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The ground water-source heat pump system for the plant factory lacks a scientific operation strategy to solve the problem of high energy consumption in winter and summer. It is very difficult and uneconomical to change the operation conditions by experimental means to obtain actual operation data. The current study aims to build a TRNSYS simulation model of the ground water-source heat pump system of Shanghai Chongming Natural Light Plant Factory. For the heating season, the simulation of energy consumption was 2315 GJ. Compared with the actual energy consumption, the relative error is -0.98%, which indicates that the simulation results are accurate and the simulation model developed is appropriate and usable. Numerical simulations for the whole year on this basis yielded that the plant factory energy supply system operates from November to March with a heating energy consumption of 3530.84 GJ and from June to September with a cooling energy consumption of 1126.24 GJ. In most cases, the indoor temperature fluctuates within a reasonable range, but in the summer high-temperature season, the plant factory temperature will reach above 40℃, which seriously affects plant growth. After optimization, the plant factory stops production in July and August, and the system stops running, the results are that the optimized system can save 56% of the annual cooling energy consumption, totalling 767.48 GJ, which can reduce the costs by 160,318.05 RMB.

Photothermal therapy (PTT) agents possess the capability to absorb light and transform it into heat, providing a promising approach for inhibiting and eradicating tumor cells. Therefore, there is a significant interest in developing novel PTT agents with superior biocompatibility and photothermal conversion efficiency. Herein, Ag2S/g-C3N4 nanoparticles (NPs) with exceptional near-infrared absorption performance were successfully synthesized using a hydrothermal method. The photothermal conversion efficiency of Ag2S/g-C3N4 NPs reached 31.28% under 808 nm laser irradiation, surpassing that of most reported PTT agents. The simultaneous application of an 808 nm laser resulted in a significant augmentation of reactive oxygen species (ROS) generation, including ·O2– and ·OH, which, in turn, triggered apoptosis and the death of tumor cells via photodynamic therapy (PDT). The efficacy of tumor elimination was confirmed through cellular and animal experiments, demonstrating the synergistic effectiveness of PTT and PDT. Importantly, no tumor regrowth was observed for 30 days after synergistic treatment. These results highlight the potential of combining photodynamic and photothermal therapies in nanomaterials for effective tumor therapy, offering a novel approach to tumor catalytic-photothermal therapy utilizing nanomaterials. [ABSTRACT FROM AUTHOR]

Dairy slurry could be a significant source of nitrogen (N) for plants, but mismanagement can lead to atmospheric ammonia losses or nitrate leaching into groundwater. To make the use of dairy slurry efficient and reasonable, the loss of N pollution to the environment should be reduced. We used repacked lysimeters to comprehensively determine ammonia emission and N leaching losses in an alfalfa–soil system. The application of dairy slurry had no significant effect on alfalfa yield at the same rate of N application in comparison to chemical fertilizer, and adding humic acids significantly increased yield by about 12%. However, the application of dairy slurry increased the ammonia emission rate significantly, leading to an increase in the cumulative amount of ammonia emission, while the addition of humic acids reduced the ammonia emissions by 11%. Chemical fertilizer and dairy slurry application significantly increased nitrate leaching compared to the control treatment, while the addition of humic acids can significantly reduce ammonium N leaching. Dairy slurry was proven to be as effective as chemical N fertilizer in achieving the optimum biomass, and adding humic acids can significantly reduce N loss to the atmosphere and groundwater. This study showed the possibility of replacing chemical fertilizer with dairy slurry in alfalfa production and the advantages of humic acids' addition to alfalfa to maintain production yield and improve environmental friendliness. [ABSTRACT FROM AUTHOR]

Baculoviridae, a virus family characterized by a single large double stranded DNA, encompasses the majority of viral bioinsecticides, representing a highly promising and environmentally friendly pesticide approach to insect control. This study focuses on the characterization of a baculovirus isolated from larvae of Calliteara abietis (Erebidae, Lymantriidae) collected in Mongolian pinaceae forests. This new isolate was called Calliteara abietis nucleopolyhedrovirus (CaabNPV). CaabNPV exhibits an irregular polyhedron shape, and significant variation in the diameter of its occlusion bodies (OBs) was observed. Nucleotide distance calculations confirmed CaabNPV as a novel baculovirus. The CaabNPV genome spans 177,161 bp with a G+C content of 45.12% and harbors 150 potential open reading frames (ORFs), including 38 core genes. A comprehensive genomic analysis categorizes CaabNPV within Group II alphabaculovirus, revealing a close phylogenetic relationship with Alphabaculovirus orleucostigmae (OrleNPV). Additionally, repeat sequence analysis identified three highly repetitive sequences consisting of 112 bp repeat units, known as homologous regions (hrs). This research contributes valuable insights into CaabNPV's phylogenetic placement, genomic structure, and its potential applications in insect biocontrol. [ABSTRACT FROM AUTHOR]

In this paper, a novel amino-functionalized Fe3O4-MnO2-SiO2-NH2 adsorbent material was prepared by successive modifying Fe3O4 with KMnO4 and SiO2 to remove heavy metal ions in mixed solution of Pb(II), Cu(II), and Ni(II). The adsorption experiments showed that initial pH value had a significant effect on the adsorption capacity of the materials for heavy metals in solution. Moreover, the materials exhibited strong selective adsorption for Pb(II). Transmission electron microscopy (TEM) results showed that the innermost dark center was the Fe3O4 core with a thickness of about 200 nm, and the outermost light circle was a coated SiO2 shell with a thickness of about 30 nm, while MnO2 can be seen between the dark center and the light circle. Various factors affecting the uptake behavior such as contact time, temperature, pH, and initial concentration of Pb(II) were investigated. The kinetics were evaluated utilizing the Lagergren pseudo-first-order and pseudo-second-order models. The best interpretation for the equilibrium data was given by Freundlich isotherm. The recycling experiment showed that Fe3O4-MnO2-SiO2-NH2 kept its adsorption and desorption efficiencies constant over 5 cycles. Importantly, the Fe3O4-MnO2-SiO2-NH2 was able to selectively remove over 73% of Pb(II) not only in mixed solution of Pb(II), Cu(II), and Ni(II) but also remove 94.7% in only Pb(II) solution at pH 6 within 1 h. [ABSTRACT FROM AUTHOR]

The treatment of wastewater is a complicated biological reaction process. Reliable effluent prediction is critical in the scientific management of water treatment plants. This research proposes a soft sensor design strategy to address the issues above, Multi-Verse Optimizer (MVO)-based random vector functional link network (MVO-RVFL). The proposed approach is utilized to anticipate real-time effluent data obtained from the Benchmark Simulation Model 1 (BSM1). The results of the experiments demonstrate that the MVO methodology can successfully find the optimum input-hidden weights and hidden biases of the RVFL model while outperforming the original RVFL and other typical machine learning approaches in all types of influent datasets. In the situation of significant water quality variations, the use of the fusion process for model development was also investigated. The experimental results demonstrate that incorporating prior knowledge can effectively improve the model's ability to cope with unexpected situations. [ABSTRACT FROM AUTHOR]

Metallic molybdenum sulfide (1T-MoS2) is considered as the most promising electrocatalyst for the acidic hydrogen evolution reaction (HER). Nevertheless, exploring a facile and effective approach for achieving high-purity 1T-MoS2 is still full of challenges. Herein, we demonstrate a two-dimensional material-assisted confined synthetic strategy, as an available method to construct and stabilize 1T-MoS2. During the hydrothermal process, the interaction between the N source and MoS2 is largely enhanced in a two-dimensional confined reactor, formed by reduced graphene oxides, successfully obtaining a high concentration of 90.1% of 1T-MoS2, named N-MoS2/rGO. The optimal N-MoS2/rGO nanosheets require a low overpotential (130 mV) to reach a current density of 10 mA·cm–2 and a low Tafel slope of 46.5 mV·dec–1. Additionally, they also exhibit high stability for at least 12 h in an acidic electrolyte maintaining 84.2% of the 1T-MoS2 phase. This work opens up an avenue to construct two-dimensional metastable materials for advanced catalysis. [ABSTRACT FROM AUTHOR]

Main observation and conclusion: Ethanol is considered a better fuel than methanol in direct alcohol fuel cells because of the high energy density and low toxicity. Compared with noble metal catalysts, nickel‐based catalysts are much cheaper in price. However, present nickel‐based catalysts still surfer from some disadvantages such as low activity and high overpotential. In this paper, we show a new and high efficient nickel‐ based catalyst for ethanol oxidation. A layer of anodized nickel passivation film (Ni‐APF) was formed on the surface of nickel sheet by anodic oxidation method with carbon dots (CDs) as co‐catalyst. At the current density of 110 mA·cm−2, the potential for Ni‐APF/CDs was only 0.541 V (vs. Ag/AgCl), which was 18.8% lower than that of Ni‐APF. Low overpotential could reduce electrode thermal loss and increase output energy. Ni‐APF/CDs showed 144.4 mA∙cm−2 peak current density at peak potential 0.662 V (vs. Ag/AgCl), which was 31% higher than that of Ni‐APF (110.3 mA∙cm−2). In this system, CDs mainly function in the increase of charge‐transfer capacity and the promotion oxidation of carbonaceous intermediates. [ABSTRACT FROM AUTHOR]

Three technologies including carbon decomposition, seed decomposition and their combination are used for spent aluminum air battery electrolyte decomposition, and the particle size of aluminum hydroxide after decomposed phase, poor differential thermal weight change and surface morphology were analysized. The results show that the aluminum hydroxide produced by the carbon decomposition process has a large particle size and coarse particles and cannot be used as a flame retardant; The particle size and morphology of aluminum hydroxide prepared by the combined process of seed decomposition and seed decomposition and carbon separation meet the requirements of flame retardant aluminum hydroxide. In the preparation of aluminum hydroxide by the combination decomposition of seed and carbon, the decomposition rate was more than 90%, which was much higher than that of the seed and carbon separation process. [ABSTRACT FROM AUTHOR]

Wireless body area network includes some tiny wearable sensors for monitoring the physiological data of user, which has been a promising method of promoting the quality and efficiency greatly in healthcare. The collected physical signs are aggregated into the medical documents and uploaded to cloud server for utilizing by the remote user. As these files are highly sensitive privacy data, there is a vital challenge that constructs a secure and efficient communication architecture in this application scenario. Based on this standpoint, we present a lightweight verifiability ciphertext-policy attribute-based encryption protocol with outsourced decryption in this article. Specifically, our construction enjoys the following six features: (1) Although the outsourced decryption enables to save the computation overhead of the data user sharply in an attribute-based encryption scheme, the ciphertext is out of control and the correctness cannot be guaranteed by the data owner. The proposal provides the verifiability of ciphertext that ensures the user to check the correctness efficiently. (2) The size of the ciphertext is constant that is not increased with the complexity of attribute and access structure. (3) For Internet of Things devices, it introduces the fog computing into our protocol for the purpose of low latency and relation interactions, which has virtually saved the bandwidth. (4) With the help of blockchain technique, we encapsulate the hash value of public parameter, original and transformed ciphertext and transformed key into a block, so that the tamper-resistance is facilitated against an adversary from inside and outside the system. (5) In the standard model, we prove that it is selectively chosen-plaintext attack-secure and verifiable provided that the computational bilinear Diffie–Hellman assumption holds. (6) It implements this protocol and shows the result of performance measurement, which indicates a significant reduction on communication and computation costs burden on every entity in wireless body area network. [ABSTRACT FROM AUTHOR]

Extremely low content of Ruthenium (Ru) nanoparticles were loaded on the carbon black (Ru/C) via reducing Ru ions with silicon monoxide. The obtained Ru/C nanocomposites exhibit an exciting electrochemical catalytic activity for hydrogen evolution reaction (HER) in the oxygen-free 0.5 M H 2 SO 4 medium. The optical one (Ru/C-2) with a low Ru amount of 2.34% shows higher activity than previously reported Ru-based catalysts. The overpotential at 10 mA cm−2 is 114 mV and the Tafel slope is 67 mV·dec−1. Ru/C-2 catalyst also has good stability. The overpotential that afford the current density of 10 mA cm−2 of 20 wt% Pt/C increased 92 mV while that of Ru/C-2 only increased 50 mV after a 30,000 s chronopotentiometry test. Furthermore, the mass activity of Ru/C-2 catalyst is even better than that of the commercial 20 wt% Pt/C when the overpotential is larger than 0.18 V. This silicon monoxide-mediated strategy may open a new way for the fabrication of high performance electrocatalysts. Extremely low content of Ruthenium nanoparticles are loaded on carbon black (Ru/C) via reducing Ru ions with silicon monoxide. The obtained Ru/C nanocomposites exhibit an exciting electrochemical catalytic activity for hydrogen evolution reaction with low onset overpotential and Tafel slope, high mass activity and good stability. Image 1 • Ru nanoparticles are loaded on carbon black via reducing Ru3+ with Si H bonds. • Ru/C-2 catalyst has an extremely low metal content of 2.43%. • The Tafel slope is 67 mV·dec−1 when Ru/C-2 is employed as a HER catalyst. • The mass activity is larger than 20 wt% Pt/C when the overpotential exceeds 0.18 V. [ABSTRACT FROM AUTHOR]

An AgCl/Ag 3 PO 4 composite has been successfully fabricated by a simple desorption–precipitation method. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible spectroscopy (UV/Vis), and photoluminescence (PL) have been used to study the structural and physicochemical characteristics of the AgCl/Ag 3 PO 4 composite. The photocatalytic activity of the AgCl/Ag 3 PO 4 composite has been tested by the degradation of parabens under visible-light irradiation. 100% of MPB was degraded within 40 min in the AgCl/Ag 3 PO 4 -visible light system. Moreover, the photocatalytic activity of AgCl/Ag 3 PO 4 remained at 94% of the original level after five runs, which was much higher than that of pure Ag 3 PO 4 (25%). The obtained results confirmed that the AgCl/Ag 3 PO 4 composite exhibited significantly higher photocatalytic performance and improved stability compared with bare Ag 3 PO 4 . The enhanced photocatalytic performance of the AgCl/Ag 3 PO 4 composite could be mainly attributed to highly efficient charge separation through a synergistic effect of AgCl, Ag 3 PO 4 , and in situ photo-reduced Ag nanoparticles. Trapping experiments confirmed h + and ·O 2 − to be the two main active species in the photocatalytic process. Finally, a possible photocatalytic mechanism for the charge-transfer process is proposed to account for the enhanced photocatalytic performance of the AgCl/Ag 3 PO 4 composite. [ABSTRACT FROM AUTHOR]

Thisstudy investigated how a natural sphalerite (NS) photocatalyst,under visible light irradiation, supports photocatalytic bacterialinactivation. This was done by comparing parent E.coliBW25113, and its two isogenic single-gene knock-outmutants, E. coliJW0797-1 (dps–mutant) and JW1721-1 (katE–mutant), where both dpsand KatEgenes are likely related to H2O2production. NS could inactivate approximately 5-, 7- and 7-log of E. coliBW25113, JW0797-1, and JW1721-1 within 6h irradiation, respectively. The two isogenic mutants were more susceptibleto photocatalysis than the parental strain because of their lack ofa defense system against H2O2oxidative stress.The ability of in situresultant H2O2to serve as a defense against photocatalytic inactivationwas also confirmed using scavenging experiments and partition systemexperiments. Studying catalase activity further revealed that in situH2O2played an important rolein these inactivation processes. The destruction of bacterial cellsfrom the cell envelope to the intracellular components was also observedusing field emission-scanning electron microscopy. Moreover, FT-IRwas used to monitor bacterial cell decomposition, key functional groupevolution, and bacterial cell structures. This is the first studyto investigate the photocatalytic inactivation mechanism of E. coliusing single-gene deletion mutants undervisible light irradiation. [ABSTRACT FROM AUTHOR]