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In the context of the subsurface pollutant detection using cooperative targets probed by ground penetrating RADAR (GPR), we assess the sampling frequency stability of the instrument as needed to make sure any time delay variation between echoes is associated with subsurface chemical detection and not with instrument drift. Thanks to surface acoustic wave (SAW) transducers designed as GPR cooperative targets, the sampling frequency of the sensors and Software SPIDAR GPR control unit is characterized for short- and long-term sampling rate stabilities. The long-term stability of the instrument is below the phase measurement noise of the SAW cooperative target. However, short-term (within each trace) phase fluctuations are observed, hinting at short-term stroboscopic delay synthesis artifacts. Having demonstrated the stability of the baseline, we demonstrate gas-phase pollutant detection in the subsurface environment using GPR interrogation of a SAW sensor functionalized with a dedicated coating for reacting with hydrogen sulfide. Finally, for onsite long-term monitoring, an embedded vector network analyzer is shown to exhibit sufficient stability and the targeted performance for this measurement by recovering the time-domain response through the inverse Fourier transform of the frequency swept characterization of the sensor. [ABSTRACT FROM AUTHOR]

In the context of direct detection sensors with compact dimensions, we investigate the gravimetric sensitivity of high-overtone bulk acoustic resonators, through modeling of their acoustic characteristics and experiment. The high frequency characterizing such devices is expected to induce a significant effect when the acoustic field boundary conditions are modified by a thin adlayer. Furthermore, the multimode spectral characteristics are considered for wideband acoustic spectroscopy of the adlayer, once the gravimetric sensitivity dependence of the various overtones is established. Finally, means of improving the gravimetric sensitivity by confining the acoustic field in a low acoustic-impedance layer is theoretically established. [ABSTRACT FROM AUTHOR]

Abstract: Among specific sensitive materials synthesized for chemical sensor development, cobalt corrole have shown attractive capabilities for CO detection . In this paper, we investigate the possibility to exploit such materials to develop surface acoustic wave (SAW)-based sensors. We actually demonstrate that SAW devices using delay line configuration allow investigating the molecular recognition occurring in non-conductive sensing layers of cobalt corroles. We have monitored phase variations of SAW devices versus various CO concentrations. Moreover, a specific testing setup has been developed to precisely dose CO at low concentrations, to avoid any CO leakage in the environment, to systematically control environmental parameters and to allow regeneration of the trapping sites of CO. [Copyright &y& Elsevier]

Stroboscopy provides an energy and computationally efficient means of sampling radiofrequency and microwave signals assumed to be reproducible under external excitation. While well known for impulse mode RADAR receivers, we here investigate its use for interrogating surface acoustic wave (SAW) transducers acting as passive cooperative targets. Amongst the originality of the implementation is the need to keep phase coherence between successive pulse generations which last up to tens of the radiofrequency periods to optimally transfer energy to the transducer. A two-chip receiver architecture is demonstrated, with a trigger signal compatible either with single-period avalanche transistor pulse excitation or frequency-agile direct digital synthesizer source. [ABSTRACT FROM AUTHOR]

In this article, we describe a new experimental setup which has been developed to investigate the fatigue behavior of thin metal films on polymer substrates as used in micro-optical components. The setup is based on the ring-on-ring test and includes an optical in situ failure detection system. The method is validated for thin Au films by comparing the in situ results with microscopical analyses using scanning electron and atomic force microscopies. [ABSTRACT FROM AUTHOR]

Deep UV-induced modification of the refractive index of polymers is a useful technique for realizing integrated optical circuits for telecommunication and sensor applications. The combination with replication techniques such as hot embossing opens up a variety of possibilities such as a monolithic integration in optical or fluidic microsystems. In this article the fundamental understanding of the deep UV process is given including examples of fabricated waveguide based devices. [ABSTRACT FROM AUTHOR]

Single-mode waveguides were fabricated by deep ultraviolet radiation in poly(methyl methacrylate) (PMMA). Using a masking process, the radiation modifies the refractive index of the PMMA forming core and cladding regions for waveguiding. Following the fabrication of the waveguides, the small molecule material aluminum tris(8-hydroxyquinoline) doped with the laser dye DCM is deposited directly onto the waveguide structures. By optical pumping (lambda=355 nm) amplified spontaneous emission was observed at the end facets of the waveguides [ABSTRACT FROM PUBLISHER]

Surface acoustic wave (SAW) transducers propagating shear waves are compatible with sensing chemical compounds in a liquid phase. However, if the liquid surrounding the sensor possesses a higher permittivity than the piezoelectric substrate, then the interdigitated electrodes for converting the incoming electromagnetic wave to acoustic waves are susceptible to capacitive short-circuiting, leading to excessive insertion losses. By using high-permittivity lithium tantalate oxide (LTO), we demonstrate chemical sensing in water without the need for dedicated microfluidic packaging. Nevertheless, the gravimetric sensitivity of these package-less transmission Love-mode delay lines remains comparable to that of low-permittivity quartz when appropriately tuning the guiding layer of thin film to confine energy to the surface in a Love mode. We extend the transmission line gravimetric sensitivity measurement to a reflective delay line geometry for passive transducers that can be wirelessly probed. For instance, ground-penetrating radar (GPR) can be used for subsurface sensing, here targeting water pollution detection, operating in the 100-500-MHz range. This center frequency was selected as a tradeoff between penetration depth (lower frequency) and antenna size (smaller at higher frequency). Nonspecific binding of proteins detection is shown in the context of biosensing applications.

The detection of organophosphates, a wide class of pesticides, in water-solution has a huge impact in environmental monitoring. Acoustic transducers are used to design passive wireless sensors for the direct detection of pesticides in water-solution by using tailored polymers as sensitive layers. We demonstrate by combining analytical chemistry tools that organophosphate molecules strongly alter polymer layers widely used in acoustic sensors in the presence of water. This chemical degradation can limit the use of these polymers in detection of organophosphates in water-solution.

Long-term monitoring of organic pollutants in the soil is a major environmental challenge. We propose to meet this issue by the development of a polymer dedicated to selectively react with H 2 S, coating surface acoustic wave transducers designed as passive cooperative targets with the compound, and probing their response using Ground Penetrating RADAR, thus providing the capability to monitor the presence of H 2 S in the subsurface environment. The selectivity is brought by including lead(II) cation in a reticulated polymer matrix which can be deposited as a thin layer on a surface acoustic wave sensor. We demonstrate a signal enhancement mechanism in which water absorption magnifies the signal detection, making the sensor most sensitive to H 2 S in an underground environment saturated with moisture.

The fast and efficient detection of foodborne pathogens is a societal priority, given the large number of food-poisoning outbreaks, and a scientific and technological challenge, given the need to detect as little as 1 viable cell in 25 gr of food. Here, we present the first approach that achieves the above goal, thanks to the use of a micro/nano-technology and the detection capability of acoustic wave sensors. Starting from 1 Salmonella cell in 25 ml of milk, we employ immuno-magnetic beads to capture cells after only 3 h of pre-enrichment and subsequently demonstrate efficient DNA amplification using the Loop Mediated Isothermal Amplification method (LAMP) and acoustic detection in an integrated platform, within an additional ½ h. The demonstrated 4 h sample-to-analysis time comes as a huge improvement to the current need of few days to obtain the same result. In addition, the work presents the first reported Lab-on-Chip platform that comprises an acoustic device as the sensing element, exhibiting impressive analytical features, namely, an acoustic limit of detection of 2 cells/μl or 3 aM of the DNA target and ability to detect in a label-free manner dsDNA amplicons in impure samples. The use of food samples together with the incorporation of the necessary pre-enrichment step and ability for multiple analysis with an internal control, make the proposed methodology highly relevant to real-world applications. Moreover, the work suggests that acoustic wave devices can be used as an attractive alternative to electrochemical sensors in integrated platforms for applications in food safety and the point-of-care diagnostics., (Copyright © 2018. Published by Elsevier B.V.)

Passive wireless transducers are used as sensors, probed by a RADAR system. A simple way to separate the returning signal from the clutter is to delay the response, so that the clutter decays before the echoes are received. This can be achieved by introducing a fixed delay in the sensor design. Acoustic wave transducers are ideally suited as cooperative targets for passive, wireless sensing. The incoming electromagnetic pulse is converted into an acoustic wave, propagated on the sensor substrate surface, and reflected as an electromagnetic echo. According to a known law, the acoustic wave propagation velocity depends on the physical quantity under investigation, which is then measured as an echo delay. Both conversions between electromagnetic and acoustic waves are based on the piezoelectric property of the substrate of which the sensor is made. Investigating underground sensing, we address the problems of using GPR (Ground-Penetrating RADAR) for probing cooperative targets. The GPR is a good candidate for this application because it provides an electromagnetic source and receiver, as well as echo recording tools. Instead of designing dedicated electronics, we choose a commercially available, reliable and rugged instrument. The measurement range depends on parameters like antenna radiation pattern, radio spectrum matching between GPR and the target, antenna-sensor impedance matching and the transfer function of the target. We demonstrate measurements at depths ranging from centimeters to circa 1 m in a sandbox. In our application, clutter rejection requires delays between the emitted pulse and echoes to be longer than in the regular use of the GPR for geophysical measurements. This delay, and the accuracy needed for sensing, challenge the GPR internal time base. In the GPR units we used, the drift turns out to be incompatible with the targeted application. The available documentation of other models and brands suggests that this is a rather general limitation. We solved the problem by replacing the analog ramp generator defining the time base with a fully digital solution, whose time accuracy and stability relies on a quartz oscillator. The resulting stability is acceptable for sub-surface cooperative sensor measurement., Competing Interests: The authors declare no conflict of interest. The founding sponsors had no role in the design of the study; in the collection, analyses or interpretation of data; in the writing of the manuscript; nor in the decision to publish the results.

The development of integrated, fast and affordable platforms for pathogen detection is an emerging area where a multidisciplinary approach is necessary for designing microsystems employing miniaturized devices; these new technologies promise a significant advancement of the current state of analytical testing leading to improved healthcare. In this work, the development of a lab-on-chip microsystem platform for the genetic analysis of Salmonella in milk samples is presented. The heart of the platform is an acoustic detection biochip, integrated with a microfluidic module. This detection platform is combined with a micro-processor, which, alongside with magnetic beads technology and a DNA micro-amplification module, are responsible for performing sample pre-treatment, bacteria lysis, nucleic acid purification and amplification. Automated, multiscale manipulation of fluids in complex microchannel networks is combined with novel sensing principles developed by some of the partners. This system is expected to have a significant impact in food-pathogen detection by providing for the first time an integrated detection test for Salmonella screening in a very short time. Finally, thanks to the low cost and compact technologies involved, the proposed set-up is expected to provide a competitive analytical platform for direct application in field settings.

Detecting chemical species in gas phase has recently received an increasing interest mainly for security control, trying to implement new systems allowing for extended dynamics and reactivity. In this work, an open-loop interrogation strategy is proposed to use radio-frequency acoustic transducers as micro-balances for that purpose. The resulting system is dedicated to the monitoring of chemical compounds in gaseous or liquid-phase state. A 16 Hz standard deviation is demonstrated at 125 MHz, with a working frequency band in the 60 to 133 MHz range, answering the requirements for using Rayleigh- and Love-wave-based delay lines operating with 40-μm acoustic wavelength transducers. Moreover, this electronic setup was used to interrogate a high-overtone bulk acoustic wave resonator (HBAR) microbalance, a new sensor class allowing for multi-mode interrogation for gravimetric measurement improvement. The noise source still limiting the system performance is due to the analog-to-digital converter of the microcontroller, thus leaving open degrees-of-freedom for improving the obtained results by optimizing the voltage reference and board layout. The operation of the system is illustrated using a calibrated galvanic deposition at the surface of Love-wave delay lines to assess theoretical predictions of their gravimetric sensitivity and to compare them with HBAR-based sensor sensitivity.