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C/Cu composites have been widely used in the field of electrical contacts due to their excellent conductivity and anti-ablation properties. However, the poor wettability between C and Cu matrix severely significantly shortens the service life of C/Cu electrical contacts. In this work, we theoretically and experimentally demonstrate that rare earth alloying in Cu matrix enhances the interfacial wettability between C and Cu, leading to the improved electrical contact performance. The wetting angle is reduced from 132° to 46° by the incorporation of La (0.56 wt%) into the Cu matrix, which is attributed to the formation of interfacial LaC2, where the Griffith's separation energy of LaC2/Cu was calculated to be −4.6 J/m2 much lower than those of C/Cu (0.13 J/m2) and C/CuLa (0.06 J/m2). The ablation surface of the electric contact demonstrates that improved wettability can diminish carbon accumulation, thereby reducing the contact resistance from 50 mΩ to 2.2 mΩ after 1000 cycles at 380 V and 60 A, with a reduction of mass loss by 50%.This work reveals the bonding mechanism of C/Cu interface, which paves a way for rational design of C/Cu-based electrical contact materials.

The preferential oxidation of alloying elements has long been recognized as the primary mechanism underlying the oxidation resistance of copper alloys. However, the presence of various alloy phases within the Cu matrix complicates the oxidation behavior. Herein, combined DFT calculations and antioxidation experiment were conducted to evaluate the oxidation behavior and underlying mechanism of Cu–La alloys. The results indicate that the oxidation resistance of Cu is significantly enhanced by La element with a reduced mass gain of 49% at 100 °C for 100 h. The effects of oxidation behavior of Cu6La on the oxidation resistance of Cu is further explored by DFT calculations. It reveals that the Cu6La phase with a low work function exhibits a strong affinity for the O atoms. However, the diffusion activation energy of the absorbed O is calculated to be lower in Cu6La than that of O in Cu, which is conducive to mitigate the further erosion of O on Cu matrix. Moreover, the Cu2O–La layer formed on the Cu6La surface is more stable and the oxygen diffusion coefficient in it is lower, which impedes the entry of oxygen. This work advances the understanding of alloying effect on oxidation of Cu surfaces that can be extended to other metal surfaces.

The treatment of acidic desulphurization wastewater is challenging due to its high acidity and complex composition. Typically, acidic desulphurization wastewater is treated as high-salt wastewater after alkali neutralization, leading to issues such as high treatment costs and secondary pollution. To achieve resource utilization and reduce pollutant discharge, diffusion dialysis was employed for heavy metal removal and acid recovery (comprising hydrochloric acid and sulfuric acid). Subsequently, the separating property of hydrochloric acid and sulfuric acid between monovalent selective electrodialysis and acid-resistant nanofiltration was compared to determine the optimal process, the parameters were optimized through experiments. The results indicated that optimal performance was achieved at membrane surface flow rate of 2.86×10-6 cm/s, with acid recovery rate of 87.5% and metal ion removal rate of >93%. The monovalent selective coefficient PSO42-Cl- reached its peak at 7.5 MPa, significantly surpassing that of monovalent selective electrodialysis. Through the combined treatment of diffusion dialysis and acid-resistant nanofiltration, hydrochloric acid with a mass fraction of 3.34% and purity of 99.65% could be obtained. The treatment water volume was 30 m3/d, total project investment was 3.96 million yuan, and operating cost was estimated at 1.27 million yuan/a. Compared to traditional treatment processes, annual savings was approximately 1.06 million yuan with the investment payback period of about 3.8 years, which had significant environmental and economic benefits.

The study examined the functional properties of lactic yeast-fermented Tartary buckwheat sprout with passion and pineapple juice (Tatary buckwheat sprout juice). Pineapple and passion fruit were included during fermentation to improve the sensory and nutritional quality of the juice. We initially created a juice with Tartary buckwheat sprouts, and then fermented it with Lactobacillus plantarum and yeast (Saccharomyces cerevisiae) to produce a novel fermented sprout juice. Our results indicated that the best organoleptic quality was achieved when the inoculum of Lactobacillus plantarum was 2%, the inoculum of yeast was 1%, and the fermentation time was 30 hours. The results showed that fermentation resulted in a 1.55-fold increase in the total amino acid content, with fresh sweet amino acids increasing by 1.75-fold and sour-bitter amino acids increasing by 1.33-fold. Additionally, the levels of acetic acid, lactic acid, citric acid, and tartaric acid in the buckwheat sprout juice increased by 12.31%, 11.45%, 4.22%, and 3.88%, respectively. GC-MS analysis revealed a significant increase of volatile flavoring substances, such as alcohols and esters, by more than 24.7% in the fermentation products. From the results, yeast-Lactobacillus fermentation process may effectively improve the nutritional values of Tartary buckwheat sprout juice.

Abstract Photothermoelectric (PTE) detectors combine photothermal and thermoelectric conversion, surmounting material band gap restrictions and limitations related to matching light wavelengths, have been widely used in telecommunication band detection. Two‐dimensional (2D) materials with gate‐tunable Seebeck coefficient can induce the generation of photothermal currents under illumination by the asymmetric Seebeck coefficient, making them promising candidate for PTE detectors in the telecommunication band. In this work, we report that a newly explored van der Waals (vdW) layered material, SnP2Se6, possessing excellent field regulation capabilities and behaviors as an ideal candidate for PTE detector implementation. With the assistance of temperature‐dependent Raman characterization, the suspended atomic thin SnP2Se6 nanosheets reveal thickness‐dependent thermal conductivity of 1.4–5.7 W m−1 K−1 at room temperature. The 2D SnP2Se6 demonstrates high Seebeck coefficient (S) and power factor (PF), which are estimated to be −506 μV K−1 and 207 μW m−1 K−2, respectively. By effectively modulating the SnP2Se6 localized carrier concentration, which in turn leads to inhomogeneous Seebeck coefficients, the designed dual‐gate PTE detector with 2D SnP2Se6 channel demonstrates wide spectral photoresponse in telecommunication bands, yielding high responsivity (R = 1.2 mA W−1) and detectivity (D* = 6 × 109 Jones) under 1550 nm light illumination. Our findings provide a new material platform and device configuration for the telecommunication band detection.

Objectives: This study aimed to summarize the existing literature on risk factors for arrhythmias after chemotherapy in cancer patients. To provide reliable evidence for treating arrhythmias after chemotherapy in oncology patients by assessing multiple biasing factors in the literature and quantifying the risk factors. Methods: The risk factors for arrhythmia following tumor chemotherapy were systematically collected from various reputable databases, including PubMed, Cochrane Library, MEDLINE, EMBASE, and multiple Chinese databases, covering the period from inception to May 2023. Two independent reviewers performed rigorous article screening, data extraction, and assessment of research quality. Data analysis was conducted using Review Manager 5.4 software, ensuring a standardized and robust approach to evaluate the gathered evidence. Results: The analysis of chemotherapy-induced arrhythmias included 16 articles, encompassing 14,785 cancer patients. Among the patients, 3295 belonged to the arrhythmia group, while 11,490 were in the non-arrhythmia group. These studies identified 12 significant risk factors associated with arrhythmias following chemotherapy in cancer patients. The findings of the analysis are as follows. General patient characteristics: The incidence of post-chemotherapy arrhythmias was 14.33 times higher in oncology patients aged ≥60 years compared to patients

Abstract Iron-based nanotubes are promising candidates for high performance electromagnetic wave absorbing fillers due to their high aspect ratio, light weight, high axial permeability and high saturation magnetization. Furthermore, the introduction of carbon can improve dielectric loss and block the agglomeration of iron nanotubes. Here, Fe@C composite nanotubes were prepared by introducing carbon onto the surface of precursor α-FeOOH’ fibers followed by hydrogen-thermal annealing. We find that Fe@C composite nanotubes retain the one-dimensional nanostructure of the precursor throughout the annealing. The well-developed lattice and nanostructure of Fe@C nanotubes endow high saturation magnetization, high anisotropy, suppressed eddy current effect and cross-particle exchange coupling as well, and thus contribute to an enhanced permeability. Coatings with Fe@C as fillers achieve a reflection loss of up to −69.34 dB at 3.37 GHz at the matching thickness of 3.97 mm. The Fe@C composite nanotubes developed here are a promising candidate for high performance electromagnetic wave absorbing fillers.

FeSiAl alloys with a composition of Fe-9.6Si-5.4Al, also known as Sendust alloys, present the unique potential to exhibit efficient electromagnetic wave absorption (EMA) in the P-band. However, the electromagnetic properties of this type of alloy are highly sensitive to the shape, microstructure, and microchemistry, which then inspire the current research. The evolution of the microstructure/microchemistry of FeSiAl particles was systematically revealed in a single particle scale for the first time, and the resulting influence on the electromagnetic properties was investigated. Recrystallization occurs in the annealing process on FeSiAl particles and the oxide films on the surface evolve evidently when annealed in 5%H2/Ar or air, which can conduce improved electromagnetic properties. The FeSiAl particles annealed in 5%H2/Ar present efficient EMA in the P-L band while those in air contribute to high reflection loss. This work indicates the feasibility of achieving a high and adjustable EMA efficiency in the P-L band through microstructure and microchemistry tailoring.