24 results on '"PHOTOCATALYSIS"'
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2. Chapter 18: Photobiohybrid Solar Conversion with Metalloenzymes and Photosynthetic Reaction Centers
- Author
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Ciesielski, Peter
- Published
- 2016
- Full Text
- View/download PDF
3. 2D Materials and Van der Waals Heterostructures. Physics and Applications.
- Author
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Bartolomeo, Antonio and Bartolomeo, Antonio
- Subjects
Technology: general issues ,2D materials ,CVD ,CdS/g-C3N4 ,Indium Selenide ,Layer-dependent ,MOS (Metal Oxide Semiconductor) capacitor ,MXene ,PMMA ,Raman mapping ,Schottky barrier ,Stone-Wales defected graphene ,Ti3C2Tx ,WS2 ,ZnO/WS2 ,ZnO/WSe2 ,adsorption energy ,and magnetic property ,copper vanadate ,density functional theory ,density of states ,diode ,electronic properties ,electronic structure ,field effect transistors ,first principles calculations ,fluorescence emission ,graphene ,graphene oxide ,graphene/MoS2 heterostructure ,half-metallocene ,heterojunction ,hybrid density functional ,large-area ,light-harvesting performance ,mechanical behaviors ,optical properties ,palladium selenide monolayer ,photoanode ,photocatalysis ,photocatalytic properties ,photodetection ,photodetector ,photovoltaics ,physical properties ,responsivity ,sensitivity ,strain-tunable ,surface plasmon resonance ,transition metal dichalcogenide ,transition metal dichalcogenides ,tungsten diselenide ,type-II heterostructure ,van der Waals heterostructure ,water splitting ,work function - Abstract
Summary: The advent of graphene and, more recently, two-dimensional materials has opened new perspectives in electronics, optoelectronics, energy harvesting, and sensing applications. This book, based on a Special Issue published in Nanomaterials - MDPI covers experimental, simulation, and theoretical research on 2D materials and their van der Waals heterojunctions. The emphasis is the physical properties and the applications of 2D materials in state-of-the-art sensors and electronic or optoelectronic devices.
4. Water Treatment with New Nanomaterials.
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Homaeigohar, Shahin and Homaeigohar, Shahin
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History of engineering & technology ,2,4-D ,LED ,adsorption ,anodization ,bench scale column extraction ,biomass activated carbon ,biomolecules ,buoyant catalyst ,carbon ,carbon magnetic iron oxide particles ,column kinetics ,ecotoxicology ,environmental risks ,membrane ,mesh ,methyl orange ,mineralization ,nanoadsorbents ,nanocatalysts ,nanocomposite fibers ,nanofiber ,nanohybrids ,nanomaterial ,nanomaterial applications ,nanomaterial challenges ,nanomaterials ,nanomembranes ,nanosorbents ,organic pollutants ,photocatalysis ,pulse electrodeposition ,selenium removal ,semi-passive ,urease ,waste water treatment ,wastewater purification ,water remediation ,water treatment ,zero valent iron nanoparticles - Abstract
Summary: Given that the threat of water shortage is expanding across the globe, the evolution of advanced technologies that enable water purification and, thus, water re-use in an energy and resource efficient manner are of great importance. In this regard, nanomaterials have been playing a crucial role and offering new opportunities for the construction of permeable and selective membranes and adsorbents. Such features are of paramount importance, particularly given the limited available energy resources. In this book, several recent studies are introduced that deal with water treatment via nanomaterial-based technologies. Such state-of-the-art technologies have employed nanomaterials that are made of polymer, composite, ceramic, and carbon, etc., and are shaped in various dimensionalities and forms such as particle (0D), fiber (1D), and film (2D-3D). The nanostructured membranes and adsorbents as well as photocatalytic nanosystems capable of active photodecomposition of organic pollutants, e.g., dyes, are the main focal points of discussion.
5. Urban and Industrial Wastewater Disinfection and Decontamination by Advanced Oxidation Processes (AOPs) Current Issues and Future Trends.
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Giannakis, Stefanos, Giannakis, Stefanos, Lado Ribeiro, Ana Rita, and Rodríguez-Chueca, Jorge
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Technology: general issues ,E.coli inactivation ,TiO2 ,UV-LED ,advanced oxidation ,advanced oxidation process ,antibiotics ,biological contaminants ,chemical oxygen demand ,circular economy ,computer-based learning ,cytotoxicity ,elimination routes ,emerging pollutants ,flower-like Bi2WO6 ,fresh urine ,graphene oxide ,heterogeneous photocatalysis ,hexacyanoferrate ,hydrothermal method ,kinetic modeling ,membrane technology ,micropollutants ,mining ,n/a ,pharmaceutical degradation ,photocatalysis ,photoreactor design ,pollution ,processes selectivity ,reactive oxygen species (ROS) ,removal efficiency ,slurry reactor ,solar disinfection ,solar photocatalysis ,substances recovery ,sustainable development goals ,theoretical analysis ,tin oxide ,titanium dioxide ,ultrasound ,wastewater ,wastewater reuse ,water contaminants ,water pollution ,water treatment ,zero energy ,zero waste - Abstract
Summary: The papers selected for publication in the Special Issue "Urban and industrial wastewater disinfection and decontamination by Advanced Oxidation Processes (AOPs): current issues and future trends" and published in this book, include topics related with (waste)water treatment and its reuse, disinfection, and pollutant degradation, advancing the know-how of the topics or assessing their integration into the new age of the circular economy of water. Likewise, aspects such as modeling of degradation processes and new materials synthesis were published, aiming to improve, optimize and predict the efficacy of the existing or the novel treatment processes. Moreover, pilot plant operation and large-scale processes were featured, assessing the feasibility of these new treatment methods in real world applications. Overall, the Special Issue and this book present innovative solutions on the field of water and wastewater treatment, with a view on the future technologies that will form the next advances of the field.
6. Synthesis, Characterization and Applications of Sustainable Advanced Nanomaterials.
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Dippong, Thomas and Dippong, Thomas
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Computer science ,Information technology industries ,17β-hydroxyandrost-4-en-3-one ,Au TOH NPs ,CDs ,CFRP ,CO2 separation ,CuCrO2-CeO2 ,SERS ,Ti-13Zr-13Nb alloy ,WO3 nanostructures ,acidic environment ,advanced metal oxide nanoparticles ,air permeability ,anisotropy ,anodization ,anodizing ,antimicrobial activity ,bioaccumulation ,biomaterials ,biotribology ,carbon nanotubes ,catalyst ,ceramic pigments ,chromite ,coloring properties ,composite materials ,copper ions ,core-shell rubber nanoparticles ,corrosion resistance ,critical behavior ,crystal structure ,crystallography ,delafossite ,detergent ,didecyldimethylammonium chloride ,divalent metal doping ,electrospinning ,energy conversion ,epitaxial thin films ,epoxy ,ester ,fluorescent ,fracture toughness ,genes ,glass transition temperature ,hydrogen production ,iridium dioxide ,lattice energy ,magnetic behavior ,magnetic properties ,magnetocaloric effect ,magnetoresistance ,manganites ,materials archeometry ,mechanical properties ,medical masks ,medieval coins ,metal-organic frameworks ,methanol ,nanomaterials ,nanoparticle ,nanoparticle perovskites ,nanosensors ,nickel ferrite ,optical properties ,orthodontic cements ,oxide nanotubes ,pH sensing ,perovskite manganite ,phase transition ,photocatalysis ,photocatalyst ,photocatalysts ,plasmonic properties of metals ,plasmonics ,poly(3-octylthiophene-2,5-diyl) ,porous carbon ,probe ,proteins ,residuals ,selenium nanoparticles ,semiconductors ,silver concentration ,smart nanostructures and nanodevices for virus detection ,solid-contact electrodes ,solubility ,spinel ,spirulina ,surface area ,surface roughness ,sustainability ,sustainable processes ,synthesis ,tensile properties ,testosterone ,washing ,zeta potential - Abstract
Summary: This Special Issue highlights the last decade's progress regarding new nanostructured materials. In this regard, the development of nanoscale syntheses and innovative characterization tools resulted in the tailored design of nanostructured materials with versatile abilities in many applications were investigated. Various types of engineered nanostructures, usually metal nanoparticles or nanoporous metal oxides, have been synthesized for various applications. This Special Issue covers the state-of-the-art of advanced nanoparticles in many disciplines (chemistry, pharmacy, nano-medicine, agriculture, catalysis, and environmental science). The Special Issue entitled, Synthesis, Characterization and Application of Sustainable Advanced Nanomaterials, including 18 original research works, focuses on highlighting the progress, challenges, and future directions in the area of the synthesis and characterization of nanomaterials and nanostructures with multiple applications in chemistry, physics, biology, and medicine [1-3].
7. Sustainable Construction Materials: From Paste to Concrete.
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Jeong, Yeonung and Jeong, Yeonung
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History of engineering & technology ,Materials science ,Technology: general issues ,CO2 uptake ,CaO-activation ,GGBFS ,ISO22197-1 ,LC3 ,Portland cement ,Rhodobacter capsulatus ,UHPC ,X-ray diffraction ,active carbon ,alkali-activated materials ,alternative additives ,alternative cementitious binders ,alternative water resources ,amorphous metallic fiber ,anatase TiO2 ,architectural injection grout ,autogenous shrinkage ,auxiliary activator ,belite-rich Portland cement ,bottom ash ,calcium silicate hydrate ,calorimetry ,carbon dioxide ,carbonation ,carbonation curing ,cement composite ,cement paste ,chemical resistance ,circular economy ,clinker binder and aggregate ,cold-bonded pelletization ,compressive strength ,concrete ,constitutive relations ,construction and demolition waste ,construction materials ,construction waste materials ,cover depth ,crack healing ,curing ,damage mechanics ,dry hydrated lime ,drying shrinkage ,ductility concrete ,durability ,embodied carbon ,fiber reinforced polymer ,filler effect ,fine aggregate ,fine recycled aggregate ,finite element analysis ,flexural performance ,flexural strength ,foam composite ,freezing ,heavy metal leaching ,high-strength ,hydration products ,hydration reaction ,industrial waste management ,internal curing ,limestone ,low-velocity impact load ,materials design ,materials properties ,mechanical properties ,metakaolin ,micropore volume ,microstructure ,mortar ,nano-silica ,nitrogen oxides (NOx) ,no-slump ,nuclear magnetic resonance ,particle density ,phase assemblage ,photocatalysis ,pollution ,pore structure ,porosity ,pozzolanic activity ,recycled aggregate ,recycled aggregate concrete ,recycled asphalt ,recycled concrete aggregate ,recycled masonry aggregate ,recycling ,residues ,self-healing of cracks ,service life ,setting time ,sewage concrete ,silica fume ,specific surface area ,strength ,strengthening methods ,sulfate ion ,superabsorbent polymer ,supplementary cementitious materials ,surface coating ,sustainable concrete ,sustainable construction materials ,sustainable development ,sustainable ultra-high-performance paste ,thawing ,thermodynamic modeling ,thermogravimetry ,titanium dioxide (TiO2) ,titanium dioxide nanotube ,two-way slab ,ultra-high-performance concrete ,ultrasonic measurements ,wastewater ,water flow test ,workability - Abstract
Summary: With increasing attention on the reduction of CO2 emissions, the sustainability of construction materials has become one of the most growing issues in concrete science and engineering research fields. New sustainable construction materials, such as alkali-activated materials, calcium sulfoaluminate (CSA) cement, and limestone calcined clay cement (LC3), have been suggested and high-performance and/or highly durable construction materials using special admixtures, such as nanomaterials, have been studied to reduce the environmental impact during the life cycle of construction materials.This Special Issue aims to highlight and share recent findings in developing new sustainable cementitious materials, modeling their hydration kinetics, investigating their microstructure, improving the performance and durability of cementitious materials using functional supplementary ingredients, suggesting novel test methods for new construction materials, etc. In this Special Issue are presented the following areas:Sustainable concrete and alternative binders;Hydration kinetics of sustainable cementitious materials;Characterization of sustainable cementitious materials;Re-utilization of industrial by-products for construction materials;High strength and durable cementitious materials;Property enhancement by functional additives;Energy storage through construction materials.
8. Obtaining and Characterization of New Materials.
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Sandu, Andrei Victor and Sandu, Andrei Victor
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History of engineering & technology ,ATR-FTIR ,CTGS ,LGS ,Mg-Ca-Y alloys ,Micro-XRF ,OM ,RuAl ,SAW sensors ,SEM-EDX ,Sn whisker ,Sn-0.7Cu-0.05Ni ,Thermogravimetry-Differential Thermal Analysis (TG-DTA) ,TiAl ,TiO2 nanoparticles ,XRD ,ZnO ,acid-base character ,acoustic materials ,activation energy ,ageing ,analysis ,annealing ,bactericidal effect ,cardiology ,caustic module ,cementitious composites ,central composite design ,ceramics ,chitosan ,clothing system ,collagen ,composite solder ,cutting ,decomposition ,dolomite/fly ash ,e-beam ,electrical discharge machining with contact breaking ,electrochemical evaluation ,epidemiology ,failure ,fly ash ,geopolymer ,geopolymer ceramic ,geopolymers ,high temperature stability ,high-temperature stability ,implant ,in vitro test ,interconnects ,interdigital transducer material ,intermetallics ,lead-free solder ,lead-free solder geopolymer ,metal band ,microstructure ,mitigation ,multi-layer thermal inserts ,n/a ,neurosurgery ,objective functions ,obstetrics/gynecology ,optical constants ,orthopedics ,osteosynthesis ,parchment ,pediatric surgery ,pediatrics ,phase formation ,photocatalysis ,process modeling ,pulmonology ,reliability ,retrieval ,segregation ,sheep wool recovery ,soldering ,sound absorption coefficient ,state of conservation ,strength development ,surface acoustic waves ,temperature exposure ,textile materials ,thermal behavior ,thermal insulation ,thermal manikin ,thin films ,water treatment ,whisker growth - Abstract
Summary: At present, more and more procedures and technologies used to discover and characterize new materials are available, including advanced characterization techniques.This Special Issue covers a wide range of topics about obtaining and characterizing new materials, from the nano to macro scales, including for new alloys, ceramics, composites, biomaterials, and polymers and the procedures and technologies used to enhance their structure, properties, and functions. To select new materials for future use, we must first understand their structure and their characteristics using modern techniques such as microscopy (SEM, TEM, AFM, STM, etc.), spectroscopy (EDX, XRD, XRF, FTIR, XPS, etc.), and mechanical tests (tensile, hardness, elastic modulus, toughness, etc.) and their behaviors (in vitro and in vivo; corrosion; and thermal-DSC, STA, DMA, magnetic properties, and biocompatibility), among many others.
9. New Trends in Photo(Electro)catalysis. From Wastewater Treatment to Energy Production.
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Palmas, Simonetta and Palmas, Simonetta
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Biology, life sciences ,Research & information: general ,AOPs ,Anodic oxidation ,Au nanoparticles ,CO2 ,Composite catalysts ,Cu-B alloy ,H2 generation ,H2 production ,Ni-Co catalyst ,TiO2 nanostructures ,TiO2 photocatalysts ,UV irradiation ,UVA ,ZnFe2O4 ,advanced oxidation processes ,amoxicillin ,ampicillin ,azo dye ,bisphenol A oxidation ,cathode ,cation distribution ,composite ,crystal size ,degree of inversion ,diamond electrodes ,electricity production ,environmental engineering ,ethanol ,facet effect ,graphitic carbon nitride ,hydrogen evolution ,hydrogen evolution reaction ,in situ deposition ,light trapping ,magnetron sputtering ,mechanical mixture ,metal and non-metal doping ,metal sulfides ,microbial fuel cell ,n/a ,nanoclusters ,niobium ,non-precious metal catalysts ,optical properties ,oxygen electrode ,photocatalysis ,photocatalyst ,photocatalytic activity ,photocatalytic oxidation ,photocatalytic reduction ,photoelectrocatalysis ,photoelectrochemical activity ,polymethylmethacrylate ,porous nickel ,renewable energy sources ,selective corrosion ,silver(II) oxide ,solar energy ,solar fuel ,surface modification ,sustainable resources ,synergy effect ,tetracycline ,titanium dioxide ,titanium dioxide (TiO2) film ,ultrasounds ,visible light ,wastewater remediation ,water reuse ,water splitting ,water treatment ,zinc oxide - Abstract
Summary: This reprint focuses on new trends in photo-electrocatalysis, specifically addressed to the remediation of wastewater and energy production. The remediation of wastewater, up to a level that is acceptable for discharge into receiving waterbodies, involves an ever-growing demand of energy, so effective and low-energy treatment processes are highly desirable. Among the other treatments, photo- and photo-electrochemical treatment processes may be considered as advanced oxidation processes (AOP), which are based on the generation of OH radicals, strong oxidizing agents able to indiscriminately degrade even the most persistent organic compounds. Photocatalysis and photo-electrocatalysis can be considered as effective methods for organic degradation, especially when the semiconductor is active in the range of visible light. Several results are presented on new morphologies and structures, which allow more photoactive, visibly responsive, and stable materials, as well as studies on combined processes in which photo- or photo-electrochemistry contribute to an increase in the sustainability of the whole process, lowering costs and achieving the most valuable final products. In view of the circular economy concept, microbial fuel cell systems are also considered as possible way to recover energy from organic pollutants contained in wastewater.
10. New Trends in Catalysis for Sustainable CO2 Conversion.
- Author
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Ereña Loizaga, Javier, Ateka, Ainara, and Ereña Loizaga, Javier
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Environmental science, engineering & technology ,History of engineering & technology ,Technology: general issues ,CO2 conversion ,CO2 decomposition ,CO2 hydrogenation ,CO2 methanation ,CO2 reduction ,CO2 utilization ,CO2-Fischer-Tropsch (CO2-FT) ,CO2-H2O photo-co-processing ,Fischer-Tropsch synthesis ,Ni-xSi/ZrO2 ,SAPO-34 ,Si promotion ,SrFeO3−x ,VIS-light driven reactions ,bifunctional composite catalysts ,biomass ,carbon allotropes ,carbon dioxide ,carbon dioxide electrolysis ,carbon nano-onions ,carbon nanofibers ,carbon nanotubes ,carbon-TiO2 ,carbon-supported iron catalyst ,catalyst ,catalyst deactivation ,climate change ,copper nanoparticles ,cycloaddition ,deep eutectic solvents ,dehydrogenation ,diesel ,electrochemical reduction of CO2 ,fixed-bed reactor ,gas hourly space velocity (GHSV) ,gasoline ,greenhouse gas ,greenhouse gas mitigation ,heterogeneous catalysis ,homogeneous catalysts ,hydrocarbons ,hydrogenation ,imidazolium cation ,ionic liquid ,ionic liquids ,iron oxide ,iron-based catalysts ,light olefins ,methane ,methanol to olefins ,molten carbonate ,n/a ,nano-catalyst ,nanocarbon ,onium salt ,oxidation ,oxygen vacancies ,photocatalysis ,photocatalysts properties ,propylene carbonate ,soft oxidant - Abstract
Summary: This Special Issue on "New Trends in Catalysis for Sustainable CO2 Conversion", released in the Catalysts open access journal, shows new research about the development of catalysts and catalytic routes for CO2 valorization, in addition to the optimization of the reaction conditions for the process. This issue includes ten articles and three reviews about different innovative processes for CO2 conversion.Carbon capture and storage (CCS) is a physical process consisting of the separation the CO2 (emitted by industry and the combustion processes for energy generation) and its transportation to geological storage isolates it from the atmosphere in the long term. However, the most promising routes for CO2 mitigation are those pursuing its catalytic valorization. By applying specific catalysts and suitable operating conditions, CO2 molecules react with other components to form longer chains (i.e., hydrocarbons). Accordingly, effort should be made to catalytically valorize CO2 (alone or co-fed with syngas) as an alternative way of reducing greenhouse gas emissions and obtaining high-value fuels and chemicals. Carbon capture and utilization (CCU) is a developing field with significant demand for research in the following aspects:The development of new catalysts, catalytic routes, and technologies for CO2 conversion;The study of new processes for obtaining fuels and chemicals from CO2;Optimization of the catalysts and the reaction conditions for these processes;Further steps in advanced processes using CO2-rich feeds (H2+CO2 or CO2 mixed with syngas), increasing product yields.
11. Nanostructured Materials for Energy Storage and Conversion.
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Pasquini, Luca and Pasquini, Luca
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Physics ,Research & information: general ,3D electrode materials ,CO2 reduction ,CuCrO2 nanoparticles ,EIS ,Li-ion batteries ,SnO2 ,TiO2 ,aluminum ion batteries ,anode ,anodes ,azo dye ,black silicon ,catalyst ,chalcopyrite compounds ,co-precipitation synthesis ,coating ,cobalt ,composites ,conductivity ,dry etching ,green synthesis ,heterogeneous catalysis ,high-rate ,hole transport layer ,hydrocarbon ,hydrothermal ,intermetallics ,iron ,light stability ,lithium-ion batteries ,mechanical properties ,mechanochemistry ,n/a ,nanoalloy ,nanoarray ,nanocrystals ,nanomaterials ,nanoparticle ,nanoparticles ,perovskite solar cell ,photocatalysis ,photovoltaics ,pilot plant ,plasmonics ,reduced graphene oxide ,scaling up ,silicon ,single molecule localization ,sodium formate ,solvent recycling ,spin coating ,super-resolution microscopy ,surface-enhanced Raman spectroscopy ,synthetic fuel ,thermal stability ,tin dioxide ,wastewater treatment ,wurtzite ,zinc sulfide - Abstract
Summary: The conversion and storage of renewable energy sources is key to the transition from a fossil-fuel-based economy to a low-carbon society. Many new game-changing materials have already impacted our lives and contributed to a reduction in carbon dioxide emissions, such as high-efficiency photovoltaic cells, blue light-emitting diodes, and cathodes for Li-ion batteries. However, new breakthroughs in materials science and technology are required to boost the clean energy transition. All success stories in materials science are built upon a tailored control of the interconnected processes that take place at the nanoscale, such as charge excitation, charge transport and recombination, ionic diffusion, intercalation, and the interfacial transfer of matter and charge. Nanostructured materials, thanks to their ultra-small building blocks and the high interface-to-volume ratio, offer a rich toolbox to scientists that aspire to improve the energy conversion efficiency or the power and energy density of a material. Furthermore, new phenomena arise in nanoparticles, such as surface plasmon resonance, superparamegntism, and exciton confinement. The ten articles published in this Special Issue showcase the different applications of nanomaterials in the field of energy storage and conversion, including electrodes for Li-ion batteries and beyond, photovoltaic materials, pyroelectric energy harvesting, and (photo)catalytic processes.
12. Molecular Catalysts for CO2 Fixation/Reduction.
- Author
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Ishida, Hitoshi, Ishida, Hitoshi, Iwasawa, Nobuharu, Machan, Charles, and Robert, Marc
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Science: general issues ,CO2 fixation ,CO2 reduction ,artificial photosynthesis ,electrocatalysis ,photocatalysis - Abstract
Summary: Society is currently confronted with the continuing environmental problems of global warming and ocean acidification related to increasing CO2 emission from anthropogenic sources. These environmental issues are also connected to the inevitable energy supply shortage due to the eventual depletion of fossil fuel sources. As a solution, the technology of recycling CO2 into useful organic materials continues to attract attention. This methodology can be categorized into two main parts: CO2 fixation and CO2 reduction. For both reactions, molecular catalysts based on transition metal coordination complexes and organometallic compounds have been developed and examined. Molecular catalysts can be characterized and iteratively improved at the molecular level through spectroscopic experiments and the isolation of intermediate species, which is particularly advantageous in comparison to heterogeneous catalysts. The fixation of CO2 into organic compounds to form a carbon-carbon bond by using organometallic catalysts is a direct methodology for CO2 utilization and represents the potential reversible storage of electrochemical energy in chemical bonds. The resultant carboxylic acid-containing compounds formed as the initial products can be subsequently converted into other organic materials, even products with new chiral centers. The reduction of CO2 by two electrons (often with a proton donor as a co-substrate) yields carbon monoxide (CO) and formic acid (HCOOH), which can be further converted to useful chemicals. Reduction reactions involving more than two electrons and two protons can produce formaldehyde (HCHO), methanol (CH3OH), and methane (CH4), which are also desirable as chemicals and fuels. For molecular electrocatalysts, more negative potentials than the equilibrium ones for CO2 reduction are generally required; the difficulty is that the equilibrium potentials for CO2 reduction are generally negative of the equilibrium potential for proton reduction to produce H2, representing a competing thermodynamically favored process. A complementary approach to an electrochemical one is to mediate CO2 reduction with photo-induced electron transfer reactions. Photo- and electrocatalytic CO2 reduction can be used to achieve artificial photosynthesis, or the production of commodity chemicals and fuels with renewable energy inputs originating from solar sources. This Research Topic covers the molecular catalysts based on coordination and organometallic compounds for CO2 fixation/reduction. It includes chemical, electrochemical, and photochemical reactions. It also covers systematic studies of reaction mechanisms and the spectroscopic characterization of catalytic intermediates. Molecular catalysts for CO2 fixation/reduction used as co-catalysts with heterogeneous catalytic systems are also included. Non-precious and abundant transition metal catalysts for CO2 fixation/reduction are important for future industrial applications as core components of the next generation of energy technologies.
13. Metallic or Metallic Oxide (Photo)catalysts for Environmental Applications.
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Hermans, Sophie, Hermans, Sophie, and Mahy, Julien
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Environmental science, engineering & technology ,History of engineering & technology ,Technology: general issues ,AgNWs ,BiOX ,FDCA ,Fe/N doping ,LED visible light ,Pb(II) ,SnO2 ,TiO2 ,ZnO ,advanced oxidation processes ,aqueous sol-gel process ,atomic layer deposition ,bimetallic nanoparticles ,carbon ,carboxylation ,catalysis ,cellobiose ,core-shell nanostructures ,decolorization and disinfection of water ,defect-engineered TiO2 ,doping N ,furoic acid ,gas-liquid flow ,glucose ,gold catalysts ,heterogeneous catalysis ,hydrogenation ,hydrolysis ,hydrothermal resistance ,mannitol ,mesoporous silica ,metal nanoparticles ,metallic oxide nanoparticles ,methylene blue ,n/a ,oxidation ,photocatalysis ,photocatalytic activity ,photocatalytic-oxidation ,pollutant degradation ,rhodamine B ,ruthenium ,selectivity modulation ,silver nanowires ,soft template ,sol-gel method ,solar light ,sorbitol ,structure-directing agent ,titania ,titania coatings ,visible light ,visible-light photocatalysis - Abstract
Summary: This reprint is the compilation of the articles submitted in the Special Issue entitled "Metallic or Metallic Oxide (Photo)catalysts for Environmental Applications" from the journal Catalysts, which gives an overview of the latest advances in the development of metallic or metallic oxide (photo)catalytic materials, with environmental applications for the elimination of organic pollutants or the valorization of biomass.
14. Materials and Processes for Photocatalytic and (Photo)Electrocatalytic Removal of Bio-Refractory Pollutants and Emerging Contaminants from Waters.
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Vacca, Annalisa and Vacca, Annalisa
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Chemical engineering ,Technology: general issues ,Au-TiO2 ,FT-ICR/MS ,GFN-xTB ,Kendrick plot ,TiO2 ,TiO2 nanotubes ,active glass ,advanced oxidation process ,antibiotics ,charge separation ,chloride ions ,chlorpyrifos ,crude oil ,cyclodextrins ,defluorination ,diethyl phthalate ,electro-oxidation ,emergent contaminants ,emerging contaminant ,g-C3N4 ,gold ,heterojunction ,ibuprofen ,n/a ,nanocatalyst ,nanoparticles ,perfluorooctanoic acid ,persistent organic pollutants ,phenol ,photocatalysis ,photodegradation ,photoelectrochemical degradation ,platinum ,pollution ,remediation ,response surface methodology ,solvothermal method ,sonolysis ,sonophotocatalysis ,strontium carbonate (SrCO3) ,van Krevelen diagram ,visible light ,wastewater treatment ,water - Abstract
Summary: Water pollution from biorefractory pollutants and emerging contaminants is still a very relevant problem worldwide. Examples of these pollutants include disinfection by-products, pharmaceutical and personal care products, persistent organic chemicals, as well as their degradation products. The occurrence of these contaminants in water has raised increasing concern due to their accumulation and persistence in the environment and the threat they pose to the ecological system and human health. In this Special Issue, papers regarding the advancements in materials and processes for use in the electro- and photoelectrochemical removal of different pollutants from water are collected. The synthesis, characterization and application of materials for use in electrochemical or photoelectrochemical techniques are presented, as well as studies concerning catalytic processes and reaction kinetics.
15. Luminescence Nanomaterials and Applications.
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Chen, Wei, Cao, Derong, and Chen, Wei
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Chemistry ,Physical chemistry ,Research & information: general ,A3 reaction ,Ag ,Bi2O2CO3 ,Fenton reaction ,GSH depletion ,MoS2 nanosheet ,PDT ,RE-doped ,UCL ,UCNPs ,Zn3Ga2GeO8:Mn phosphors ,ZnO ,afterglow ,air-water interface ,alkaline phosphatase ,anti-counterfeiting ,anti-counterfeiting application ,antibacterial activity ,ascorbic acid ,bio-detection ,bio-imaging ,carbon dots ,carboxymethylcellulose ,cell viability ,copper catalyst ,cytotoxicity ,dip catalyst ,dosimetry ,dye sensitization ,energy transfer ,fading ,fluorescence sensing ,fluorescent nanoprobe ,glucose oxidase ,gold nanoparticles ,gold nanostructures ,graphene oxide nonwoven membrane ,heterogeneous nanoparticles ,heterojunction ,hybrid nanosystem ,hydrogen peroxide ,hydrothermal approach ,hydroxyl radicals ,interfacial polymerization ,lanthanide nanoparticles ,linear response doses ,luminescence ,luminescence enhancement ,metal-organic frameworks ,miRNA-150 ,miRNA-155 ,microtube ,multicolor emission ,n/a ,nanomaterials ,noble metal nanocrystal ,novel fluorescent probe ,organic dye ,photocatalysis ,photodynamic therapy ,photosensitizer ,photothermal conversion ,photothermal therapy ,plasmon enhancement ,polyaniline ,protein nanocomposite ,room temperature phosphorescence ,sensitivity ,silver ,singlet oxygen photogeneration ,solar evaporation ,spraying method ,sulfur quantum dots ,thermoluminescence ,thermoresponsive polymer ,ultraviolet upconversion ,upconversion nanomaterials ,visible/ultraviolet light excitation ,water purification ,white light emitting diodes ,wound-healing ,α-Bi2O3 - Abstract
Summary: This Special Issue reprint covers the synthesis of luminescent nanomaterials, applications for in vitro and in vivo imaging, detection based on fluorescence resonance energy, and the applications of luminescent nanoparticles for photodynamic activation and solid-state displays, as well as new materials and structures, such as perovskite quantum dots, and novel phenomena, such as aggregation-induced emissions. In total, there are 15 papers (2 reviews and 13 research articles) in this Special Issue consisting of the major areas of upconversion of luminescent nanomaterials; luminescent nanomaterials for solid-state lighting, displays, and anti-counterfeiting; particle-based sensing technology; particle-based therapeutics; and new materials and structures. This Issue represents new developments in luminescence nanotechnology.
16. Laser Synthesis of Nanomaterials.
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Boutinguiza, Mohamed, Boutinguiza, Mohamed, Riveiro, Antonio, and del Val, Jesús
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Technology: general issues ,2,2'-bipyridine ,PEGDA ,SERS ,XRD ,antibacterial effects ,buffer gas ,coefficient of friction ,copper nanoparticles ,diamond-like carbon ,femtosecond laser ,gold ,gold nanoparticles ,graphene ,graphene oxide ,hematite ,heterostructure ,hollow channel ,hybrid carbon-metal flake ,hydrogen evolution ,hydrogen evolution reaction ,impedance ,laser ablation ,laser fragmentation ,laser power ,laser processing ,laser reduction in liquid ,laser sintering ,laser synthesis ,laser-induced deposition ,maghemite ,magnetite ,magnetron sputtering ,metallic nanoparticles ,molybdenum sulfides ,multiphoton reduction ,n/a ,nanocatalysts ,nanocomposite ,nanoparticles ,nanosecond laser pulses ,nanosponges ,noble-metal films ,orthorhombic carbon ,para-nitrophenol ,permittivity ,photocatalysis ,photoelectrocatalysis ,photolysis ,plasmonic nanoparticles ,plasmonics ,polarization analysis ,porous nanostructures ,pulsed laser deposition ,pulsed leaser deposition ,reactive pulsed laser deposition ,semiconductors ,sol-gel ,solid lubricants ,supercritical carbon dioxide ,supercritical fluid ,transition metal chalcogenides ,ultraviolet photodetection ,wear ,zinc oxide - Abstract
Summary: Nanomaterials are a large area of research at present. These materials, which have at least one of their dimensions in the nanoscale (i.e., in a length range from 1 nm to 100 nm), have remarkable or unconventional properties, unlike bulk materials. These materials are currently used in many applications; however, new potential uses are being investigated. In this sense, there is large interest in their use in medicine, electronic devices, the production and storage of energy, composite materials, etc. The production of nanomaterials is addressed through physical and/or chemical methods; however, most of these methods exhibit low reproducibility or a low production rate or make use of toxic chemicals. In order to avoid most of these drawbacks, the laser-based synthesis of nanomaterials has emerged as an alternative to overcome these limitations. This family of methods use a laser beam to produce different nanomaterials (e.g., nanoparticles, nanowires or 2D materials) using diverse approaches. Techniques such as those based on laser ablation, laser vaporization, pulsed laser deposition (PLD), laser-chemical vapor deposition (LCVD), etc., are being explored at present to fabricate these nanoscale materials with a controlled size and shape. In this context, here we present research papers addressing the most recent developments in this field to summarize the current state of the art in the synthesis of nanomaterials using laser techniques.
17. Industrial and Municipal Wastewater Treatment with a Focus on Water-Reuse.
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Wagner, Martin, Bauer, Sonja, and Wagner, Martin
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Environmental science, engineering & technology ,Technology: general issues ,CALUX reporter gene bioassays ,CuO nanoparticles ,Daphnia magna ,MBR ,Mexico ,Punica granatum L. ,Qatar ,UV ,Willmott's index agreement ,adsorption ,advanced oxidation processes ,agricultural wastewater ,balanced scorecard ,biosorption ,boron-doped diamond ,carbamazepine ,carbon footprint ,casual loop diagrams ,catalysis ,catering ,ceramic membranes ,clay minerals ,climate change mitigation ,cooking ,cost-benefit analysis ,degradation ,developing countries ,ecotoxicity ,effect-based trigger value ,electrooxidation ,energy efficiency ,environmental benefit ,evaluation ,granular activated carbon ,green synthesis ,greenhouse gas emissions ,hospitality ,industrial wastewater ,industrial water reuse ,infiltration models ,intermittent aerator ,irrigation ,life cycle assessment ,livestock fodder production ,meal preparation ,methyl green ,model efficiency ,municipal wastewater treatment plants ,organoclays ,ozonation ,pesticides ,phosphorus recovery ,phosphorus removal ,photocatalysis ,photolysis ,produced water characterization ,produced water treatment ,salts recovery ,scenario analysis ,semistructured interviews ,sludge disposal ,sludge production ,sludge quality ,sludge stabilization ,spatial planning ,treated wastewater ,urban wastewater ,waste stabilisation ponds ,wastewater ,wastewater reuse ,wastewater survey ,wastewater treatment ,wastewater treatment systems ,water reclamation ,water reuse ,water-reuse concepts ,wool dyeing wastewater - Abstract
Summary: Population growth and climate change are leading to global water scarcity. Water shortages are thus hindering rural, urban and industrial development. These days, approximately half of the world's population is affected temporarily by water scarcity. To enable a secure water supply, alternative water sources must be generated to tackle the challenge of water scarcity. An important alternative resource is the reuse of treated wastewater. Water reuse processes are rarely considered and implemented. In contrast to the storage and use of rainwater, treated wastewater is a valuable resource, as it is available daily. Certain wastewater treatment processes are required to produce the new resource "reused water". The treatment processes depend on the quality of the wastewater since industrial and municipal wastewater flows are characterized by different concentrations. Moreover, water reuse methods must be developed in order to use the treated wastewater as efficiently as possible. Ideally, the reused water can be provided according to the "fit for purpose" principle and applied directly in areas such as irrigation, street cleaning, toilet flushing or make-up water for cooling systems.The Special Issue brings together new wastewater treatment technologies and water reuse concepts to tackle the challenges of climate change with the aim of bringing the resource "reused water" according to the "fit for purpose" principle to the user. This issue aims to draw on global experiences, approaches and solutions.
18. Heterogeneous Photocatalysis. A Solution for a Greener Earth.
- Author
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Lambert, Stéphanie, Lambert, Stéphanie, and Mahy, Julien
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Environmental science, engineering & technology ,History of engineering & technology ,Technology: general issues ,6-mercaptopurine photodegradation ,CNS-doped TiO2 ,Ce-modified ZnO ,LC/HRMS coupling ,LED ,NaYF4:Yb,Er ,NiTiO3 ,Pd-modification ,SiO2 ,TGA-MS ,TiO2 ,UV-Vis-NIR photocatalysis ,UV-visible light assisted photocatalytic activity ,Zr/N doping ,activation treatments ,adsorption ,advanced oxidation processes ,alcohol ,ambient crystallization ,anatase ,antimicrobial activity ,aqueous sol-gel process ,charge separation efficiency ,coagulation ,composite photocatalyst ,contaminants of emerging concern ,cytostatic ,doping ,ecotoxicity estimations ,electrocatalysts ,electron microscopy ,electrospinning ,emerging pollutants ,environment remediation ,fabric ,g-C3N4 ,glass fiber ,green synthesis ,high resolution mass spectrometry ,iron oxide ,kinetics ,landfill leachate ,ligand-to-metal charge transfer ,lime precipitation ,magnetic ,maprotiline ,mesoporous titania ,methylene blue (MB) degradation ,mild temperature ,n/a ,nano-Ag-TiO2 nanostructured nanofibers ,nanoparticles ,nickel oxide ,oxidation ,oxygen evolution reaction ,oxygen-based bidentate diketone ,p-nitrophenol degradation ,peptization ,photo-Fenton ,photocatalysis ,photocatalytic ,photodegradation ,photodegradation kinetics ,photoluminescence ,pollutant degradation ,pollutant removal ,recombination ,remediation of aqueous pollutants ,reverse osmosis concentrate ,semi-pilot plant ,smectite ,sol-gel ,sol-gel process ,sol-gel synthesis ,structural elucidation ,thiacloprid ,titania ,transformation products ,tri-doped TiO2 ,trimetallic ,upconversion phosphor ,wastewater ,water treatment - Abstract
Summary: This reprint is a compilation of the articles submitted in the Special Issue entitled, "Heterogeneous Photocatalysis: A Solution for a Greener Earth", from the journal Catalysts, which presents an overview of the latest advances in the development of innovative photocatalytic processes.
19. Environmental Friendly Catalysts for Energy and Pollution Control Applications.
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Lombraña, José Ignacio, Ferreiro, Cristian, Lombraña, José Ignacio, and Valdés, Héctor
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Environmental science, engineering & technology ,Technology: general issues ,Ad/Ox ,BaQD ,CO oxidation ,Co3O4 ,E. coli K12 ,FCC ,Fisher-Tropsch ,Lewis and Brønsted acid sites ,NOx emission ,Pareto chart ,Pd-based promoter ,Pt-based promoter ,SO2 ,absorption ,activated carbon ,adsorption ,anaerobic ,biocatalyst ,biomass ,carbamazepine ,carbon dioxide ,catalytic ozonation ,characterizations ,composites ,continuous flow ,core-shell structures ,cyanide ,degradation ,environmental catalysis ,exoelectrogen ,ferric coordination complex ,fixed-bed reactor ,fluid catalytic cracking ,granular activated carbon ,heterogeneous catalysis ,hybridization ,hydrogenation ,metal-organic frameworks ,methylene blue ,microenvironment ,natural zeolite ,optimization ,organic wastewater ,oxidation ,perturbation graph ,phenol ,photo-Fenton ,photocatalysis ,porous electrode ,preparation method ,reaction mechanism ,recalcitrant compounds ,refinery compliance ,sodium citrate ,sodium humate ,spherical polymer templates ,three-phase modelling ,titanium dioxide ,toluene ,turbidity ,volatile organic compounds ,wastewater treatment - Abstract
Summary: Catalysts are widely used in a great variety of technologies, providing remarkable efficiency in order to address sustainable energy production, climate change challenges, and to reduce industrial emissions. In the framework of the Environmental Catalysis section promoted by the Catalysts Editorial Office, this Special Issue, entitled "Environmental Friendly Catalysts for Energy and Pollution Control Applications", comprises novel studies representing the state-of-the-art research for efficient energy generation and industrial emission control based on new environmentally friendly catalyst materials (EFCs). In particular, in this Special Issue (SI), different kinds of catalysts are presented for catalytic solutions, including the reduction of NOx emissions (new zeolite catalyst modified with Pt), the elimination of volatile organic compounds (Co3O4@SiO2 and acidic surface transformed natural zeolite) and the removal of SO2 emissions (through adsorption processes with sodium citrate). Moreover, novel biocatalysts for bioanodes and new functional nanostructured catalysts based on metal-organic framework (MOFs) for different applications are also included. Additionally, articles compiled in this SI are also focused on the improvement of catalytic processes. Thus, selected processes based on activated carbons (modified with titanium dioxide) and optimized Fenton processes for the removal of aqueous organic pollutants or for the inactivation of bacteria are also presented.
20. Carbon Nanostructures for Enhanced Photocatalysis for Biocidal Applications.
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Pyrgiotakis, Georgios
- Abstract
In the last few decades, the demand for safer environmental conditions has increased dramatically. The burden of infectious diseases worldwide, related to contamination via contact with contaminated surfaces (fomites), is a growing issue. Globally, these infections are linked to an estimated 1.7 million deaths a year from diarrheal disease and 1.5 million deaths from respiratory infections [1]. Apart from hospitals, the problem has become a growing liability at places where food is prepared and handled [2], where there is a growing risk associated with the cross-contamination of edible goods and where large amounts are handled by a single facility [3]. Already many
E. coli andSalmonella outbreaks have been recorded and linked to single a facility [2, 4, 5]. The problem of cross-contamination via surfaces can also be traced, in smaller scale, to households where common areas can accumulate pathogens that can potentially become a threat, especially to more sensitive population groups [6]. There are also biological threats in forms of dangerous epidemic outbreaks (Ebola and SARS) and biological warfare weapons (anthrax and smallpox). The need for effective and efficient disinfection is driving the industry in the development of a wide range of products. These products can currently be divided into three major categories: [ABSTRACT FROM AUTHOR]- Published
- 2014
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- View/download PDF
21. Technologies for Advanced Wastewater Treatment in the Mediterranean Region.
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Malato, Sixto, Oller, Isabel, Fernández-Ibáñez, Pilar, and Fuerhacker, Maria
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Research in and application of advanced wastewater treatment technologies in the Mediterranean Basin require public awareness of the need for sustainable water resources to be raised through local information programs. Since wastewater treatment and reuse systems are generally capital-intensive and require highly-paid specialized operators, this point must be given especial relevance when applying new techniques, such as membrane bioreactors, tertiary chemical oxidation processes, etc., in these countries. This chapter gives a general overview on research currently underway in the Mediterranean Basin countries on innovative technologies for wastewater treatment, and compares them to the conventional technologies currently employed in wastewater treatment plants. Moreover, not only water availability, but also water quality, is essential for human life, health and safety, especially if sanitary requirements are not met. A summary of disinfection applications and research activities under development in the South Mediterranean and Middle East Regions is presented. [ABSTRACT FROM AUTHOR]
- Published
- 2011
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22. Catalytic Wastewater Treatment Using Pillared Clays.
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Perathoner, Siglinda and Centi, Gabriele
- Abstract
After introduction on the use of solid catalysts in wastewater treatment technologies, particularly advanced oxidation processes (AOPs), this review discussed the use of pillared clay (PILC) materials in three applications: (i) wet air catalytic oxidation (WACO), (ii) wet hydrogen peroxide catalytic oxidation (WHPCO) on Cu-PILC and Fe-PILC, and (iii) behavior of Ti-PILC and Fe-PILC in the photocatalytic or photo-Fenton conversion of pollutants. Literature data are critically analyzed to evidence the main direction to further investigate, in particularly with reference to the possible practical application of these technologies to treat industrial, municipal, or agro-food production wastewater. [ABSTRACT FROM AUTHOR]
- Published
- 2010
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23. Zinc Oxide LB Films with Improved Antireflective, Photoactive and Mechanical Properties.
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Naszályi Nagy, Lívia, Ábrahám, Nóra, Kovács, Attila L., van der Lee, Arie, Rouessac, Vincent, Cot, Didier, Ayral, André, and Hórvölgyi, Z.
- Abstract
Multifunctional Langmuir–Blodgett films were prepared using sol–gel derived ZnO and silica nanoparticles synthesized by the procedure of Seelig et al. [1] and Stöber et al. [2], respectively. High inherent porosity was observed for ZnO particles (30–40%) by pycnometry, scanning angle reflectometry, N
2 adsorption–desorption and ellipsometric porosimetry methods. Water contact angle of ZnO nanoparticles was determined from the non-dissipative part of the obtained surface pressure-surface area isotherms, and by scanning angle reflectometry measurements in a Wilhelmy film balance. Antireflective and photocatalytically active coatings of ZnO particles were deposited on glass, conductive glass and silicon substrates. The antireflectivity of ZnO LB films was improved by the integration of silica nanoparticles in the LB film. The photocatalytic activity and the mechanical stability of the samples were enhanced by means of surface modification with 3-methacryloxypropyl(trimethoxy)silane. [ABSTRACT FROM AUTHOR]- Published
- 2008
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24. Photocatalytic Degradation of Anionic Surfactant in Titanium Dioxide Suspension.
- Author
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Szabó-Bárdos, Erzsébet, Zsilák, Zoltán, and Horváth, Ottó
- Abstract
In TiO
2 -based photocatalytic degradation of an anionic detergent (lauryl benzenesulfonate) initial pH of 5.0 proved to be most appropriate for high efficiency of surfactant conversion, although lower pHs were more favorable for the adsorption on the surface of the catalyst. A catalyst concentration of 1 g dm−3 was optimum for the mineralization of this pollutant. After decreasing the surfactant concentration below the limit of foaming in a closed photo-reactor utilizing H2 O2 as electron acceptor, total mineralization of the pollutant could be achieved by a longer-time irradiation in a second, air-bubbled reactor. The activity of the photocatalyst proved to be constant even after several reusages. The temperature increase promoted the photoassisted degradation of the anionic detergent in the range of 20–50 °C measured in a home-built pilot equipment. The progress of mineralization became faster only after the conversion of surfactant reached 80–85%. There was found an optimum concentration of the oxidizer, H2 O2 , above which the efficiency of degradation could not be significantly enhanced. [ABSTRACT FROM AUTHOR]- Published
- 2008
- Full Text
- View/download PDF
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