducted in the Catalan and the Júcar Mediterranean river basin districts (RBD). The European Water Framework Directive (WFD) provided two systems to set river types (systems A or B from Annex II), which have been officially used by water authorities across Europe to set "national river types" (NRTs). However, essential hydrological variables for TRs are largely omitted. NRTs established according to the WFD were compared with TR categories obtained by using a rainfall-runoff model, "natural flows prescribed regimes" (NFPRs), and with "aquatic phases regimes" (APRs) calculated by using TREHS software. The biological quality indices currently used in Spain, based on macroinvertebrates and diatoms (IBMWP, IMMI-T, and IPS), were compared with a "general degradation" gradient in order to analyze the two TR river classification procedures (NFPR and APR). The results showed that NRTs did not properly classify TRs, and that the APR classification identified ecologically meaningful categories, especially those related to stagnant phases. Four "management temporary river categories" based on APRs are proposed to be used for water managers to properly assess the ecological status of TRs. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
14. Improvement of the drought indicators system in the Júcar River Basin, Spain.
- Author
-
Ortega-Gómez, Tatiana, Pérez-Martín, Miguel A., and Estrela, Teodoro
- Subjects
- *
DROUGHTS , *DROUGHT forecasting , *DROUGHT management , *WATER management ,ENVIRONMENTAL aspects - Abstract
Droughts are one of the gravest natural threats currently existing in the world and their occurrence and intensity might be exacerbated in the coming years due to climate change. The severe impacts that droughts cause to inland water resources and to the associated socio-economic activities justify the continuous monitoring of the drought. The case study presented shows a practical application of a distributed drought monitoring system implemented in a real river basin district, the Júcar River Basin District (43,000 km 2 ), where drought periods of marked intensity have occurred historically and the climate ranges from humid in the north to semiarid in the south. Five drought indices have been applied: Standardised Precipitation Index (SPI) for meteorological drought; Palmer Drought Severity Index (PDSI) and a new soil moisture index (HI), for edaphic drought; Normalised Difference Vegetation Index (NDVI) for the vegetation activity; and Spanish Status Index (SI), for the operational drought. All indices are standardised to compare them. The relationship between the standardised operational drought index SI and the long-term meteorological indices, SPI-12 or SPI-24, show that in a medium size basin the concept of “prolonged drought” required by the European Commission under the Water Framework Directive could be defined by the use of accumulated precipitation indices. The number of months to be accumulated depends on the size of the basin and the water management system properties. In large basins, such as the Júcar river basin (22,000 km 2 ), there are significant deviations due to the spatial distribution of the drought. The use of a unique aggregated indicator could hide a significant drought in a specific area, or on the other hand show a non-real drought. Evolution of drought indices for each water management system must be accompanied by spatially distributed drought maps to better understand the drought status and its evolution. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
- View/download PDF
15. TREHS: An open-access software tool for investigating and evaluating temporary river regimes as a first step for their ecological status assessment.
- Author
-
Gallart, Francesc, Cid, Núria, Latron, Jérôme, Llorens, Pilar, Bonada, Núria, Jeuffroy, Justin, Jiménez-Argudo, Sara-María, Vega, Rosa-María, Solà, Carolina, Soria, Maria, Bardina, Mònica, Hernández-Casahuga, Antoni-Josep, Fidalgo, Aránzazu, Estrela, Teodoro, Munné, Antoni, and Prat, Narcís
- Subjects
- *
HYDROGRAPHY , *HYDROLOGY , *AQUATIC sciences , *BIOTIC communities , *ECOLOGY - Abstract
When the regime of a river is not perennial, there are four main difficulties with the use of hydrographs for assessing hydrological alteration: i) the main hydrological features relevant for biological communities are not quantitative (discharges) but qualitative (phases such as flowing water, stagnant pools or lack of surface water), ii) stream flow records do not inform on the temporal occurrence of stagnant pools, iii) as most of the temporary streams are ungauged, their regime has to be evaluated by alternative methods such as remote sensing or citizen science, and iv) the biological quality assessment of the ecological status of a temporary stream must follow a sampling schedule and references adapted to the flow- pool-dry regime. To overcome these challenges within an operational approach, the freely available software tool TREHS has been developed within the EU LIFE TRIVERS project. This software permits the input of information from flow simulations obtained with any rainfall-runoff model (to set an unimpacted reference stream regime) and compares this with the information obtained from flow gauging records (if available) and interviews with local people, as well as instantaneous observations by individuals and interpretation of ground-level or aerial photographs. Up to six metrics defining the permanence of water flow, the presence of stagnant pools and their temporal patterns of occurrence are used to determine natural and observed river regimes and to assess the degree of hydrological alteration. A new regime classification specifically designed for temporary rivers was developed using the metrics that measure the relative permanence of the three main phases: flow, disconnected pools and dry stream bed. Finally, the software characterizes the differences between the natural and actual regimes, diagnoses the hydrological status (degree of hydrological alteration), assesses the significance and robustness of the diagnosis and recommends the best periods for biological quality samplings. [ABSTRACT FROM AUTHOR]
- Published
- 2017
- Full Text
- View/download PDF
16. Water accounting for stressed river basins based on water resources management models.
- Author
-
Pedro-Monzonís, María, Solera, Abel, Ferrer, Javier, Andreu, Joaquín, and Estrela, Teodoro
- Subjects
- *
WATERSHED management , *ENVIRONMENTAL economics , *HYDROLOGY , *DECISION support systems , *SALINE water conversion - Abstract
Water planning and the Integrated Water Resources Management (IWRM) represent the best way to help decision makers to identify and choose the most adequate alternatives among other possible ones. The System of Environmental-Economic Accounting for Water (SEEA-W) is displayed as a tool for the building of water balances in a river basin, providing a standard approach to achieve comparability of the results between different territories. The target of this paper is to present the building up of a tool that enables the combined use of hydrological models and water resources models to fill in the SEEA-W tables. At every step of the modelling chain, we are capable to build the asset accounts and the physical water supply and use tables according to SEEA-W approach along with an estimation of the water services costs. The case study is the Jucar River Basin District (RBD), located in the eastern part of the Iberian Peninsula in Spain which as in other many Mediterranean basins is currently water-stressed. To guide this work we have used PATRICAL model in combination with AQUATOOL Decision Support System (DSS). The results indicate that for the average year the total use of water in the district amounts to 15,143 hm 3 /year, being the Total Water Renewable Water Resources 3909 hm 3 /year. On the other hand, the water service costs in Jucar RBD amounts to 1634 million € per year at constant 2012 prices. It is noteworthy that 9% of these costs correspond to non-conventional resources, such as desalinated water, reused water and water transferred from other regions. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
17. Groundwater intensive use and mining in south-eastern peninsular Spain: Hydrogeological, economic and social aspects.
- Author
-
Custodio, Emilio, Andreu-Rodes, José Miguel, Aragón, Ramón, Estrela, Teodoro, Ferrer, Javier, García-Aróstegui, José Luis, Manzano, Marisol, Rodríguez-Hernández, Luis, Sahuquillo, Andrés, and del Villar, Alberto
- Subjects
- *
GROUNDWATER , *ABSTRACTION reactions , *HYDROGEOLOGICAL modeling , *WATER use , *GROUNDWATER monitoring - Abstract
Intensive groundwater development is a common circumstance in semiarid and arid areas. Often abstraction exceeds recharge, thus continuously depleting reserves. There is groundwater mining when the recovery of aquifer reserves needs more than 50 years. The MASE project has been carried out to compile what is known about Spain and specifically about the south-eastern Iberian Peninsula and the Canary Islands. The objective was the synthetic analysis of available data on the hydrological, economic, managerial, social, and ethical aspects of groundwater mining. Since the mid-20th century, intensive use of groundwater in south-eastern Spain allowed extending and securing the areas with traditional surface water irrigation of cash crops and their extension to former dry lands, taking advantage of good soils and climate. This fostered a huge economic and social development. Intensive agriculture is a main activity, although tourism plays currently an increasing economic role in the coasts. Many aquifers are relatively high yielding small carbonate units where the total groundwater level drawdown may currently exceed 300 m. Groundwater storage depletion is estimated about 15 km 3 . This volume is close to the total contribution of the Tagus-Segura water transfer, but without large investments paid for with public funds. Seawater desalination complements urban supply and part of cash crop cultivation. Reclaimed urban waste water is used for irrigation. Groundwater mining produces benefits but associated to sometimes serious economic, administrative, legal and environmental problems. The use of an exhaustible vital resource raises ethical concerns. It cannot continue under the current legal conditions. A progressive change of water use paradigm is the way out, but this is not in the mind of most water managers and politicians. The positive and negative results observed in south-eastern Spain may help to analyse other areas under similar hydrogeological conditions in a less advanced stage of water use evolution. [ABSTRACT FROM AUTHOR]
- Published
- 2016
- Full Text
- View/download PDF
18. Key issues for determining the exploitable water resources in a Mediterranean river basin.
- Author
-
Pedro-Monzonís, María, Ferrer, Javier, Solera, Abel, Estrela, Teodoro, and Paredes-Arquiola, Javier
- Subjects
- *
WATER management , *WATER supply , *SALINE water conversion , *WATERSHEDS - Abstract
One of the major difficulties in water planning is to determine the water availability in a water resource system in order to distribute water sustainably. In this paper, we analyze the key issues for determining the exploitable water resources as an indicator of water availability in a Mediterranean river basin. Historically, these territories are characterized by heavily regulated water resources and the extensive use of unconventional resources (desalination and wastewater reuse); hence, emulating the hydrological cycle is not enough. This analysis considers the Jucar River Basin as a case study. We have analyzed the different possible combinations between the streamflow time series, the length of the simulation period and the reliability criteria. As expected, the results show a wide dispersion, proving the great influence of the reliability criteria used for the quantification and localization of the exploitable water resources in the system. Therefore, it is considered risky to provide a single value to represent the water availability in the Jucar water resource system. In this sense, it is necessary that policymakers and stakeholders make a decision about the methodology used to determine the exploitable water resources in a river basin. [ABSTRACT FROM AUTHOR]
- Published
- 2015
- Full Text
- View/download PDF
19. GIS-based models for water quantity and quality assessment in the Júcar River Basin, Spain, including climate change effects
- Author
-
Ferrer, Javier, Pérez-Martín, Miguel A., Jiménez, Sara, Estrela, Teodoro, and Andreu, Joaquín
- Subjects
- *
GEOGRAPHIC information systems , *WATER quality , *CLIMATE change , *WATERSHEDS , *WATER supply , *QUANTITATIVE research , *BODIES of water - Abstract
Abstract: This paper describes two different GIS models – one stationary (GeoImpress) and the other non-stationary (Patrical) – that assess water quantity and quality in the Júcar River Basin District, a large river basin district (43,000km2) located in Spain. It aims to analyze the status of surface water (SW) and groundwater (GW) bodies in relation to the European Water Framework Directive (WFD) and to support measures to achieve the WFD objectives. The non-stationary model is used for quantitative analysis of water resources, including long-term water resource assessment; estimation of available GW resources; and evaluation of climate change impact on water resources. The main results obtained are the following: recent water resources have been reduced by approximately 18% compared to the reference period 1961–1990; the GW environmental volume required to accomplish the WFD objectives is approximately 30% of the GW annual resources; and the climate change impact on water resources for the short-term (2010–2040), based on a dynamic downscaling A1B scenario, implies a reduction in water resources by approximately 19% compared to 1990–2000 and a reduction of approximately 40–50% for the long-term (2070–2100), based on dynamic downscaling A2 and B2 scenarios. The model also assesses the impact of various fertilizer application scenarios on the status of future GW quality (nitrate) and if these future statuses will meet the WFD requirements. The stationary model generates data on the actual and future chemical status of SW bodies in the river basin according to the modeled scenarios and reflects the implementation of different types of measures to accomplish the Urban Waste Water Treatment Directive and the WFD. Finally, the selection and prioritization of additional measures to accomplish the WFD are based on cost-effectiveness analysis. [Copyright &y& Elsevier]
- Published
- 2012
- Full Text
- View/download PDF
20. Investigation of pesticides and their transformation products in the Júcar River Hydrographical Basin (Spain) by wide-scope high-resolution mass spectrometry screening.
- Author
-
Fonseca, Eddie, Renau-Pruñonosa, Arianna, Ibáñez, María, Gracia-Lor, Emma, Estrela, Teodoro, Jiménez, Sara, Pérez-Martín, Miguel Ángel, González, Francisco, Hernández, Félix, and Morell, Ignacio
- Subjects
- *
TIME-of-flight mass spectrometry , *MASS spectrometry , *PESTICIDES , *WATERSHEDS , *BODIES of water , *WATER , *ATRAZINE , *HERBICIDES - Abstract
The Water Framework Directive 2000/60/EC implemented by the European Union established as the main objectives to achieve a "good ecological and chemical status" of the surface water and a "good quantitative and chemical status" of groundwater bodies. One of the major pressures affecting water bodies comes from the use of pesticides and their potential presence in the water ecosystems. For this purpose, the reliable determination of pesticides and their transformation products (TPs) in natural waters (both surface and groundwater) is required. The high number of compounds potentially reaching the aquatic environment makes extraordinary difficult, if not impossible, to investigate all these compounds even using the most powerful analytical techniques. Among these, liquid chromatography coupled to high-resolution mass spectrometry is emphasized due to its strong potential for detection and identification of many organic contaminants thanks to the accurate-mass full spectrum acquisition data. This work focuses on wide-scope screening of many pesticides and their TPs in surface water and groundwater samples, collected between March and May 2017, in the Júcar River Hydrographical Basin, Spain. For this purpose, a home-made database containing more than 500 pesticides and TPs was employed. Analyses performed by liquid chromatography coupled to quadrupole-time of flight mass spectrometry (LC-QTOF MS) allowed the identification of up to 27 pesticides and 6 TPs. The most detected compounds in groundwater were the herbicides atrazine, simazine, terbuthylazine, and their TPs (atrazine-desethyl, terbumeton-desethyl and terbuthylazine-desethyl). Regarding surface water, the fungicides carbendazim, thiabendazole and imazalil, the herbicide terbutryn and the TP terbumeton-desethyl were also detected. These results illustrate the wide use of these compounds (in the present or in the recent past) in the area under study and the vulnerability of the water bodies, and are in accordance with previous findings in other water bodies of the different Spanish Hydrographic systems. Image 1 • High resolution mass spectrometry wide-scope screening of pesticides in water. • 27 pesticides and 6 transformation products were found in water samples. • Some compounds not included in routine target quantitative methods were identified. • Screening methodology was validated for 20 compounds commonly found in water. • Triazines and transformation products were the most frequently identified. [ABSTRACT FROM AUTHOR]
- Published
- 2019
- Full Text
- View/download PDF
Catalog
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.