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In mobile communication, the most exploratory technology of fifth generation is massive multiple input multiple output (MIMO). The minimum mean square error and zero forcing based linear detectors are used in multiuser detection for MIMO single-carrier frequency division multiple access (SCFDMA). When the received signal is detected and regularization sequence is joined in the equalization of spectral null amplification, these schemes experience an error performance and the signal detection assesses an inversion of a matrix computation that grows into complexity. Ordered successive interference cancelation (OSIC) detection is considered for MIMO SC-FDMA, which uses a posteriori information to eradicate these problems in a realistic environment. To cancel the interference, sorting is preferred based on signal-to-noise ratio and log-likelihood ratio. The distinctiveness of the methodology is to predict the symbol with the lowest error probability. The proposed work is compared with the existing methods, and simulation results prove that the defined algorithm outperforms conventional detection methods and accomplishes better performance with lower complication.

Microplastics are widespread in coastal and marine environments, and sediments serve as a sink for microplastics. In this study, four sediment cores were collected from the Kuala Gula Mangrove area. The abundance of microplastics in mangrove sediments ranged from 25–130 items/kg dry weight. The highest abundance of microplastic was observed at the KG04 site near the mouth of the river. The number of microplastics by sampling site was significantly different (p < 0.01), with station KG04 having the highest fiber content. The dominant color of microplastics was blue, and the main shape was fiber. Rayon, cotton, Polyethylene terephthalate (PET), and azlon were observed from FT-IR, indicating that the potential sources of microplastic and fiber could come from household laundry wastewater. Microplastics tended to accumulate in deeper depths at KG01 (p < 0.01), whereas other stations showed no significant difference (p > 0.05). However, this study provides evidence that mangroves can be a trap for microplastics and can be used as baseline data for future studies. [ABSTRACT FROM AUTHOR]

In this study, we objectively focus on the relationship between the number of coronavirus (COVID-19) cases and key climate variables. We found that the risk of COVID-19 was approximately doubled during warm summer months when the aerosol molecules are likely stimulated by temperature and rainfall. Given that India is currently emerging as the new epicenter for the third and fourth outbreaks of COVID-19, we selected four key hotspot states-Maharashtra, Andhra Pradesh, Kerala, and Tamil Nadu - to closely look into the impact of climate variables on the spread of COVID-19 infected cases during 2020 and 2021. We found that COVID-19 is most active in temperature between 27°C and 32°C, while it is active in monthly average rainfall between 250 mm and 350 mm. This study further confirms that, although temperature and rainfall are not the initial triggers of COVID-19, both variables seem to play significant roles in spreading COVID-19 in India, especially during the summer season of 2020 and 2021, when the Indian summer monsoon was stronger in these four states. [ABSTRACT FROM AUTHOR]

This research synthesises two evaluations of a local level climate change adaptation and planning process in the southernmost coastal region, Kanyakumari, India which was supported through community-based appraisals. First, understanding the public perception of climate change factors is crucial in generating support for climate change response. Second, generating enough grass-root level support from the local population to assess the long-term climate change impacts on decision-making to design the adaptation strategies for sea-level rise. These two results highlight the level of understanding and awareness of climate change's impact by the local population in the coastal region of Kanyakumari. A well-designed questionnaire with structured interviews, to collect data on local knowledge and local perception of climate change and sea-level rise from 100 respondents was distributed each in 44 coastal villages in the study area. The finding showed that 20.7% of the local population have knowledge of climate change and its impacts and 18.4% of the population agreed that the impact of sea-level rise is experienced in the coastal region. This study is to provide insight into the communities' knowledge of the adaptive capacity of the local population to cope with climate change towards the treaty of sea-level rise. [ABSTRACT FROM AUTHOR]

Mangroves are typically found in tropical coastal areas, and these ecosystems face deterioration and loss due to threats from climate and human factors. In this study, sediment cores were collected from human-planted mangroves in sub-tropical Ximen Island, China, and were determined for sedimentary phosphorus (P) species. The objective was to investigate the ability of mangroves planted in a zone bordering their temperature limit to preserve and regulate P. Our results showed that bioavailable P (BAP), which includes exchangeable-P (Ex-P), iron-bound P (Fe-P), and organic P (OP), accounted for approximately 64% of total P (TP). Apatite P (Ca-P), which accounted for 24% of TP, most likely originated from aquaculture activities surrounding the island. The vertical distribution of sedimentary P species along the sediment cores showed a rather constant trend along the salt marsh stand but considerable fluctuations for the mangroves and bare mudflat. These results indicate that mangroves accumulated P when there was a high P discharge event, and that this P was eventually released during organic matter decomposition and contributed to Ca-P formation. Nevertheless, old and young mangroves accumulated higher sedimentary P species, OP, and BAP compared to the salt marsh stand and bare mudflat areas. This study showed the potential of mangroves planted outside their suitable climate zone to preserve and regulate P. [ABSTRACT FROM AUTHOR]

Mangroves are areas that connect the land and sea, and are important to the ecosystem. They are important places for food sources and the habitat of aquatic fauna in the tidal areas. However, the existence of plastic debris poses a risk to the aquatic environment. This study aimed to investigate the accumulation of microplastics (MPs) in sediment cores from two mangrove areas. The first mangrove area is in the outer section of the Songkhla lagoon (SK), while the second is in the coastal area of Pattani province (PN). Sediment core sampling was performed from SK = 8 stations and PN = 5 stations. Surface enrichment of MP was observed, especially in sediments of 0–4 cm. MPs were found throughout the depth in both areas, while fewer MPs were found in deeper sediment core layers (p < 0.05) at some stations inside the mangrove zone. Simple linear regression of the observed MPs and distance in the horizontal were found to be significant at SK within the mangrove zone with r2 = 0.79 (p < 0.05). MP fibers were the most commonly found MP type in both areas and were less than 1 mm. Blue and black MPs were the most abundant colors found in both areas. The six polymer types reported in this study comprised polyethylene, rayon, rubber, styrene, Poly (vinyl acetate), and paint. The findings of the present study suggest that long-term monitoring of marine debris along coastlines is necessary to help improve national policies and measures related to marine plastic debris. [ABSTRACT FROM AUTHOR]

Hyperpycnal flows are important agents for transporting detrital sediments from rivers to oceans. Previous studies often assumed that the deposits of flood‐controlled delta fronts would be dominated by graded sand with common hummocky cross‐stratification. This study documents, for the first time, hybrid event beds and plumite deposits inside the succession of a modern delta front. This delta in the Taiwan Strait is fed by the Choshui River, which is considered a highly efficient sediment transport system with individual floods with extremely high suspended sediment concentrations. The deltaic event beds recorded in the core were interpreted as hyperpycnal flow‐generated hybrid event beds and turbidites triggered by hypopycnal flows. Accelerator Mass Spectrometry 14C dating, grain‐size analysis and measurements of stable isotopic composition of organic matter were conducted to delineate the depositional process of the recognized beds. The internal subdivisions of the hybrid event beds were differentiated mainly based on sedimentary textures, including cohesive mud content, sand content and sorting. The disorganized portion (division H3) appears internally chaotic and contains large rafted substrate clasts but also displays an upward increase in dispersed cohesive mud from 35% (division H3a) to 50% (division H3b). In contrast, massive H1 divisions are characterized by much lower cohesive mud of ca 8%. The vertical arrangement between depositional facies allows the discrimination of three hybrid event bed types. The stable carbon isotopic composition of the organic matter reveals that the cohesive mud in each division of the hybrid event beds was sourced from marine substrate, rather than supplied by the original hyperpycnal flows. Therefore, the hybrid event beds are generated by energetic hyperpycnal flows, which can delaminate the muddy sea‐floor and incorporate large quantities of substrate fragments. The bulking of erosional hyperpycnal turbulent flow forces flow transformation and generates a more cohesive flow with a turbulent, dense head and trailing bipartite debris flow. The occurrence of hybrid event beds in modern shallow delta front settings is also an important novelty, implying a high density of hyperpycnal flows at the mouth of sediment‐laden rivers as well as the crucial impact of substrate entrainment on the development of hybrid event beds. [ABSTRACT FROM AUTHOR]

Tropical rivers deliver ∼60% of particulate organic carbon to the world ocean. However, compositions and loadings of sedimentary organic matter (OM) from tropical small mountainous rivers are largely unknown. Here, we provide an initial constrain on sources of sedimentary OM from 28 fluvial systems across Luzon in the Philippines by measuring total organic carbon (TOC), total nitrogen (TN), stable carbon isotope (δ13C) and radiocarbon activity of TOC (expressed as fraction modern—Fm), as well as grain size and mineral surface area (SA) of sediments. Results indicate that sediments in Luzon rivers contain both contemporary and 14C‐depleted OM (Fm: 0.71–1.06, mean 0.97 ± 0.07) with a wide range of δ13C values (−28.3‰ to −17.7‰, −24.9 ± 2.2‰). This is attributed to the OM sources originated from modern surface soil and 14C‐depleted subsoil and deep soil vegetated by C3 and C4 plants, with mean fraction of C3 plant at 80% ± 11%. Minor input from bedrock may also contribute to the 14C‐depleted OM in sediments, accounting for 6% ± 6%. Sediments in most rivers are featured by low OC loadings (OC/SA ratio < 0.4 mg C m−2), owing either to a less OM input or intensive OM degradation. The estimated yields of particulate OC from Luzon vary between 3.2 and 3.7 t km−2 yr−1, which is higher than most tropical large rivers. Key Points: C3 and C4 plants underlain by modern surface soils represent the main contribution to organic matter (OM) found in Luzon river sedimentsDegraded OM in subsoils and deep soils or bedrock contribute to radiocarbon (14C)‐depleted OM in Luzon riversThe yields of particulate organic carbon from tropical small mountainous rivers on Luzon are much higher than that of other tropical large river systems [ABSTRACT FROM AUTHOR]

The deep-ocean carbon cycle, especially carbon sequestration and outgassing, is one of the mechanisms to explain variations in atmospheric CO2 concentrations on millennial and orbital timescales. However, the potential role of subtropical North Pacific subsurface waters in modulating atmospheric CO2 levels on millennial timescales is poorly constrained. An increase in the respired CO2 concentration in the glacial deep-ocean due to biological pump generally corresponds to deoxygenation in the ocean interior. This link thus offers a chance to study oceanic ventilation and coeval export productivity based on redox-controlled sedimentary geochemical parameters. Here, we investigate a suite of geochemical proxies in a sediment core from the Okinawa Trough to understand sedimentary oxygenation variations in the subtropical North Pacific over the last 50 000 years (50 ka). Our results suggest that enhanced mid-depth western subtropical North Pacific (WSTNP) sedimentary oxygenation occurred during cold intervals and after 8.5 ka, while oxygenation decreased during the Bölling-Alleröd (B/A) and Preboreal. The enhanced oxygenation during cold spells is linked to the North Pacific Intermediate Water (NPIW), while interglacial increase after 8.5 ka is linked to an intensification of the Kuroshio Current due to strengthened northeast trade winds over the tropics. The enhanced formation of the NPIW during Heinrich Stadial 1 (HS1) was likely driven by the perturbation of sea ice formation and sea surface salinity oscillations in the high-latitude North Pacific. The diminished sedimentary oxygenation during the B/A due to a decreased NPIW formation and enhanced export production, indicates an expansion of the oxygen minimum zone in the North Pacific and enhanced CO2 sequestration at mid-depth waters, along with the termination of atmospheric CO2 concentration increase. We attribute the millennial-scale changes to an intensified NPIW and enhanced abyss flushing during deglacial cold and warm intervals, respectively, closely related to variations in North Atlantic Deep Water formation. [ABSTRACT FROM AUTHOR]

The East China Sea Shelf has an unusually wide and low gradient shelf, supplied from sediment‐charged rivers and large river delta systems, with bottom currents sweeping the sea floor and located in the path of strong typhoons. Sediment gravity flow deposits, including four hybrid event beds and a high density turbidite, are identified in a core from the mid‐shelf of the East China Sea. The hybrid event beds typically comprise three or two internal divisions from the base to the top: (i) H1, H3 and H5; or (ii) H3 and H5. Radiocarbon ages of the hybrid event beds were in the range of 3821 to 8526 yr bp. Based on correlation with surrounding cores, the hybrid events may have happened at any time between 1930 yr bp and 3890 yr bp. The δ13C values in hybrid event beds together with bathymetry data suggest local erosion on the shelf. The average δ13C value for the H1 division is similar to the H3 division in the hybrid event beds, implying that the organic matter in the H1 and H3 divisions may come from the same source area. Cross‐plots of upper continental crust normalized rare earth elements in the five units reveal that the sediment source of the four hybrid event beds and the turbidite was ultimately primarily from Korean rivers. Partial transformation from a moderate‐strength debris flow with the additional role of erosional bulking can explain occurrences of hybrid event beds on the East China Sea Shelf. The data indicate that hybrid sediment gravity flow deposits were sourced from intra‐shelf failures and subsequently transformed and deposited as hybrid event beds. The study shows that hybrid sediment gravity flows and turbidity currents may not necessarily indicate proximity to a major fluvial or deltaic system and that intra‐shelf sedimentation can be a sediment source. It is unlikely that the debris flows and turbidity currents were triggered by a hyperpycnal flow or tsunami, because both can carry continental and/or coastal signals which have not been recognized in the core. Typhoons are the probable triggering mechanism. [ABSTRACT FROM AUTHOR]

We investigate suspended particles collected from the upper mixed layer in the inner shelf of the southern East China Sea during autumn 2013 for carbon and nitrogen (POC and PN) contents and their isotope compositions (δ13C and δ15N) along with hydrographic parameters to understand the sources and dynamics of particulate organic matter (POM) in the study area. Results indicated that the extensive hydrological processes affect the biogeochemical composition of suspended POM, as revealed by the horizontally mixing POM and the spatial variation of δ15N and molar C/N ratio. Low C/N (2.4–6.5) and a weak correlation between POC and in situ chlorophyll fluorescence suggested that POM is dominated by the recently formed and well‐preserved planktonic OM. By fitting the linear correlation between δ13C and POC data with a photosynthetic fractionation model, we further disentangled dynamic controls of phytoplankton production and species diversity on δ13C variability (−24.3 to −21.3‰), emphasizing the constant effect of productivity‐derived POC on δ13C (0.02‰ per μg/L). The δ15N variability (2.3–7.4‰) is largely controlled by the mixing of isotopically different nitrogen sources, in which the importance of biological nitrogen fixation is unfolded based on the small δ15N and the negative correlation between δ15N of POM and seawater temperature. This implies that Kuroshio‐induced biological N fixation plays an important role in supporting the marine production in the East China Sea. These hydrologically driven δ13C and δ15N changes of marine productivity‐derived POM suggest that internal biophysical dynamics rather than terrestrial versus marine OM mixing largely control the C and N compositional variability in the shelf seas. Plain Language Summary: Mixing of water masses on the shallow continental shelf of the East China Sea is thought to impact biogeochemical dynamics of suspended particulate organic matter on seasonal basis, but the mechanisms involved remain unclear. In this study, we measured carbon and nitrogen elemental and isotopic composition of particulate organic matter in the upper mixed layer along with hydrographic parameters during autumn season when the upwelled Kuroshio water travels closer to the coast. Results indicated that particulate organic matter is dominated by two sources of plankton‐derived organic matter that mixed horizontally by hydrodynamics. In addition, the upwelled Kuroshio contribute to marine productivity significantly by inducing biological nitrogen fixation on the shelf; the region is otherwise N‐starved. These findings based on observational and analytical results can help marine biogeochemists understand how carbon and nitrogen isotopes varied seasonally by the impact of offshore current over the river‐dominated shallow shelf, although the influence of Kuroshio on marine fisheries is beyond the scope of our investigation. Key Points: Hydrological conditions largely control the biogeochemical composition of suspended particulate organic matter in the southern East China SeaParticulate organic matter in the upper mixed layer is mainly of marine origin, despite having wide ranges of δ13C and δ15N valuesKuroshio‐induced biological nitrogen fixation is important for marine production in the southern East China Sea [ABSTRACT FROM AUTHOR]

Lower glacial atmospheric CO2 concentrations have been attributed to carbon sequestration in deep oceans. However, potential roles of voluminous subtropical North Pacific in modulating atmospheric CO2 levels on millennial timescale are poorly constrained. Further, an increase in respired CO2 concentration in the glacial deep ocean due to biological pump generally is coeval with less oxygenation in the subsurface layer. This link thus offers a chance to visit oceanic ventilation and the coeval export productivity based on redox-controlled sedimentary geochemical parameters. Here we investigate a suite of sediment geochemical proxies to understand the sedimentary oxygenation variations in the subtropical North Pacific (core CSH1) over the last 50 thousand years (ka). Our results suggest that sedimentary oxygenation at mid-depths of the subtropical North Pacific intensifies during the episodes of late glacial (50-25 ka), Last Glacial Maximum (LGM) and also the interval after 8.5 ka, especially pronounced for the North Atlantic millennial-scale abrupt cold events of the Younger Dryas, Heinrich Stadial (HS) 1 and 2. On the other hand, oxygen-depleted seawater is found during the Bölling-Alleröd (B/A) and Preboreal. Our findings of enhanced sedimentary oxygenation in the subtropical North Pacific is aligned with intensified formation of North Pacific Intermediate Water (NPIW) during cold spells, while the ameliorated sedimentary oxygenation seems to be linked with the intensified Kuroshio Current since 8.5 ka. In our results, diminished sedimentary oxygenation during the B/A indicates an enhanced CO2 sequestration at mid-depth waters, along with slight increase in atmospheric CO2 concentration. Mechanistically, we speculate that these millennial-scale changes were linked to the strength of North Atlantic Deep Water, leading to intensification of NPIW formation and enhanced abyss flushing during deglacial cold and warm intervals, respectively. Enhanced formation of NPIW seem to be driven by the perturbation of sea ice formation and sea surface salinity oscillation in high latitude North Pacific through atmospheric and oceanic teleconnection. During the B/A, decreased sedimentary oxygenation likely resulted from an upward penetration of aged deep water into the intermediate-depth in the North Pacific, corresponding to a resumption of Atlantic Meridional Overturning Circulation. [ABSTRACT FROM AUTHOR]

We measured bromine to total organic carbon (Br:TOC) ratios as an organic source indicator in terrestrial and marine settings of Taiwan, a tectonically active margin that differs from previously studied, passive margins. Terrestrial lake sediments, soils, and river bed and suspended sediments showed Br:TOC ratios ranging from 0.02 to 2.8 mg‐Br/g‐TOC. In ocean margin sediments, Br:TOC ratios ranged from terrigenous values up to 7.6 mg‐Br/g‐TOC. A two‐component Br:TOC mixing model for ocean margin sediments indicates roughly equal proportions of terrigenous and marine organic matter (FT and FM, respectively). Terrestrial δ13C values varied from −31.5 to −24.7‰, a range which is twice the difference between the isotopic terrigenous and marine end‐members used to calculate these proportions. FT and FM based on δ13C were similar to those using Br:TOC if averaged across all marine sediments but often differed at the level of individual samples. Depth profiles of amounts of these two forms of organic matter (OCterr and OCmar) using Br:TOC ratios show that OCmar burial is relatively constant while OCterr and hence TOC vary more strongly; this pattern suggests either episodic terrigenous carbon inputs or winnowing before burial. Variations in TOC:TN and δ13C are consistent with this control of TOC by terrigenous carbon. This study validates Br:TOC as a source indicator for terrigenous versus marine‐derived organic matter in sediments derived from mountainous areas in Oceania. As a single parameter source indicator it should have less error than δ13C due to less uncertainty of the terrestrial end‐member. Plain Language Summary: Ocean margins account for most burial of organic matter in Earth's sediments. This burial affects global cycles such as carbon, nitrogen, and oxygen. Both land and sea contribute organic matter to these margin sediments, varying in extent in different places and times. Here we explore the use of bromine as an indicator of land versus sea contribution in Taiwan—representing the sediment‐rich, southwest Pacific region of Oceania. We compare the use of bromine with the more commonly used stable carbon isotope approach, finding that each provides 50:50 estimates of land versus sea sources at the scale of averages. Nevertheless, there is less agreement at the scale of individual samples, probably due to wide ranges of carbon isotope compositions in terrestrial end‐members. Key Points: We report the first time Br measurements of terrestrial particulates and marine sediments in and off Taiwan and, by example, the important source areas of OceaniaBr:TOC ratios show less variability in terrigenous end‐members than δ13C and hence provide an advantage in binary mixing models to estimate organic matter sourcesBr:TOC ratios in marine sediments imply relatively constant inputs of marine organic matter coupled to episodic inputs of terrigenous organic matter [ABSTRACT FROM AUTHOR]

Continental shelves and marginal seas are key sites of particulate organic matter (POM) production, remineralization and sequestration, playing an important role in the global carbon cycle. Elemental and stable isotopic compositions of organic carbon and nitrogen are thus frequently used to characterize and distinguish POM and its sources in suspended particles and surface sediments in the marginal seas. Here we investigated suspended particulate matter (SPM) collected around deep chlorophyll maximum (DCM) layers in the southern East China Sea for particulate organic carbon and nitrogen (POC and PN) contents and their isotopic compositions (ϐ13CPOC and ϐ15NPN/ to understand provenance and dynamics of POM. Hydrographic parameters (temperature, salinity and turbidity) indicated that the study area was weakly influenced by freshwater derived from the Yangtze River during summer 2013. Elemental and isotopic results showed a large variation in ϐ13 CPOC (-25.8 to -18.2 ‰) and ϐ15NPN (3.8 to 8.0 ‰), but a narrow molar C =N ratio (4.1-6.3) and low POC = Chl a ratio (<200 g g-1) in POM and indicated that the POM in DCM layers was newly produced by phytoplankton. In addition to temperature effects, the range and distribution of ϐ13CPOC were controlled by variations in primary productivity and phytoplankton species composition; the former explained ∼70% of the variability in ϐ13CPOC. However, the variation in ϐ15NPN was controlled by the nutrient status and ϐ15NNO-3 in seawater, as indicated by similar spatial distribution between ϐ15NPN and the current pattern and water masses in the East China Sea; although interpretations of ϐ15NPN data should be verified with the nutrient data in future studies. Furthermore, the POM investigated was weakly influenced by the terrestrial OM supplied by the Yangtze River during summer 2013 due to the reduced sediment supply by the Yangtze River and north-eastward transport of riverine particles to the northern East China Sea. We demonstrated that the composition of POM around DCM layers in the southern East China Sea is highly dynamic and largely driven by phytoplankton abundance. Nonetheless, additional radiocarbon and biomarker data are needed to reevaluate whether or not the POM around the DCM water depths is influenced by terrestrial OM in the river-dominated East China Sea. [ABSTRACT FROM AUTHOR]

The stability of Earth's critical zone is intimately linked with erosion, weathering and vegetation type and density. Therefore, it affects global biogeochemical processes which in turn affect the global climate by absorbing and reflecting solar radiation, and by altering fluxes of heat, water vapour, carbon dioxide and other trace gases through various feedback mechanisms. However, there is a lack of knowledge about how Earth's critical zone processes have changed over time and their link with past monsoon variability, especially in Asia. The study of lake sediments, which contain a suite of inorganic elemental and isotopic proxies, may facilitate the understanding of the Earth's critical zone processes on millennial timescales. Here we reconstruct the history of erosion-weathering-vegetation interactions since ~14.7 ka using geochemical records from a radiocarbon-dated sediment core from Lake Gonghai in the monsoon-arid transitional zone of north China. Detrital (Al, Ti, K, Rb) and authigenic (Ca, Sr) elemental records reveal distinct, millennial-scale, late deglacial-Holocene erosion and weathering patterns and transitions with the former (latter) elements showing higher (lower) values in warm intervals and vice versa. Chemical Index of Alteration (CIA) molar, a humidity proxy, suggests low humidity during the late deglacial ~11.5-14.7 ka, high humidity during the early-mid Holocene ~11.5-3.2 ka and intermediate humidity during the late Holocene interval since ~3.2 ka. The results of cross-spectral analysis and comparison of our records with other climate reconstructions also suggest a pattern of orbitally-phased humidity changes in north China. Overall, our results provide evidence for the solar-forcing of Earth's surface processes in mid-latitude China under natural climatic conditions. [ABSTRACT FROM AUTHOR]

Abstract: Marine gas hydrates, one of the largest methane reservoirs on Earth, may greatly affect the deep sea sedimentary environment and biogeochemistry; however, the carbon geochemistry in gas hydrate‐bearing sediments is poorly understood. In this study, we investigated the carbon variables in sediment core 973‐3 from the southwestern Taiwan Basin in the South China Sea to understand the effect of environmental factors and archaeal communities on carbon geochemistry. The carbon profiles suggest the methanogenesis with the incerase of dissolved inorganic carbon (DIC) and high total organic carbon (TOC) (mean = 0.46%) originated from terrigenous organic matter (mean δ13CTOC value of −23.6±) driven by the abundant methanogen ‘Methanosaeta and Methanomicrobiales'. The active anaerobic oxidation of methane is characterized by the increase of DIC and inorganic carbon (IC), and the depleted δ13CIC, coupled with the increase of TOC and the decrease of δ13CTOC values owing to the methanotroph ‘Methanosarcinales/ANME’ in 430–840 cm. Environmental factors and archaeal communities in core 973‐3 are significantly correlated to carbon variables owing to methane production and oxidation. Our results indicate that the carbon geochemical characteristics are obviously responding to the formation and decomposition of gas hydrates. Furthermore, pH, Eh and grain size, and Methanosaeta greatly affect the carbon geochemistry in gas hydrate‐associated sediments. [ABSTRACT FROM AUTHOR]

Continental shelves and marginal seas are key sites of particulate organic matter (POM) production, remineralization and sequestration, playing an important role in the global carbon cycle. Elemental and stable isotopic compositions of organic carbon and nitrogen are frequently used for characterizing organic matter and distinguishing their sources in suspended particulates and surface sediments in the marginal seas. Here we investigate suspended particulate matters (SPM) collected from the deep chlorophyll maximum (DCM) layer in the continental shelf of the East China Sea for particulate organic carbon and nitrogen (POC and PN) contents and their isotopic compositions (δ13CPOC and δ15NPN) to understand biogeochemical characteristics of POM straddling at biotic-dominated DCM depths. When combined with hydrographic parameters, such as temperature, salinity and turbidity, and chlorophyll a (Chl a), these elemental and isotopic results revealed that POM in the DCM layers was largely from the newly-produced, in situ phytoplankton-dominated OM and have wider δ13CPOC and δ15NPN compositions than previously thought. As supported by the POC to Chl a ratio, a large variation of δ13CPOC was resulted from the changes in primary productivity and phytoplankton species, whereas the nutrient status and δ15N of dissolved nitrate were the main controlling factors of δ15NPN variability in the DCM layers. Consistently, the spatial distribution of δ15NPN showed a similarity with the current pattern in the East China Sea, with 15N-enriched freshwater in the coastal region and Kuroshio Water in the northeast of Taiwan Island, but nutrient-depleted Taiwan Warm Current Water in the mid-shelf; as the latter seems to have promoted the N2-fixation, resulting in the depleted δ15NPN in the mid-shelf. Furthermore, SPM investigated here seems not to be influenced by the terrestrial organic matter supplied by the Yangtze River (Changjiang) in summer 2013, a finding that is contrary to a number of previous studies' conclusion. Nonetheless, given the complications associated with stable isotopes of organic matter, additional parameters such as radiocarbon and biomarkers are crucial to revalidate whether or not SPM in the DCM depths is influenced by terrestrial organic compounds in the river-dominated East China Sea. [ABSTRACT FROM AUTHOR]

Mangroves are highly productive blue carbon ecosystems that preserve high organic carbon concentrations in soils. In this study, particle size, bulk elemental composition and stable carbon isotope were determined for the sediment cores collected from the landward and seaward sides of two mangrove forests of different ages (M1, ca. 60; M2, ca. 4 years old) to determine the effects of geomorphic setting and age (L1 = old mangrove and S1 = salt marsh stand in M1; L2 = young mangrove and S2 = bare mudflat in M2) on sediments and organic carbon accumulation. The objective of this study was to determine the feasibility of the northernmost human-planted mangroves in China to accumulate sediment and carbon. Our results showed that fine-grained materials were preserved well in the interior part of the mangroves, and the capacity to capture fine-grained materials increased as the forest aged. The biogeochemical properties (C/N: 5.9 to 10.8; δ13C: −21.60‰ to −26.07‰) indicated that the local organic carbon pool was composed of a mixture of autochthonous and allochthonous sources. Moreover, the accumulation of organic carbon increased with the forest age. The interior part of the old mangrove had the highest organic carbon stock (81.93 Mg Corg ha−1). These findings revealed that mangrove reforestation had positive effects on sediments and organic carbon accretion. [ABSTRACT FROM AUTHOR]

In this study, the spatial distribution of lignin-derived phenols, bulk elemental composition and different phosphorus (P) species in surface sediments along six rivers discharging into Zhejiang coast, Southeast China, were investigated to improve the understanding of the carbon and P dynamics in these small river systems. The Shuang, Jiao, Ximen, Feiyun and Ao Rivers have total organic carbon (TOC) ranging from 0.29% to 2.77% and Λ (total lignin in mg/100 mg TOC) ranging from 0.24 to 4.24; Qiantang River has the lowest Λ (0.08–0.19) but the highest TOC (1.05%–6.46%). Jiao, Ximen, Feiyun and Ao Rivers have mean the total P (TP) and bioavailable P (BAP) of 34 to 124 mg/kg and 29 to 89 mg P/kg, and mean OC/OP molar ratio of 397–917. Qiantang River has the lowest mean TP and BAP of 13 mg P/kg and 7 mg P/kg, and highest OC/OP of 18,753; whereas Shuang River has the highest mean TP and BAP of 645 mg P/kg and 559 mg P/kg, and lowest mean OC/OP of 90. The lowest Λ, TP and BAP, but highest OC/OP, in the Qiantang River could be due to tidal bore causing rapid cycling of carbon and P. Trends of slight decrease in abundance of OC, Λ, TP and BAP, but increasing ratios of vanillic acid to vanillin [(Ad/Al)v], syringic acid to syringaldehyde [(Ad/Al)s] and OC/OP farther downstream of the rivers indicate a continuous decomposition of organic matter during transport along the rivers. [ABSTRACT FROM AUTHOR]

Grain size is an important controlling factor of the chemical composition of sediments. To understand the role of grain size in the content of rare earth elements (REE) in tropical mountainous river sediments and to establish suitable provenance proxies, sediments collected from Pahang River and Kelantan River, Peninsular Malaysia, were determined for REE contents in six size fractions (<2 μm, 2–4 μm, 4–8 μm, 8–16 μm, 16–32 μm, and 32–63 μm). The results indicate that the total REE contents (∑REE) from these two rivers are weakly correlated with grain sizes. The normalized REE patterns of various grain-size fractions to <63 μm fractions revealed a flat pattern for light rare earth elements (LREE), but were gradually enriched in heavy rare earth elements (HREE) with increasing grain size. These results indicate that the grain size constraint on REE is very complex. The relationship between REE contents and mineral compositions of size-fractioned sediments further suggests that clay minerals cause high REE contents in clay components (<2 μm). The dilution effect of quartz and feldspars on REE is another controlling factor, leading to low REE content in medium-fine silt components (2–32 μm). In addition, heavy minerals, zircon, monazite and amphibole, play an important role in enriching REE in coarse silt components (32–63 μm), especially zircon as the major contributor to the enrichment of HREE with increasing grain size. By combining the content of REE, the normalized REE patterns and the REE characteristic parameters for different grain sizes, we find that the 4–8 μm fraction is sensitive to REE variation among the six size fractions investigated. Furthermore, the relationship between upper continental crust-normalized δEu and (Gd/Yb) is reliable for distinguishing the sediment characteristics of Pahang River and Kelantan River and can therefore be used as an effective indicator for identifying Malaysian river-sourced sediments in the southern South China Sea. • REE compositions in different grain-size fractionated sediments from two tropical mountainous rivers are different. • Mineral composition is the main controlling factor of the grain size effect on REE. • The 4–8 μm fraction represents REE variation sensitively among six size fractions investigated in these two rivers. • δEu UCC -(Gd/Yb) UCC discriminant diagram can be used to distinguish Malaysian river-sourced sediments in the southern SCS. [ABSTRACT FROM AUTHOR]

• Various types of soils and bedrocks contribute to variability of sedimentary OC composition in different rivers. • Biospheric OC contents are higher in sediments of northwestern rivers than that of southern rivers. • Marked differences in fluxes of biospheric and petrogenic OC emerge for different proxy constraints tracing OC provenance. Oceanic islands in the western Pacific export ∼35% of particulate organic carbon (OC) to the world ocean, but composition and age of OC varies dramatically among and within the islands. Understanding island-wide variation in sources and controls on the sedimentary OC in a series of rivers is therefore essential to assess the role of oceanic islands on the global carbon cycle. Stable and radioactive carbon isotopic compositions of sedimentary OC in 17 rivers across Taiwan indicate various proportions of biospheric OC derived from soil overlain by C3 and C4 vegetation and petrogenic OC from sedimentary and metamorphic rocks. Higher fractions of biospheric OC occur in sediments of northwestern rivers, while petrogenic OC is dominant in southern river sediments. Vegetation type, lithological setting, and sediment yield in river basins largely control island-wide OC compositions in river sediments. Considerable differences in export fluxes of biospheric and petrogenic OC based on different provenance proxies exist for individual rivers, highlighting the need for additional radiocarbon measurement (with high sample frequency) to better understand the role of oceanic islands in the global carbon cycle. [ABSTRACT FROM AUTHOR]

The Yellow River (or Huanghe and also known as China's Sorrow in ancient times), with the highest sediment load in the world, provides a key link between continental erosion and sediment accumulation in the western Pacific Ocean. However, the exact age of its influence on the marginal sea is highly controversial and uncertain. Here we present high-resolution records of clay minerals and lanthanum to samarium (La/Sm) ratio spanning the past ~1 million years (Myr) from the Bohai and Yellow Seas, the potential sedimentary sinks of the Yellow River. Our results show a climate-driven provenance shift from small, proximal mountain rivers-dominance to the Yellow River-dominance at ~880 ka, a time period consistent with the Mid-Pleistocene orbital shift from 41-kyr to 100-kyr cyclicity. We compare the age of this provenance shift with the available age data for Yellow River headwater integration into the marginal seas and suggest that the persistent influence of the Yellow River on the Chinese marginal seas must have occurred at least ~880 ka ago. To our knowledge, this study provides the first offshore evidence on the drainage history of the Yellow River within an accurate chronology framework.