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A novel SrWO4-poly(3,4-ethylene dioxythiophene) (PEDOT)-polypyrrole (PPy) nanocomposite was synthesized via chemically oxidative polymerization and considered by using numerous method of the techniques. The resulting SrWO4/PEDOT-PPy nanocomposite demonstrated remarkable electrochemical sensing capabilities for sulfadiazine (SFA). As a modified glassy carbon electrode (SrWO4/PEDOT-PPy/GCE) revealed for superior catalytic activity in the electrochemical oxidation of sulfadiazine, enabling sensitive detection with quantification and detection limits of 1.0936 × 10−9 M µA−1 and 2.2104 × 10−9 M µA−1, respectively. This technique effectively determined SFA content in real samples. Additionally, SrWO4/PEDOT-PPy demonstrated extraordinary photocatalytic ability, achieving a Methylene Blue (MB) degradation rate of up to 99.1% under halogen light irradiation within 80 min. Hybrid photocatalyst has exhibited to strong reusability and photocatalytic stability under frequent light exposure. A contrivance for the photocatalytic deprivation of MB by SrWO4/PEDOT-PPy is proposed. These results underscore the crucial role of SrWO4/PEDOT-PPy in practical environmental remediation analysis. The fluorescence investigations have betrothed to terephthalic acid radical formations of SrWO4/PEDOT-PPy hybrids, which were modulated by different approaches, and its mainly driven for higher illumination aptitudes. Meanwhile, this was more supporting for physio-chemical properties of the phenomenon, at this consequential with significantly well improved to the photocatalytic performances. Because of this, SrWO4/PEDOT-PPy hybrid materials were comprehended to deliver excellent kinetics, and better recyclable activities. [ABSTRACT FROM AUTHOR]

An organic–inorganic hybrid polyoxometalate (POM) CoPMoV [PMoVI8VIV4VV2O42][Co(Phen)2(H2O)]2[TEA]2•H3O•3H2O (Phen = 1,10-phenanthroline, TEA = triethylamine) prepared by hydrothermal synthesis was explored as a heterogeneous catalysts to remove methylene blue (MB) through Fenton-like reaction and catalytic reduction. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS) were employed to characterize CoPMoV. The MB removal rates for the Fenton-like reaction and the catalytic reduction were 91.6% (120 min) and 97.5% (2 min), respectively, under optimum conditions. CoPMoV demonstrated excellent stability and recyclability in the Fenton-like reaction and catalytic reduction, which was confirmed by 5 cycle tests. Plausible mechanisms for MB degradation and reduction have also been proposed. Benefiting from the excellent redox properties of cobalt and [PMoVI8VIV4VV2O42]5− anion, CoPMoV could act as a Fenton-like and reductive catalyst for the removal of MB. This study provides a green and facile strategy to design POM-based organic–inorganic material for dye wastewater treatment via oxidation and reduction. [ABSTRACT FROM AUTHOR]

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The nanoporous materials derived from the ZiF-8 metalorganic framework are highly interesting because of their features like good thermal stability, catalytic performance, and electric conductivity. Therefore, ZiF-derived metal oxide was utilized in several applications, for instance, energy storage and environmental remediations. Herin, we compare the as-prepared ZnO, ZiF-8, and ZnO derived from ZiF-8 in terms of structural, thermal, and morphological properties. Thus, the photocatalytic performance of all compositions. The preparation process is an effective parameter in the morphology of the sample surface. The as-synthesized ZnO had nanoparticle morphology with a size of 50–80 nm. However, the ZiF-8 has cubic morphology with a long rod. The decomposition of ZiF-8 converted the sample to ZnO coated by carbon, indicating a high surface and fit morphology for photocatalysis. These results mean that ZnO derivative from ZiF-8 nanoparticles has the best efficiency for water desalination with 95%. ZnO drives from ZiF-8 demonstrated the smallest charge transfer resistance compared to that of as-prepared ZnO, and ZIF-8, coinciding with the conclusion of the EIS results. The transient photoresponses and electrochemical impedance spectra of the compounds were used further to explore the separation efficiency of the photogenerated charge carriers. [ABSTRACT FROM AUTHOR]

Till date it is a great challenge to synthesize CdS photocatalyst with a high stability. In this study, a stable CdS photocatalyst was successfully synthesized by a simple, cost‐effective hydrothermal route via cadmium acetate and thiourea as Cd and S precursors, respectively. The effect of different processing times (8 h and 24 h) and molar ratios on the photocatalytic activity and stability were mainly investigated. The samples were characterized in detail by XRD, FT‐IR, XPS, UV‐vis DRS, Photolummiscence spectroscopy and Surface photovoltage. The photocatalytic activity of the as‐obtained nanostructures was examined for methylene blue (MB) dye degradation under visible light irradiation (λ≥420 nm). After 70 min of irradiation, nearly 82 % of MB was degraded by CdS nanostructures, display an improved photocatalytic activity for MB degradation with an apparent rate constant (k) of 0.019 min−1. Additionally, CdS nanostructures sustained a good photostability after five consecutive cycles. The higher photocatalytic activity of CdS nanostructure is attributed to an efficient separation of photogenerated electron‐hole pairs stimulated by its optimal molar ratio, optimal temperature and surface morphology. Our synthesized stable nanostructures have potential for dye contaminated waste‐water treatment. [ABSTRACT FROM AUTHOR]

Zirconium dioxide nanomaterials doped with samarium were produced through a bio-template method, utilizing citric acid as a fuel. Various advanced methods, for instance, XRD, TEM, EDX, PL, XPS, and UV–Vis spectrophotometry, were employed to characterize the compositions. XRD analysis confirmed that all peaks corresponded to the tetragonal phase of ZrO2, with no presence of impurities from other phases. The elemental composition was analyzed using EDX, verifying the presence of Zr, Sm, and O. The energy gap widening concerning the pure ZrO2 may be the well-known Moss–Burstein shift. This shift was linked to an increase in the bandgap (from 5.25eV to 5.54eV) with increasing concentrations of Sm. This observation was made during the analysis of the photocatalysis of pure ZrO2 and various concentrations of Sm-doped ZrO2 for Methylene Blue. The augmentation of Sm doping resulted in an improvement in the efficiency of removing Methylene Blue, increasing the removal rate from 35% to 80%. [ABSTRACT FROM AUTHOR]

Doping transition metals in ZnO nanoparticles play a vital role in enhancing its photocatalytic activity. (Co,Ni) co-doped ZnO nanoparticles have been synthesized via sol–gel combustion method and explored the impact of co-doping on the structural, optical, morphological and photocatalytic properties of ZnO nanoparticles. The XRD pattern elucidated hexagonal wurtzite structure. The incorporation of co-dopants led to red-shift in the energy band gap. Photoluminescence spectral analysis showed the existence of different defects in the lattice on variation of energization. The assessment for photocatalytic activity was carried out by evaluating the degradation of methylene blue (MB) and rhodamine B (RhB) dyes under sunlight irradiation. Among the photocatalysts, 3%Co–3%Ni showed excellent photocatalytic activity within 75 min. This is in accordance with the decrement in crystallite size, red-shift of band gap, introduction of electron trap levels by the dopants and presence of defects such as oxygen vacancies. Additionally, the calculated CIE co-ordinates of the sample lies in the white region (0.32, 0.32) of CIE diagram and computed CCT were above 5000 K establishing its application in cold white light. [ABSTRACT FROM AUTHOR]

Using environmentally friendly technologies to meet the environmental issue of wastewater is very essential. With this regard, a novel PANI@Er-doped ZnO (PEZ) ternary heterojunction was synthesized using ultrasonic-assisted wet impregnation method. This PEZ heterojunction was found enhanced photocatalytic efficiency with better stability in comparison of their counter parts. All parameters of synthesized samples were explored by XRD, UV-DRS, FE-SEM, EDAX, PL, and UV–Vis Spectroscopy to measure the detoriation rate. Significant photodegradation efficiency against methylene blue (MB) was observed nearly 89% in neutral medium in 90 min. The direction of migration of charge carriers, degradation in rate of recombination of photo-generated electron–hole pairs, and their effective separation of synthesized nanocomposite were responsible for this boost up degradation. UV-DRS and PL studies were conducted to assess the energy band gap that determines the absorption behavior of the produced photocatalyst and validate the active interactions of dopant metals with Polyaniline backbone chains. Pseudo -first order relation, best adjusted by an R2 value of 1, best characterized the kinetic studies of methylene blue for all synthesized samples. Therefore, it can be said that Er-ZnO is a unique multifunctional material with applications as a catalyst for the breakdown of organic dyes and an improvement in catalytic behavior upon integration of organic material PANI. The obtained PANI@Er-doped ZnO nanocomposites are anticipated to be effective photocatalyst for the elimination of methylene blue in aqueous environment. [ABSTRACT FROM AUTHOR]

In this study, we synthesized a novel ceramic material Bi0.5Na0.5Ti0.95 (Ni0.2Fe0.2Sb0.6)0.05O3 named BNT-NFS via the solid-state route and assessed its efficacy as a photocatalyst for removing methylene blue dye from wastewater. The synthesized samples underwent thorough characterization using thermogravimetric analysis combined differential thermal analysis TGA-TDA, X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) analysis, and UV–Visible measurements. TGA-DTA and XRD analyses confirmed the successful formation of BNT-NFS material at 1150 °C, exhibiting a hexagonal phase structure. FTIR analysis revealed an intense band at 421 cm−1, corresponding to metal-oxide vibrations in the BNT-NFS spectrum. SEM observations unveiled a distinct microstructure of BNT-NFS composed of grains of varying sizes. BET analysis indicated that the prepared BNT-NFS powder possessed a significant specific surface area of 261.36 m2/g. Optical and photocatalytic assessments demonstrated that BNF-NFS perovskite is a semiconductor material with a band gap of 2.73 eV, exhibiting satisfactory photocatalytic activity for methylene blue MB dye removal. Notably, the removal efficiency reached 60% after 210 min of exposure to sunlight irradiation. This result is better than that registered for the pristine BNT. [ABSTRACT FROM AUTHOR]

This study utilized glucose as the main raw material to prepare carbon nanospheres (CNs) using a hydrothermal method. Polyvinylpyrrolidone (PVP) was employed to modify the CNs, resulting in PVP grafted CNs (PVP-g-CNs). The structural morphology and functional group changes of the CNs before and after modification were characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD). Additionally, the dispersibility and adsorption performance of the modified CNs for methylene blue (MB) were tested. The results showed that the modified CNs exhibited an increased size and altered surface structure, while the amorphous crystal structure remained unchanged. PVP-g-CNs demonstrated good dispersibility in water, and adsorption tests revealed that when the PVP addition amount was 0.50 g and the MB solution mass concentration was 30 mg/L, the maximum adsorption capacity of PVP-g-CNs for MB reached 155.03 mg/g, with the adsorption capacity increasing with the pH of the solution. The fitting results of the adsorption model showed conformity to the pseudo-second-order kinetic model and the Langmuir model, with a theoretical maximum adsorption capacity of 238.095 2 mg/g, thus demonstrating excellent adsorption performance. [ABSTRACT FROM AUTHOR]

A simple sol–gel combustion process was employed for the creation of MFe2O4 (M=Ni, Co) nanoparticles. The synthesized nanoparticles, acting as both photocatalysts and gas sensors, were analyzed using various analytical techniques. MFe2O4 (M=Ni, Co) material improved the degradation of methylene blue (MB) under UV-light irradiation, serving as an enhanced electron transport medium. UV–vis studies demonstrated that NiFe2O4 achieved a 60% degradation, while CoFe2O4 nanostructure exhibited a 76% degradation efficacy in the MB dye removal process. Furthermore, MFe2O4 (M=Ni, Co) demonstrated chemosensitive-type sensor capabilities at ambient temperature. The sensor response and recovery times for CoFe2O4 at a concentration of 100 ppm were 15 and 20, respectively. Overall, the synthesis of MFe2O4 (M=Ni, Co) holds the potential to significantly improve the photocatalytic and gas sensing properties, particularly enhancing the performance of CoFe2O4. The observed enhancements make honey MFe2O4 (M=Ni, Co) a preferable choice for environmental remediation applications. [ABSTRACT FROM AUTHOR]

Effluents generated in aquaculture could contribute to increased risk of environmental contamination. Aquaponic could facilitate the resolution of this problem by transforming those potential pollutants into nutrients for plants, providing an extra vegetable production in a circular economy framework. Highly profitable vegetables such as pitaya (Hylocereus spp.) could improve the economic viability of these farms, but little is known about its performance in aquaponic systems. Rooting and vegetative growth of 12 cuttings of white-fleshed pitaya (Hylocereus undatus) and red-fleshed pitaya (Hylocereus hybridum) were evaluated over a period of six months in two aquaponic systems rearing tilapia with different hydroponic subsystems (Nutrient Film Technique, NFT and Media Bed, MB). A control group of hydroponic culture using substrate filled pots was used for comparison. Water quality and environmental parameters were also measured to evaluate their influence on plant development. Hylocereus hybridum showed higher vegetative growth, and earlier shoot emission in combination with the control system, followed by the NFT and finally the MB. In relation to root growth, Hylocereus undatus showed best results in combination with the substrate system. Best results for precocity in root emission, evaluated in the NFT system, were obtained for Hylocereus hybridum. Water quality parameters had no significant effect on plant development, while fish live weight increased in both systems.

A novel, rapid, and facile method for one-step sonoelectrochemical synthesis of zinc oxide nanoparticles (UEZ) was introduced in this study. The optimum operating parameters have been selected at a voltage of 7.5 V, KCl concentration of 0.5 M, and the reaction time of 60 min. The as-prepared UEZ were characterized by XRD, SEM, and HRTEM. It was found that the UEZ has a hexagonal wurtzite structure with high crystalline quality, good purity, a size range of 30–100 nm, and good photocatalytic degradation of methylene blue. This work provides a facile route for large-scale synthesizing ZnO nanoparticles via anodization. [ABSTRACT FROM AUTHOR]

Water pollution caused by harmful bacteria, heavy metals and dye is a global issue that requires strategic solutions to minimize its environmental impact. In this work, novel polysaccharide-modified polyurethanes (PS-PU) were prepared and evaluated in the removal of S. aureus, methylene blue (MB), and Cu2+ from wastewater. The PS-PU materials were analyzed by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and Nuclear magnetic resonance spectroscopy (1H NMR). The PS-PU has shown impressive antibacterial capabilities against S. aureus, while also demonstrating effective adsorption properties for MB and Cu2+. For optimizing the conditions to maximize MB and Cu2+ removal, the impacts of solution pH, adsorbent dosage, adsorption time, and temperature were investigated. The maximum adsorption of chitosan-modified polyurethane (CS-PU), chitosan and cyclodextrin-modified polyurethane (CS-PU-CD) for MB were 95.15% and 97.58% respectively in just 30 min of contact. When it comes to the removal of Cu2+, the maximum removal rates of 94.73% (CS-PU) and 96.87% (CS-PU-CD) were achieved after 40 min of absorption. The absorption behavior of this system was better described by the quasi-second-order kinetics and Langmuir isotherm model. The intraparticle diffusion demonstrated the multi-step nature of the adsorption process and the pollutants removal was associated with electrostatic adsorption. In summary, the PS-PU materials produced in this study proved to be exceptional adsorbents for treating wastewater that contains different pollutants, including S. aureus, MB, and Cu2+. [ABSTRACT FROM AUTHOR]

Background: The respiratory rehabilitation technique is a crucial component of early cardiac recovery in geriatric patients with acute myocardial infarction (AMI). This study primarily investigated the effectiveness of a novel respiratory rehabilitation technique, metronomic breathing (MB), on geriatric patients after percutaneous coronary intervention for AMI and compliance with home-based rehabilitation compared to traditional respiratory rehabilitation. Methods: From June 2022 to March 2023, 75 acute myocardial infarction (AMI) patients admitted to the Shanghai Tenth People's Hospital Cardiovascular Department were consecutively enrolled. Ultimately, 46 patients completed the follow-up in this study— 26 in the MB group and 20 in the control group—who underwent the novel MB technique and conventional abdominal breathing training. The primary endpoint of the study was left ventricular function measured by noninvasive hemodynamics three months after discharge. The secondary endpoints were compliance and quality of life after three months of home rehabilitation. Results: After the intervention, several cardiac functional parameters (SV, SVI, CO, CI, LCW, and LCWI), myocardial contractility parameters (VI), and systemic vascular resistance parameters (SVR and SVRI) were significantly greater in the MB group than in the preintervention group (P < 0.05). Furthermore, post-treatment, the MB group exhibited greater SV, SVI, CO, CI, and VI; lower SVR, SVRI, and SBP; and a lower readmission rate three months later than did the control group. The SF-36 scores after three months of MB intervention, PE, BP, GH, VT, SF, RE, and MH, were all significantly greater than those before treatment (P < 0.05). Moreover, the MB group displayed greater compliance with home-based cardiac rehabilitation (P < 0.05). Conclusion: Compared to conventional respiratory rehabilitation training methods, short-term metronomic respiratory therapy is more effective for reducing systemic vascular resistance, enhancing left ventricular ejection function, enhancing quality of life, and increasing home-based rehabilitation compliance in geriatric patients following AMI with PCI. [ABSTRACT FROM AUTHOR]

This study aims to compare the methylene blue (MB) removal capacity from aqueous solutions of seven natural Date Palm (Phoenix dactylifera L.) By‐products (DPBPS). These include: Leaflets (DPLL), Rachis of leaf (DPRL), Fruit Bunch Stalk (DPFBS), Empty Fruit Bunch (DPEFB), Leaf Base (DPLB), fibrillium (DPF) and Spathe Sheath (DPSS), obtained from three different date palm cultivars: Degla, Ghers and Takermost from Ouargla Oasis in the Algerian Sahara, and to investigate the influence of the palm date nature part and cultivar on MB adsorption. Batch adsorption experiments were conducted at different concentrations; 30, 45, 60, 75, 90, and 105 mg/L of MB with 2.5 g of DPBP of each cultivar. The DPBPS of all cultivars exhibits remarkable adsorption efficiencies for MB removal. The highest maximal experimental adsorption capacities were observed for Degla DPLB (4.192 mg/g), Ghers DPF (4.191 mg/g) and Takermost DPF (4.193 mg/g) with(99.81 %), (99.79 %), and (99.82 %) adsorption rates in their cultivar respectively. Conversely, the lowest maximal experimental adsorption capacities were found for Degla DPLL 4.048 mg/g, Ghers DPEFB (4.12 mg/g) and Takermost DPSS (4.089 mg/g) with 96.40 %, 98.09 %, and at 97.67 % adsorption rates in each cultivar respectively. The equilibrium adsorption data were analyzed using Langmuir and Freundlich models. The results indicated a good fit with the Freundlich model. The studied DPBPS represent natural, low‐cost, and locally available adsorbents that effectively remove MB from wastewater. [ABSTRACT FROM AUTHOR]

The ability of heterogeneous photocatalysis to effectively remove organic pollutants from wastewater has shown great promise as a tool for environmental remediation. Pure zinc ferrites (ZnFe2O4) and magnesium‐doped zinc ferrites (Mg@ZnFe2O4) with variable percentages of Mg (0.5, 1, 3, 5, 7, and 9 mol%) were synthesized via hydrothermal route and their photocatalytic activity was checked against methylene blue (MB) taken as a model dye. FTIR, XPS, BET, PL, XRD, TEM, and UV‐Vis spectroscopy were used for the identification and morphological characterization of the prepared nanoparticles (NPs) and nanocomposites (NCs). The 7% Mg@ZnFe2O4 NPs demonstrated excellent degradation against MB under sunlight. The 7% Mg@ZnFe2O4 NPs were integrated with diverse contents (10, 50, 30, and 70 wt.%) of S@g‐C3N4 to develop NCs with better activity. When the NCs were tested to degrade MB dye, it was revealed that the 7%Mg@ZnFe2O4/S@g‐C3N4 NCs were more effective at utilizing solar energy than the other NPs and NCs. The synergistic effect of the interface formed between Mg@ZnFe2O4 and S@g‐C3N4 was primarily responsible for the boosted photocatalytic capability of the NCs. The fabricated NCs may function as an effective new photocatalyst to remove organic dyes from wastewater. [ABSTRACT FROM AUTHOR]

Tetragonal ZrO2, synthesized by the sol–gel method and dip-coating technique, was found to be photocatalytically active for the degradation of methylene blue. The ZrO2 thin films were characterized by X-ray diffraction (XRD), Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and UV-vis spectroscopy. The photocatalytic degradation of methylene blue was carried out with this material. We identified the tetragonal phase in ZrO2 thin film at different annealing temperatures from 400 °C to 550 °C. The XRD study indicated that the films were monocrystalline in nature with preferred grain orientation along (011) plane and exhibited a tetragonal crystal structure. The crystallite size of the films increased with increasing annealing temperature. FTIR explained the bonding nature and confirmed the formation of the composite. UV-Vis showed the optical absorbance was high in the visible region and the optical band gap value increased with annealing temperature. The photocatalytic experimental results revealed that ZrO2 thin films degraded MB by 20%, 24%, 29%, and 36%, with annealing temperatures of 400 °C at 550 °C for 10 h, respectively. Our results provide useful insights into the development of photocatalytic materials and degradation of methylene blue. [ABSTRACT FROM AUTHOR]

Preterm and extremely low-birth-weight newborns are at a higher risk for early-onset neonatal sepsis (NN-SP). This condition is often linked to intrapartum fever, PROM, and sepsis occurring within the first day of life. The causal pathogen can be acquired through intrauterine transmission or from the mother’s flora. Therefore, our study aimed to evaluate PC and PI in cases involving NN-SP. Therefore, we can conclude that analyzing the PC and its indices can improve the prognosis of sepsis in NN. Studying NN using this method is a cost-effective approach that helps prevent mortality and morbidity. Early identification of newborn sepsis can help reduce the associated medical tests and medical bills. Clinical correlation with specific indicators and tools is a method for achieving this.

Electrochemical technology is frequently used to treat industrial dye wastewater. However, its degradation efficiency is restricted by pH, and the low current efficiency and high energy consumption limit its broader application. Based on this, we constructed an innovative electro-driven catalytic system by integrating nanotechnology with electric current. This system operates without pH constraints, has low energy consumption, and allows for the recycle and reuse of both electrodes and catalysts. Firstly, we synthesized palladium (Pd) cubes via a solvothermal method, and characterized their morphology, structural composition, and crystalline properties using transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and other methods. The prepared Pd cubes possessed dual catalytic properties of electro-driven catalysis and Fenton catalysis, achieving a synergistic degradation effect under an electric field. Subsequently, the study explored how catalysts dosage, H2O2 concentration, pH and Cl− concentration affect the catalytic rate. The optimized system was able to degrade 99.17 % of MB within 1 h and was effective against various organic pollutants. After five cycles of reuse, the recovered catalysts maintained over 90 % degradation efficiency in decomposing MB. This process realizes efficient degradation with a low concentration of catalysts, offering a novel approach for nanotechnology in wastewater treatment under electro-driven conditions.

Plumage color, a pivotal attribute delineating diverse Muscovy duck strains, assumes considerable significance within the field of Muscovy duck breeding research. This study extends the existing research by delving into the hereditary aspects of genes associated with plumage coloration in Muscovy ducks. The principal objective is to discern marker genes conducive to targeted breeding strategies based on plumage color, thereby furnishing indispensable technical foundations for the development of novel Muscovy duck varieties. Our investigation focused on scrutinizing the impact of MYOT and MB genes on the genetic expression of plumage color at both the RNA and protein levels in Muscovy ducks. The results elucidate that black Muscovy ducks manifest markedly elevated mRNA and protein expression levels of MYOT and MB genes in comparison to their white counterparts, indicating that both genes may play a constructive regulatory role in the context of plumage coloration in Muscovy ducks. The outcomes of this study delineate a discernible correlation between MYOT and MB genes and the plumage coloration in Muscovy ducks. Employing gene expression analysis, we successfully identified candidate genes that may be intricately linked to the determination of plumage color in these ducks.

In the current investigation, functionalization of the multiwalled carbon nanotubes (MWCNTs-TMD) is conducted to enhance the adsorption potential applications. A ratio of 1:3 of the oxidizing acids (HNO3 and H2SO4) is used to attach the oxygen functional groups to the surface of MWCNTs and the prepared sample is F-MWCNT. To examine the surface morphology of the functionalized tubes in the prepared samples, transmission electron microscopy and scanning electron microscopy were utilized. Meanwhile, energy dispersive X-ray, and X-ray diffraction analysis were employed to account for the elemental composition and structure, respectively. The data obtained from these investigations revealed a notable decrease in the length and diameter of the functionalized tubes. The adsorption efficiency of F-MWCNTs was examined by methylene blue removal from aqueous solutions. The results demonstrated that the removal percentage of F-MWCNTs could reach 80%. Functionalized MWCNTs have greater surface area than the pristine one, which improves the efficiency of MWCNTs-based filters for water purification. The functionalization process provides an effective approach to modify MWCNTs and significantly enhances their adsorption efficiency.

Ferroptosis is expected to be a therapeutic target for cancers including pancreatic cancer. We aimed to screen genes that regulate ferroptosis and doxycycline resistance in pancreatic cancer and to explore the underlying mechanisms. Bioinformatics analysis was performed to identify genes that respond to ferroptosis in two human pancreatic cancer cells with GOT1 knocked down or not. 325 and 842 genes were upregulated in MiaPaCa and Tu8902 cells in response to GOT1 knockdown, with 43 genes shared. Among the 43 genes, 14 genes were identified to interact with ferroptosis key genes. MB and HMOX1 were the genes most sensitive to Erastin and doxycycline. Moreover, MB and HMOX1 expression was higher in human normal pancreatic duct epithelial cells than in pancreatic cancer cells. MB and HMOX1 proteins physically bound and promoted each other's expression. By interacting with HMOX1, MB suppressed pancreatic cancer cell proliferation, colony formation and invasion, and promoted cell ferroptosis and sensitivity to erastin and doxycycline. Silencing HMOX1 reversed the promoting effect of MB on cell ferroptosis and sensitivity to doxycycline. A pancreatic cancer xenograft model was established by subcutaneous injection of Panc‐1 cells transfected with or without Ad‐MB, and doxycycline was administered intraperitoneally. Overexpression of MB enhanced the inhibitory effect of doxycycline on xenograft growth. In conclusion, MB facilitated doxycycline sensitivity in pancreatic cancer cells through promoting HMOX1‐mediated ferroptosis. [ABSTRACT FROM AUTHOR]

This study employs a simple and feasible approach for fabricating the porous ZnCo2O4 catalyst with excellent electrochemical activity. We offer insight into the excellent performance of these catalysts by coupling electrochemical measurements with physical characterization methods. These embrace electron microscopy to investigate the morphological structure of the porous catalysts, cyclic voltammetry (CV) to determine the electrochemically active surface area of catalyst materials, linear sweep voltammetry (LSV) to evaluate the oxygen evolution potential (OEP), and electrochemical degradation experiment to assess the degradation performance. ZnCo2O4 porous catalyst exhibits durable stability and high OEP, and provides a large active surface and sufficient numbers of active sites for electrochemical reactions. The ZnCo2O4 porous catalyst can be anticipated as a highly active electrode material for wastewater treatment. This study provides a viable strategy for developing highly active and stable electrode materials on electrochemical applications. [ABSTRACT FROM AUTHOR]

In the present work, SnO2-Fe3O4@MWCNT nanocatalyst was fabricated according to a sonochemical-hydrothermal procedure. The surface morphology and structure analyses of the synthesized SnO2-Fe3O4@MWCNT were investigated by transmission electron microscope (TEM), X-ray diffraction (XRD), Raman spectroscopy, EDS, FTIR and BET analyses. The degradation efficiency of SnO2-Fe3O4@MWCNT nanocatalyst in MB solution was tested by several experimental conditions such as SnO2-Fe3O4@MWCNT dosage (8–20 mg/L), initial MB concentration (20–50 mg/L), initial solution pH (5–9), and ultrasonic output power (37–60 kHz). SnO2-Fe3O4@MWCNT nanocatalyst retained its efficiency as 85% at common experimental conditions of 16 mg/L of SnO2-Fe3O4@MWCNTs, 45 mg/L of MB, pH of 8, H2O2 of 15 mM, and 60 kHz in 60 min under ultrasonic irradiation. In addition, the optimum experiment conditions for SnO2-Fe3O4@MWCNTs in MB degradation were investigated. The experiment result showed that the degradation efficiency of MB was increased by adding H2O2 to the reaction medium due to forming more free radicals. Further, it was detected that OH• radicals were determined to be the dominant oxidative species in MB degradation using SnO2-Fe3O4@MWCNT catalyst. The reuse tests showed that SnO2-Fe3O4@MWCNT sonocatalyst preserved its very stable structure after using the same catalyst 5 times. The intermediates and by-products after MB degradation using the catalyst were indicated by GC–MS analysis. Overall the results showed that the SnO2-Fe3O4@MWCNT sonocatalyst has excellent potential for treating organic pollutants in wastewater. [ABSTRACT FROM AUTHOR]

A comparative study of the complex formation of ethidium bromide (EtBr) and methylene blue (MB) with synthetic single-stranded (ss-) polynucleotides poly(rA) and poly(rU) was conducted. The absorption spectra of these ligands decreased upon interaction with ss-polynucleotides and poly(rA)-poly(rU) formed at their hybridization. In the case of the MB-polynucleotide complexes, the fluorescence intensity decreases, while in the case of EtBr, the fluorescence intensity increases along with the enhancement of concentrations of polynucleotides. Based on the fluorescence spectra analysis of the complexes EtBr with ss- and hybrid ds-polynucleotides, the binding curves in Scatchard coordinates were constructed (r/Cf and r), and the values of the binding parameters of polynucleotides determined, including the binding constant value K and the number of bases n (base pairs at hybridization) per binding site.. [ABSTRACT FROM AUTHOR]

In the current investigation, functionalization of the multiwalled carbon nanotubes (MWCNTs-TMD) is conducted to enhance the adsorption potential applications. A ratio of 1:3 of the oxidizing acids (HNO 3 and H 2 SO 4) is used to attach the oxygen functional groups to the surface of MWCNTs and the prepared sample is F-MWCNT. To examine the surface morphology of the functionalized tubes in the prepared samples, transmission electron microscopy and scanning electron microscopy were utilized. Meanwhile, energy dispersive X-ray, and X-ray diffraction analysis were employed to account for the elemental composition and structure, respectively. The data obtained from these investigations revealed a notable decrease in the length and diameter of the functionalized tubes. The adsorption efficiency of F-MWCNTs was examined by methylene blue removal from aqueous solutions. The results demonstrated that the removal percentage of F-MWCNTs could reach 80%. Functionalized MWCNTs have greater surface area than the pristine one, which improves the efficiency of MWCNTs-based filters for water purification. The functionalization process provides an effective approach to modify MWCNTs and significantly enhances their adsorption efficiency. • F-MWCNTs based-filters were examined for dye removal from water recourses. • The removal percentage of FMWCNTs could reach 80%. • Functionalization significantly enhances the filtration efficiency of MWCNTs. • The internal structures of raw and functionalized MWNTs were demonstrated by TEM images. [ABSTRACT FROM AUTHOR]

This study aims to enhance the photocatalytic activity of graphitic carbon nitride (g-C 3 N 4) for visible light H 2 evolution and pollutant degradation by creating Ni 0.8 Co 0.2 /Zn 0.8 Cd 0.2 S (ZCS)/g-C 3 N 4 (CN) ternary nano-photocatalyst. Ni 0.8 Co 0.2 /ZCS/CN is produced via chemical reduction and hydrothermal methods. The morphology, structural characteristics, and photocatalytic characteristics of the nano-photocatalyst were assessed by FE-SEM, EDS, HR-TEM, BET, XRD, FTIR, UV–Vis DRS, PL, EIS and UV–Vis spectroscopy. Photocatalytic water splitting and degradation of methylene blue (MB, C 16 H 18 N 3 SCl) in an aqueous solution were carried out under an LED lamp (100 W, 400 nm–700 nm) irradiation for 4 and 3 h, respectively. Considering the test results, the H 2 evolution rate of Ni 0.8 Co 0.2 /ZCS/CN was measured at 1980 μmol/g.h, which demonstrates an astonishing 1980-fold increase in comparison with g-C 3 N 4. Additionally, the degradation efficiency of MB equals 85 % within 3 h. The improved catalytic performance of Ni 0.8 Co 0.2 /ZCS/CN is primarily attributed to forming of a heterojunction between Ni 0.8 Co 0.2 /ZCS and g-C 3 N 4 nanosheets, facilitating the separation and migration of photoexcited charge carriers. Consequently, this ternary nano-photocatalyst can be a potential photocatalytic material for H 2 evolution under visible light. This research offers guidelines for developing novel heterojunction catalysts that are highly efficient and environmentally friendly. • Ni 0.8 Co 0.2 /Zn 0.8 Cd 0.2 S/g-C 3 N 4 is produced via chemical reduction and hydrothermal methods. • Photocatalytic water splitting and degradation of MB were carried out under visible light. • Ni 0.8 Co 0.2 /Zn 0.8 Cd 0.2 S/g-C 3 N 4 exhibits a significant enhancement in H 2 evolution and MB degradation compared to g-C 3 N 4. • Ni 0.8 Co 0.2 /Zn 0.8 Cd 0.2 S/g-C 3 N 4 exhibited durability for 16 h. [ABSTRACT FROM AUTHOR]

Objective(s): In this work, silver nanoparticles (Ag NPs) were synthesized by green tea plant extract as an easy, cost-effective, environmentally friendly, and reliable synthesis. The silver nanocomposite with different amounts of starch (0.5, 1, 1.5 g) were prepared. Then, the methylene blue (MB) dye degradation and the antibacterial activity of the nanocomposite were evaluated as an environmental challenge. Methods: The samples were characterized using scanning electron microscope (SEM) for observation size and morphology, energy dispersive X-ray analysis (EDX) for determination elemental analysis, Fourier transform infrared spectroscopy (FTIR) for investigation functional groups, and X-ray diffraction analysis (XRD) for confirmation crystalline structure. The catalytic properties of the synthesized samples were studied in MB degradation. Results: The maximum degradation (more than 90%) was related to Ag NP with 0.5 g of starch. The antibacterial activity of Ag NPs and nanocomposites was investigated against Staphylococcus aureus (S. aureus) as Gram-positive and Pseudomonas aeruginosa (P. aeruginosa) as Gram-negative bacteria. The samples indicated inhibitory activity with suitable inhibition zone and were more effective against S. aureus as compared to P. aeruginosa. Conclusions: In general, the green synthesis of Ag NP-starch has good catalytic potential in MB degradation in an aqueous medium in a short time with high efficiency. [ABSTRACT FROM AUTHOR]

Medulloblastoma (MB) is a frequently occurring malignant brain tumor in children, and many of these tumors are identified by the abnormal activation of the Sonic Hedgehog (SHH) pathway. Although the Shh inhibitor GDC0449 initially shows some effectiveness in certain tumors, they eventually recur due to drug resistance mechanisms, highlighting the need for new treatment options. In this study, we explore whether GDC0449 induces autophagy in the human MB cell lines. To investigate the ultrastructural pathology changes of GDC0449-treated Daoy and D283 cells, we employed Transmission Electron Microscopy (TEM) technology to identify the expression of autophagic vacuoles. Our results indicate that GDC0449 only increases autophagy in Daoy cells by increasing the LC3-II/LC3-I ratio and autophagosome formation.We also analyzed Beclin1, LC3, Bax, and Cleaved-caspase3 protein and mRNA expression levels of autophagic and apoptotic markers using fluorescence confocal microscopy, RT-PCR, and Western blot. We found that cell autophagy and apoptosis increased in a dose-dependent manner with GDC0449 treatment. Additionally, we observed increased mammalian target of rapamycin (mTOR) phosphorylation and decreased protein kinase B (AKT/PKB), Ribosomal Protein S6, eIF4E-binding protein (4EBP1) phosphorylation in GDC0449-treated Daoy cells. It was observed that inhibiting autophagy using Beclin1 siRNA significantly blocked the apoptosis-inducing effects of GDC0449, suggesting that GDC0449 mediates its apoptotic effects by inducing autophagy.Our data suggests that GDC0449 inhibits the growth of human MB Daoy cells by autophagy-mediated apoptosis. The mechanism of GDC0449-induced autophagy in Daoy cells may be related to the inhibition of the PI3K/AKT/mTOR signaling pathway. [ABSTRACT FROM AUTHOR]

In this work, the modification of Bi2MoO6 with critic acid (CA-BMO) to achieve enhanced adsorption of methylene blue (MB) solution in dark and desorption under visible light irradiation was reported. The as-prepared materials were synthesized by a hydrothermal method and characterized via SEM, FT-IR, XRD, and XPS techniques. Only 16.5% of 10 mg L−1 MB was removed within 10 min by using 0.5 g L−1 Bi2MoO6, while 92.9% removal of MB could be achieved by using 0.5 g L−1 CA-BMO, which enhanced the adsorption removal by a factor of 4.6. The adsorption capacity for MB was 18.9 mg g−1. Desorption efficiency of MB was only observed in CA-BMO system, and it depends on the wavelength of the light source, pH, and the presence of metal ions. Characterization results suggested that carboxyl groups, which were modified onto the surface of Bi2MoO6, could serve as adsorption sites for MB, and the connections were damaged under light, thus leading to the desorption of MB from the surface of the CA-BMO. This study provides a novel reagent-free desorption strategy for dye recovery without secondary pollution, which facilitates the development and application of Bi-based adsorbent for dye-containing wastewater treatment. [ABSTRACT FROM AUTHOR]

In this study, zinc oxide (ZnO) and zinc oxide-zirconium dioxide nanocomposites (ZnO@ZrO2) were synthesized by a low-cost solution combustion route to study their structural, morphological, optical, and photocatalytic performance. The properties of synthesized nanocomposites were characterized by x-ray diffraction (XRD), UV–vis absorption spectroscopy, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). Phase formation and purity were confirmed using XRD and EDS. Optical absorption spectra revealed that the addition of ZrO2 significantly affected optical absorption and band gap energy. The band gap energy increased from 3.01 to 3.24 eV with addition of ZrO2 in ZnO. FTIR spectra confirmed the formation of ZnO and ZnO@ZrO2. SEM micrographs showed a significant change in the morphology of the ZrO2 addition in ZnO. BET analysis showed surface area for sample P3 (ZnO@0.4ZrO2) was 28.9 m2/g while for sample P1 (ZnO) was 22.5 m2/g. In addition, the photocatalytic performance of ZnO and ZnO@ZrO2 for the decomposition of methylene blue (MB) dye was studied for all samples exposed to solar light. The effect of different contents of ZrO2 in ZnO@ZrO2 in terms of degradation efficiency and degradation time are described in detail. The sample P3 showed highest photodegradation efficiency of 84.52 % at degradation time of 240 minutes.

An improved photocatalytic activity of Graphitic carbon nitride (CN) photocatalyst was achieved by incorporating Cu2+ into CN in the presence of hyperbranched polyethylene amine (HPEI) as a capping agent. The addition of Cu to CN (CNHPEI+Cu) increased the photocatalytic degradation efficiency of wastewater dye pollutant methylene blue (MB) from 42 % to 95 %. E. coli and MS2 performed best in terms of inactivation to CNHPEI+Cu, achieving 5.5 ± 0.3 and 5.3 ± 0.1 log inactivation after 60 min of exposure, respectively. Excellent catalyst reusability and photocatalytic activity for MB in various types were obtained. To investigate the photocatalyst structure, morphology, optical, and photoelectric properties, we used X-ray diffraction (XRD), UV–Vis diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), X-ray photoelectron spectroscopy (XPS), and photocatalytic activity. It was found through XRD and XPS that the prepared photocatalysts were made up of Cu-doped CN and that the valence state of Cu was Cu0. Under the visible part of the solar spectrum (>400 nm), the N2 adsorption-desorption isotherms of pure CN, CNHPEI, and CNHPEI+Cu showed that copper did not alter the microstructure of pure CN. The photocatalytic activity of CNHPEI+Cu was improved by incorporating Cu0 into CN, as this reduces the rate of electron-hole recombination in pure CN and accelerates the separation of electron-hole pairs. Electron spin resonance (ESR) spin trap experiments on the production of reactive oxygen species (ROS) from CNHPEI+Cu under visible light indicate that the presence of superoxide radicals (O2•−), hydroxyl radicals (•OH) and holes could enhance the photocatalytic activity of the material.

Simple Summary: Medulloblastoma is one of the most common malignant brain tumor types and comprises the molecular groups WNT-MB, SHH-MB TP53-wildtype, SHH-MB TP53-mutant and non-WNT/non-SHH MB. Developmental gene expression data suggest that these molecular groups arise from different sites of origin in the developing brain. Therefore, we hypothesized that intraoperative observation could enable the neurosurgeon to predict the molecular group during surgery and opt for a less aggressive resection in molecular groups with favorable prognosis to preserve neurological function. We reviewed the intraoperative reports, surgical videos and information on the molecular group of 58 patients who were operated at our institution from 1996 to 2020. Our data demonstrate that the correct prediction of the molecular group based on the intraoperatively observed site of origin was limited. Based on our results, we conclude that maximal safe resection should remain the aim of surgery irrespective of the observed site of origin. Developmental gene expression data from medulloblastoma (MB) suggest that WNT-MB originates from the region of the embryonic lower rhombic lip (LRL), whereas SHH-MB and non-WNT/non-SHH MB arise from cerebellar precursor matrix regions. This study aimed to analyze detailed intraoperative data with regard to the site of origin (STO) and compare these findings with the hypothesized regions of origin associated with the molecular group. A review of the institutional database identified 58 out of 72 pediatric patients who were operated for an MB at our department between 1996 and 2020 that had a detailed operative report and a surgical video as well as clinical and genetic classification data available for analysis. The STO was assessed based on intraoperative findings. Using the intraoperatively defined STO, "correct" prediction of molecular groups was feasible in 20% of WNT-MB, 60% of SHH-MB and 71% of non-WNT/non-SHH MB. The positive predictive values of the neurosurgical inspection to detect the molecular group were 0.21 (95% CI 0.08–0.48) for WNT-MB, 0.86 (95% CI 0.49–0.97) for SHH-MB and 0.73 (95% CI 0.57–0.85) for non-WNT/non-SHH MB. The present study demonstrated a limited predictive value of the intraoperatively observed STO for the prediction of the molecular group of MB. [ABSTRACT FROM AUTHOR]

Background: Athletes in combat sports, such as judo, often experience muscle cell damage due to physical and metabolic stress. This study investigates the impact of anaerobic interval exercises involving both upper and lower limbs at different temperatures on physiological indicators. Methods: Fifteen judokas, with an average age of 20.7 ± 2.0 years, participated in the study. They had an average body height of 178 ± 6.3 cm, body mass of 76.3 ± 12.6 kg, VO2max of 43.2 ± 7.8 mL·kg−1, and peak power of 12.1 W·kg−1. The main experiment involved performing five sequences of pulsating exercise on a cycle ergometer for both upper and lower limbs. This was conducted in a thermoclimatic chamber set at temperatures of 21 ± 0.5 °C and 31 ± 0.5 °C with a relative humidity of 50 ± 5%. The sequences alternated pulsations of varying durations and loads between the upper and lower limbs, with a 15 min break following each sequence. Within each sequence, participants underwent four anaerobic limb tests. Biochemical markers, including interleukin-1β (IL-1β), interleukin-6 (IL-6), and heat shock protein 70 (HSP70), were measured using the enzyme-linked immunosorbent assay (ELISA) method before and after exercise, and again at 1, 24, and 48 h post-exercise. Muscle cell damage was evaluated based on lactate dehydrogenase (LDH) activity and myoglobin (Mb) concentration. Results: Both temperature conditions elicited physiological and biochemical responses. Positive correlations were observed between white blood cell count (WBC) and LDH concentration at 21 °C, as well as between WBC and IL-6 at 21 °C. At 31 °C, correlations were seen between WBC and myoglobin, and WBC and LDH. Conclusions: Muscle cell damage was evident under both conditions, as indicated by increased myoglobin levels. These findings offer insights into training strategies and underscore the physiological responses observed in combat sports athletes. [ABSTRACT FROM AUTHOR]

Increasing disruption of water toxicity takes our attention to remove hazardous organic pollutants like p-nitrophenol (PNP) and methylene blue (MB) using a photocatalyst, and for this, simple solvothermal technique was used to create Ce-doped ZnO nanoflowers with various concentration of cerium, calcined at 600 °C for two hours. An effect of different concentration of dopant on structural, morphological, optical, and photocatalytic properties of ZnO with different concentrations of cerium was determined by characterizing the as prepared samples by XRD, UV-DRS, PL spectroscopy, zeta potential, and FE-SEM equipped with (EDS). The flower-like morphology and composition of synthesized samples was confirmed by FE-SEM equipped with EDS. The successful degradation of p-nitrophenol (PNP) and methylene blue (MB) was achieved using cerium doped ZnO as a photocatalyst when compared to the host matrix ZnO under UV radiation. 1% Ce-doped ZnO exhibits higher degradation efficiency as compared to other dopant concentration. This diminished photodegradation was successfully explained using PL, zeta potential, and UV-DRS study. Thus, cerium doping makes ZnO a prospective photocatalyst for removing organic contaminant in water. [ABSTRACT FROM AUTHOR]

Amniotic tissues and methylene blue (MB) provide the ability for neuroregeneration, and MB enables intraoperative neurostaining. We first combined the techniques to explore a neuroprotective effect on early functional outcomes in a retrospective proof-of-concept trial of 14 patients undergoing radical prostatectomy (RP). The patients were followed up at a median of 13 months, and the continence and potency rates were reported. Early recovery of continence was found after three months. No effect on potency was detected. The findings indicate the feasibility of this tissue-engineering strategy, and justify prospective comparative studies. [ABSTRACT FROM AUTHOR]

A 67-year-old man presented with dizziness secondary to ventricular tachycardia (VT) originating from the moderator band. The VT was refractory to multiple antiarrhythmic medications requiring extracorporeal membrane oxygenation and eventual curative ablation. We highlight a malignant form of idiopathic VT, unique electrocardiogram characteristics, and ablation considerations. (Level of Difficulty: Intermediate.).

Biosynthesis of nickel ferrite (NiFe2O4) nanoparticles (NPs) using an aqueous extract of Murraya koenigii (M. koenigii) leaves is a novel, environmentally benign and cost effective method. NiFe2O4 NPs were characterized by different spectroscopic and microscopic techniques, including Ultraviolet–Visible (UV–Vis) spectroscopy, X-ray Diffraction (XRD), Fourier Transform Infrared (FTIR) spectroscopy, Raman spectroscopy, Thermogravimetric Analysis (TGA), Transmission Electron Microscopy (TEM), High-Resolution Scanning Electron Microscopy (HRSEM), Energy-dispersive X-ray spectrometry (EDX) and Vibrating-Sample Magnetometer (VSM). The observed results revealed that prepared NiFe2O4 NPs are highly pure, crystalline, partially spherical with an average size of 2–6 nm and attribute magnetic properties. The magnetization of the obtained biosynthesized nanoparticles is noticed ∼5.2 emu/g at 10 K Oe. The NiFe2O4 NPs exhibited a heterogeneous photo Fenton's catalytic feature in the presence of oxalic acid at ambient conditions. The effects of pH, dosage of NiFe2O4 catalyst and doses of oxalic acid on the degradation efficiency of 10 mg/L MB dye were assessed. The optimal degradation efficiency of ⁓ 98.5% was achieved within 70 min, and the observed results elucidated that the photocatalytic reactions follow first-order chemical kinetics. Thermodynamic parameters such as activation energy (Ea), enthalpy of activation (ΔH‡), entropy of activation (ΔS‡), and free energy of activation (ΔG‡) were evaluated, applying Arrhenius and activated complex theory ascertained the endothermic, less random and nonspontaneous features of photocatalytic process. NiFe2O4 NPs were also tested against different bacteria and found to have antibacterial properties. Hence, magnetic NiFe2O4 NPs can be exploited for its multifunctional applications, and specifically for the remediation of dye-contaminated wastewater.

The development of a photocatalyst production through low cost is still a significant concern for locating target material properties and possibility of mass production. Bismuth vanadate (BiVO4) is a semiconductor and mostly used in photocatalysis due to its photocatalytic efficiency in the visible light range. In this research work, a novel synthesis of the BiVO4 photocatalyst was performed using surfactants through a hydrothermal route. Oxalic acid, cetyltrimethyl ammonium bromide (CTAB), and ammonium fluoride (NH4F) were used as surfactants to maintain crystal orientation, morphology, and greater photocatalytic activity. The synthesized materials were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDX), UV–Visible spectroscopy (UV–Vis), photoluminescence spectroscopy (PL), Fourier transform infrared spectroscopy (FTIR), and photocatalytic activity. The photocatalytic activity of a prepared sample was investigated via destruction of MB, RhB dye and an antibiotic TC under visible light irradiation. Moreover, it was confirmed that by using XRD and SEM characterization the BiVO4/NH4F nanorods exhibited unique morphology and structure. EDX spectroscopy successfully assessed elemental composition of synthesized samples. Optical properties were examined using PL and UV–Visible spectroscopy. The prepared nanorods material degraded almost 77% of MB, 69% of RhB, and 73% of TC in 120 min. The degradation efficiency of BiVO4/NH4F material is increased due to the lower recombination rate and enhanced production of a number of defects and oxygen vacancies. [ABSTRACT FROM AUTHOR]

3D porous graphene nanosponge has broad application prospects in intelligent sensing, wastewater treatment, environmental remediation and other fields. However, the previously reported graphene-based 3D structure sponge column usually has difficulty achieving compression resistance and excellent adsorption effect. In this study, a novel, simple and low-cost sandwich structure is assembled. The carbon fiber/reduced graphene oxide/polydimethylsiloxane (CF/rGO/P) with excellent compression electrical properties is used as the intermediate layer, and the flexible polyvinylidene fluoride/rGO/P (PV/rGO/P) is used as the upper and lower layers. A composite assembled graphene sponge column with outer pressure resistance and middle compression resistance is prepared. Results show that this composite sponge has a small resistance(30–100 Ω/cm). Under 60% compression deformation, the resistance sensitivity could reach 36.44. The physical adsorption of methylene blue (MB) dye has reached more than 93.7% after 24 h, and the electrochemical adsorption rate is 3.12 times faster than the physical adsorption rate. This sandwich assembly structure exhibits an excellent positive synergistic effect, maintaining high adsorption and desorption properties for MB dyes under high compression cycles. It can be applied to the recovery of cationic dyes in the dynamic flow waste liquid, thereby broadening the application of hydrogel graphene nanosponge in the field of environmental protection.

A simple g-C3N4 and CuCl2 composite catalyst (CN@CuCl2) was prepared via direct blending-drying method and compared with ternary heterojunction series catalysts (CN/CuO/Cu2O-x) and g-C3N4 disposed by copper chloride solution (CN/CuCl2). The specific surface area and micropore surface area of g-C3N4 were increased after recombination with copper chloride, and the absorption range and ability of visible light were greatly enhanced, which showed the best photocatalytic activity. The degradation rate constant of high concentration methylene blue was about 2.6 times that of g-C3N4, and the degradation rate reached 59% after 180 min of illumination. This enhanced photocatalytic activity is mainly attributed to the ionic Z-scheme photocatalytic system, which relies on the charge transport of the electron mediator CuCl2 (Cu2+/Cu1+) in the redox reaction to promote the photoexcited e- and h+ separation and migration between g-C3N4 and Cu2O. [ABSTRACT FROM AUTHOR]

Highlights: What are the main findings? Comparison of healthy controls with subtypes of medulloblastoma using FTIR spectra. Analysis of physicochemical changes in FTIR spectrum in medulloblastoma and brain tissue. What is the implication of the main finding? MB and normal brain tissue can be distinguished from one another to some extent using FTIR spectroscopy in the region 800–1800 cm−1. FTIR spectroscopy as a potential method in the diagnostics of medulloblastoma. Introduction: Medulloblastoma (MB) is the most common malignant tumor of the central nervous system in childhood. FTIR spectroscopy provides a holistic view of the chemical composition of biological samples, including the detection of molecules such as nucleic acids, proteins, and lipids. This study evaluated the applicability of FTIR spectroscopy as a potential diagnostic tool for MB. Materials and methods: FTIR spectra of MB samples from 40 children (boys/girls: 31/9; age: median 7.8 years, range 1.5–21.5 years) treated in the Oncology Department of the Children's Memorial Health Institute in Warsaw between 2010 and 2019 were analyzed. The control group consisted of normal brain tissue taken from four children diagnosed with causes other than cancer. Formalin-fixed and paraffin-embedded tissues were sectioned and used for FTIR spectroscopic analysis. The sections were examined in the mid-infrared range (800–3500 cm−1) by ATR-FTIR. Spectra were analysed using a combination of principal component analysis, hierarchical cluster analysis, and absorbance dynamics. Results: FTIR spectra in MB were significantly different from those of normal brain tissue. The most significant differences related to the range of nucleic acids and proteins in the region 800–1800 cm−1. Some major differences were also revealed in the quantification of protein conformations (α-helices, β-sheets, and others) in the amide I band, as well as in the absorbance dynamics in the 1714–1716 cm−1 range (nucleic acids). It was not, however, possible to clearly distinguish between the various histological subtypes of MB using FTIR spectroscopy. Conclusions: MB and normal brain tissue can be distinguished from one another to some extent using FTIR spectroscopy. As a result, it may be used as a further tool to hasten and enhance histological diagnosis. [ABSTRACT FROM AUTHOR]

In this study, a Z-scheme heterojunction CoFe 1.95 Y 0.05 O 4 /Ag/g-C 3 N 4 (CFYO/ACN) magnetic nanocomposite was prepared by hydrothermal synthesis. The composite was characterised and analyzed using different characterization tools and its photocatalytic degradation activity towards methylene blue (MB) was investigated. The results showed that the CFYO/ACN photocatalyst compared to CoFe 1.95 Y 0.05 O 4 (CFYO) and Ag/g-C 3 N 4 (ACN), the composite CFYO/ACN had the highest degradation efficiency of MB, which was up to 97 % within 120 min, which was 1.26 and 1.09 times higher than that of ACN and CFYO, respectively. The enhancement of the catalytic performance of CFYO/ACN was attributed to the fact that the heterogeneous junction formation effectively inhibited the complexation of photogenerated carriers. In addition, five consecutive cyclic degradation experiments showed that CFYO/ACN exhibited efficient photocatalytic degradation, stable crystal structure, and easy recycling in the photodegradation process. Finally, the capture experiments confirmed that superoxide radicals (⋅ O 2 −) and hydroxyl radicals (·OH) play a major role in the degradation process. This study provides an effective strategy for the construction of efficient photocatalysts. • A novel magnetic composite photocatalyst is prepared in this paper. • The CFYO/ACN composite showed high degradation efficiency of MB under light conditions. • Efficient charge separation and cycle stability were demonstrated in the photocatalytic degradation of MB by the composite catalyst. [ABSTRACT FROM AUTHOR]