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Treatment of recalcitrant and xenobiotic pharmaceutical compounds in polluted waters have gained significant attention of the environmental scientists. Antibiotics are diffused into the environment widely owing to their high usages, very particularly in the last two years due to over consumption during covid 19 pandemic worldwide. Quinolones are very effective antibiotics, but do not get completely metabolized due to which they pose severe health hazards if discharged without proper treatment. The commonly reported treatment methods for quinolones are adsorption and advanced oxidation methods. In both the treatment methods, metal organic frameworks (MOF) have been proved to be promising materials used as stand-alone or combined technique. Many composite MOF materials synthesized from renewable, natural, and harmless materials by eco-friendly techniques have been reported to be effective in the treatment of quinolones. In the present article, special focus is given on the abatement of norfloxacin and ofloxacin contaminated wastewater using MOFs by adsorption, oxidation/ozonation, photocatalytic degradation, electro-fenton methods, etc. However, integration of adsorption with any advanced oxidation methods was found to be best remediation technique. Of various MOFs reported by several researchers, the MIL-101(Cr)–SO 3 H composite was able to give 99% removal of norfloxacin by adsorption. The MIL – 88A(Fe) composite and Fe LDH carbon felt cathode were reported to yield 100% degradation of ofloxacin by photo-Fenton and electro-fenton methods respectively. The synthesis methods and mechanism of action of MOFs towards the treatment of norfloxacin and ofloxacin as reported by several investigation reports are also presented. [Display omitted] • Applications of metal organic framework for removal of pharmaceutical components are discussed. • Toxicological properties of norfloxacin and ofloxacin are presented. • Action mechanisms of MOFs in treatment of quinolones are explained. • Future scope and existing research gaps are identified. [ABSTRACT FROM AUTHOR]

Electro deionization using microbial communities has been proven as a competent method for desalination and abatement of water pollution by removing ionic chemicals from the target waters. Microbial Desalination Cell (MDC) facilitates microbial deionization which can either support or be a substitute for the conventional desalination methods. Generation of electricity is accomplished by the bio electrochemical oxidation of organic compounds present as contaminants in wastewater which in turn attribute to the migration of ions in MDC system. The present review aims to elucidate the theory, principles and the application of microbial desalination cell and microbial fuel cell (MFC) in treatment of saline and wastewaters. Air cathode MDC and stacked MDC for purification of saline water are found to give promising results. Air pump assisted microbial desalination cell reported 150.39 ppm h−1 of salt removal with an operational time period of 80 h and showed consistent results. Hence the air cathode assisted MDC showed dominant capacity of salt removal compared to stacked MDC. Also, three major types of microbial fuel cell, namely photosynthetic biofilm MFC, constructive wetland MFC and ceramic membrane supported MFC are reviewed for their potentials in wastewater treatment by deionization method and electricity generation. Complete (100%) removal of chemical oxygen demand was reported by photosynthetic microbial fuel cell operated for 16 days having 435.8 Ω of external resistance. When constructive wetland microbial fuel cell was operated for 10 days with 1000 ohms of external resistance, it exhibited complete (100%) removal of chemical oxygen demand from the wastewater. About 92% of chemical oxygen demand removal was demonstrated by ceramic membrane supported microbial fuel. Compared to ceramic membrane microbial fuel cell, photosynthetic and constructive wetland microbial fuel cell displayed better performance in terms of pollutant removal capacity and economical factor. Ability of the electrogenic species, namely Geobacter, Shewanella, Clostridium and Bacillus and the photosynthetic species, namely Chorella Vulgaris Rhodopsuedomonas, and Scenedesmus abundans in microbial deionization methods and their performance levels reported by several researchers are presented. [ABSTRACT FROM AUTHOR]

Graphene is a high surface area special carbon compound with exceptional biological, electronic and mechanical properties. Graphene-based materials are potential components used in water treatment on different modes and processes. Ibuprofen and ciprofloxacin are two commonly found pharmaceutical contaminants discharged into water bodies from industrial, domestic and hospital sources. Their concentration levels in water bodies are reported in the range of 1 μg/L to 6.5 mg/L and 0.050–100 μg/L respectively. Their toxic effects pose very high risk to the inhabiting organisms. Their ability to resist biodegradation and capacity to bioaccumulate makes the conventional methods less effective in removal. In the present article, treatment of these compounds via three methods, adsorption, photocatalytic degradation and electro–fenton reactions using graphene-based materials along with the methods adopted for synthesis and treatment are reviewed. The uptakes obtained by graphene-derived adsorbents are presented along with the optimal operating conditions. Studies reported complete removal of ibuprofen from wastewater was achieved at 7 pH for 60 min using graphene membrane as adsorbent and uptake of 99% of ciprofloxacin was exhibited for graphene nanoplates/boron nitrate aerogel at a pH of 7 and 60 min. The reduced graphene oxide surface exhibits higher affinity to light adsorption which leads to the formation of photo generated electrons. The future perspectives for improved applications of graphene-based materials and the research gap currently existing are highlighted. [Display omitted] • Applications of graphene based materials for removal of pharmaceutical components are reviewed. • Mechanism of ibuprofen and ciprofloxacin removal is described. • Toxicological properties are discussed. • Photocatalytic degradation of ibuprofen and ciprofloxacin is described. [ABSTRACT FROM AUTHOR]

The excessive and unorganised utilisation of pesticides have posed negative impacts on soil and water at higher levels. Pesticides are a major class of persistent organic compounds with high resistance to natural biodegradation and enhanced tendency to bio accumulate. The severe health hazards imposed on the living organisms hinder the ecosystem and lead to chronic and irreversible health issues. Photocatalytic method is reported as a potential alternative with a variety of techniques and materials that are safer, easier, durable, cost-effective and efficient. Nanomaterials play a key role in this domain due to their versatility. In particular, nanostructured materials of organized shapes and morphological properties have gained enormous attention in research and real-time applications. Specifically, nanomaterials like nanotubes, nanorods and nanowires have unique properties and anisotropic structure that make them more suitable for treating pesticide wastes with photocatalysis. Variety of tuning methods and materials are emerging to enhance the activity of titanium and zinc based nanocatalysts in remediation methods. In the present article, four pesticides, namely, atrazine, chlorpyrifos, paraquat and naphthalene are chosen due to their common occurrence and usage in agricultural applications. These pesticides are highly toxic and need special attention to explore appropriate remediation methods. The report also details the latest innovations reported by several research studies in exploring the potential of specially synthesised nanoparticles for photocatalytic removal of pesticide pollutants from environment. For zinc-based hybrid nanomaterials, the maximum disintegration reported were 99%, 98%, 73.3% and 92.3% for atrazine, chlorpyrifos, paraquat and naphthalene, respectively. [Display omitted] • Photocatalytic remediation technologies for pesticide pollutants are discussed. • Removal of atrazine, chlorpyrifos, paraquat and naphthalene are described. • Mechanism of photocatalytic degradation and the pathways are elaborated. • Existing research gaps and future perspectives are explained. [ABSTRACT FROM AUTHOR]

Membrane based filtration is one of the promising technologies for rehabilitation of wastewater streams for reuse and recycle. Many advancements have emerged with the use of novel materials and innovative integrated technologies. The present investigation focuses on the treatment methods based on submerged and stages systems of membranes for water purification. Ceramic, polymeric and mixed matrix type of membranes fabricated for specific type of effluents, their modification methods for accelerating the rejection efficiency, permeability, durability, stability and antifouling properties are detailed in this review. Graphene oxide is the most considered membrane material for adsorption purposes as it exhibits larger surface area, abundant functional groups contain oxygen and has good supply of ligands which is responsible in metal adsorption as it enhances electrostatic interaction by bonding metal ions with graphene oxide nanosheets. Energy derivation in terms of biogas production was also reported in some integrated methods. In many cases, embedded nanomaterial matrices yielded maximum efficiencies in both the submerged and staged operations. However, submerged type of membranes are reported more than the staged type due to simpler configuration with relatively lesser equipment, operational and maintenance issues. In treatment of a low strength wastewater, aluminum oxide based membrane in fluidized bed assembly was reported to yield promising results with reduced power requirement. [Display omitted] • Comprehensive review on novel membrane system application for removal of pollutants is presented. • Applications of submerged and staged membrane systems for wastewater treatment are discussed. • Removal performance using embedded nano materials is explained. • Bottlenecks and future perspectives on membrane research are presented. [ABSTRACT FROM AUTHOR]

Uranium, a radionuclide, is a predominant element utilized for speciality requirements in industrial applications, as fuels and catalyst. The radioactive properties and chemical toxicity of uranium causes a major threat to the ecosystem. The hazards associated with Uranium pollution includes the cancer in bones, liver, and lungs. The toxicological properties of Uranium are discussed in detail. Although there are many methods to eliminate those hazards, this research work is aimed to describe the application of bioremediation methods. Bioremediation methods involve elimination of the hazards of uranium, by transforming into low oxidation form using natural microbes and plants. This study deeply elucidates the methods as bioleaching, biosorption, bioreduction and phytoremediation. Bioleaching process involves bio-oxidation of tetravalent uranium when it gets in contact with acidophilic metal bacterial complex to obtain leach liquor. In biosorption, chitin/chitosan derived sorbents act as chelators and binds with uranium by electrostatic attraction. Bio reduction employs a bacterial transformation into enzymes which immobilize and reduce uranium. Phytoremediation includes phytoextraction and phytotranslocation of uranium through xylems from soil to roots and shoots of plants. The highest uranium removal and uptake reported using the different methods are listed as follows: bioleaching (100% uranium recovery), biosorption (167 g kg−1 uranium uptake), bioreduction (98.9% uranium recovery), and phytoremediation (49,639 mg kg−1 uranium uptake). Among all the techniques mentioned above, bioleaching has been proved to be the most efficient for uranium remediation. • Bioremediation methods for removal and recovery of uranium are discussed. • Toxicological properties and effects of uranium on human and other living organisms are presented. • Mechanisms of uranium removal by bioremediation are elaborated. • Future perspectives of uranium removal methods are presented. [ABSTRACT FROM AUTHOR]

Bioremediation of heavy metals has become a major environmental concern due to their bio resistant nature and tendency to accumulate. Application of various technologies, involving physical and chemical working principles are applied and passive uptake using sorption involving eco-friendly substrates gained significant attention. Biochar, a cheaper and efficient material, offers good potential due to the greater ease of production, treatment and disposal. This review focuses on the effective application of biochar to treat water contaminated by three specific heavy metals: chromium, lead and arsenic. The on-field applications like soil amendment, industrial wastewater treatment and groundwater treatment using biochar are highlighted. The review article describes the feedstock available for biochar production, various production processes and the importance of optimum conditions like pyrolysis temperature, rate and retention time for various feedstocks reported in literature. The energy requirement of the production process can be supplied by its own energy output. Various modifications that are suitable for the biochar from distinct feedstocks are also discussed. The removal performance of biochar at different working conditions like pH, initial concentration of pollutant and adsorbent dose are consolidated. The highest removal efficiencies reported were by coconut shell biochar (Cr – 99.9%), canola straw biochar (Pb – 100%) and perilla leaf biochar (As – 100%). The adsorption mechanism is explained with reference to kinetics, isotherms, and molecular dynamics. Adsorption mechanism of most of the biochars was found to fit either Freundlich or Langmuir isotherm. [Display omitted] • Comprehensive review on biochar application for removal of chromium, lead and arsenic is discussed. • Different methods used for biochar modification are discussed. • Removal performance of biochar at different working conditions are consolidated. • Kinetic, isotherm and molecular dynamic models are reviewed. [ABSTRACT FROM AUTHOR]