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Water samples from Xikuangshan (China), the world largest antimony (Sb) mine with a Sb mining and smelting history of more than 200 years, were analyzed. These water samples ranged from stream water in the vicinity of the mining and smelting area that received seepage from ore residues to the underground mine-pit drainage. The concentrations of total Sb, Sb (III) and Sb (V) of the samples were determined by HPLC-ICP-MS. In addition, water pH and concentrations of major cations and anions were analyzed. All 18 samples demonstrated total Sb concentrations with ppm levels from 0.33 ppm to 11.4 ppm, which is two to three orders of magnitude higher compared to the typical concentration of dissolved Sb in unpolluted rivers (less than 1 ppb). This is probably the first time that such high Sb contents have been documented with complete environmental information. Distribution of total Sb and Sb species was investigated, taking into account the respective local environment (in the mining area or close to the smelter, etc.). Sb (V) was the predominant valence in all 18 samples. Only trace levels of Sb (III) were detected in 4 of the 18 samples. Geochemical speciation modeling showed the dominant species was Sb(OH). It is also probably the first time that such high Sb contents have been documented in the natural environment with Sb speciation distribution information. Several potential oxidation pathways are also discussed that might have facilitated the oxidation of Sb (III) in the natural environment. Signs of intoxication were observed among local mine workers with extensive exposure to different forms of Sb for a long period of time. [ABSTRACT FROM AUTHOR]

In the absence of detailed broad-scale studies, both spatially and temporally, the overall status (disturbed, recovering, or in decline) of many of the reefs that make up the Great Barrier Reef remains uncertain. Moreover, of the numerous and varied threats, their relative role in impacting individual reefs is generally unclear. Here, we adopt a novel approach to reliably reconstruct historical disturbance events at Rib and Davies Reefs, two mid-shelf reefs, using uranium-thorium (U-Th) dating of dead corals. Corrected 230Th ages obtained from dead Acropora spp. bracket time periods of lowest coral cover observed during independent ecological surveys in the late 1980s and 2000s at 1988.2 ± 1.3 and 2003.9 ± 6.2 CE, shortly after the arrival of crown-of-thorns starfish (CoTS) at Rib Reef in 1983-1985 and 2000-2002, respectively. At Davies Reef, 230Th ages dated to 1999.2 ± 1.2 CE when coral cover was halved as a result of Cyclone Tessi and an "unknown" disturbance in 2000-2001. Prior to modern surveys, there is remarkable overlap in 230Th ages between reefs, with repeated peaks in the age distribution having a return period of ~10-15 years, akin to the periodicity of modern CoTS outbreaks. Our findings suggest that U-Th dating of dead corals can provide a robust foundation for understanding disturbance history and show promise in contributing to the effective monitoring of coral communities by providing a reliable benchmark with which to assess recovery. [ABSTRACT FROM AUTHOR]