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The popularity of using phase change materials (PCMs) for heat storage and recovery of metal hydrides’ reaction has grown tremendously. However, a fundamental study of the coupling of such a system with a low-temperature PEM (polymer electrolyte membrane) fuel cell is still lacking. This work presents a numerical investigation of the dehydrogenation performance of a metal hydride reactor (MHR)-PCM system coupled with a fuel cell. It is shown that to supply the fuel cell with a constant H2 flow rate, the PCM properties need to be in an optimized range. The effects of some design parameters (PCM freezing point, the initial desorption temperature, the nature and the size of the PCM) on the dehydrogenation performance of MHR-PCM system are discussed in detail. The results showed that the MHR-PCM could supply hydrogen at 12 NL/min only for 20 min maximum due to the significant endothermic effect occurring in the MHR. However, reducing the requested H2 flowrate to 5.5 NL/min, the hydrogen desorption to a fuel cell is prolonged to 79 min. Moreover, this system can accommodate different PCMs such as paraffin and salt hydrates for comparable performance. This study demonstrates the ability of MHR-PCM systems to be used as range extenders in light-duty fuel cell vehicles.

Two-tank metal hydride pairs have gained tremendous interest in thermal energy storage systems for concentrating solar power plants or industrial waste heat recovery. Generally, the system’s performance depends on selecting and matching the metal hydride pairs and the thermal management adopted. In this study, the 2D mathematical modeling used to investigate the heat storage system’s performance under different thermal management techniques, including active and passive heat transfer techniques, is analyzed and discussed in detail. The change in the energy storage density, the specific power output, and the energy storage efficiency is studied under different heat transfer measures applied to the two tanks. The results showed that there is a trade-off between the energy storage density and the energy storage efficiency. The adoption of active heat transfer enhancement (convective heat transfer enhancement) leads to a high energy storage density of 670 MJ m−3 (close to the maximum theoretical value of 755.3 MJ m−3). In contrast, the energy storage efficiency decreases dramatically due to the increase in the pumping power. On the other hand, passive heat transfer techniques using the bed’s thermal conductivity enhancers provide a balance between the energy storage density (578 MJ m−3) and the energy efficiency (74%). The utilization of phase change material as an internal heat recovery medium leads to a further reduction in the heat storage performance indicators (142 MJ m−3 and 49%). Nevertheless, such a system combining thermochemical and latent heat storage, if properly optimized, can be promising for thermal energy storage applications.

The integration of thermal energy storage systems (TES) in waste-heat recovery applications shows great potential for energy efficiency improvement. In this study, a 2D mathematical model is formulated to analyze the performance of a two-tank thermochemical heat storage system using metal hydrides pair (Mg2Ni/LaNi5), for high-temperature waste heat recovery. Moreover, the system integrates a phase change material (PCM) to store and restore the heat of reaction of LaNi5. The effects of key properties of the PCM on the dynamics of the heat storage system were analyzed. Then, the TES was optimized using a genetic algorithm-based multi-objective optimization tool (NSGA-II), to maximize the power density, the energy density and storage efficiency simultaneously. The results indicate that the melting point Tm and the effective thermal conductivity of the PCM greatly affect the energy storage density and power output. For the range of melting point Tm = 30–50 °C used in this study, it was shown that a PCM with Tm = 47–49 °C leads to a maximum heat storage performance. Indeed, at that melting point narrow range, the thermodynamic driving force of reaction between metal hydrides during the heat charging and discharging processes is almost equal. The increase in the effective thermal conductivity by the addition of graphite brings about a tradeoff between increasing power output and decreasing the energy storage density. Finally, the hysteresis behavior (the difference between the melting and freezing point) only negatively impacts energy storage and power density during the heat discharging process by up to 9%. This study paves the way for the selection of PCMs for such combined thermochemical-latent heat storage systems.

Heat storage systems based on two-tank thermochemical heat storage are gaining momentum for their utilization in solar power plants or industrial waste heat recovery since they can efficiently store heat for future usage. However, their performance is generally limited by reactor configuration, design, and optimization on the one hand and most importantly on the selection of appropriate thermochemical materials. Metal hydrides, although at the early stage of research and development (in heat storage applications), can offer several advantages over other thermochemical materials (salt hydrates, metal hydroxides, oxide, and carbonates) such as high energy storage density and power density. This study presents a system that combines latent heat and thermochemical heat storage based on two-tank metal hydrides. The systems consist of two metal hydrides tanks coupled and equipped with a phase change material (PCM) jacket. During the heat charging process, the high-temperature metal hydride (HTMH) desorbs hydrogen, which is stored in the low-temperature metal hydride (LTMH). In the meantime, the heat generated from hydrogen absorption in the LTMH tank is stored as latent heat in a phase change material (PCM) jacket surrounding the LTMH tank, to be reused during the heat discharging. A 2D axis-symmetric mathematical model was developed to investigate the heat and mass transfer phenomena inside the beds and the PCM jacket. The effects of the thermo-physical properties of the PCM and the PCM jacket size on the performance indicators (energy density, power output, and energy recovery efficiency) of the heat storage system are analyzed and discussed. The results showed that the PCM melting point, the latent heat of fusion, the density and the thermal conductivity had significant impacts on these performance indicators.

Abstract: Metal hydride represents a promising candidate for hydrogen storage, because the technique is essentially safe, compact and flexible. However, the properties of the metal hydride tend to change in repeated hydriding/dehydriding cycles, which will inevitably affect the performance of corresponding hydrogen storage system. The effect is investigated in this paper by numerical simulation using a commercial package COMSOL MULTIPHYSICS 3.5a, and a typical material- LaNi5 is chosen for discussion. Through sensitivity analysis, the influences of variation in key properties over repeated cycles on the charging time of a tank-type storage system, are evaluated and some useful conclusions are drawn. [Copyright &y& Elsevier]