1. Influence of cobalt ions on spectroscopic and emission characteristics of lead aluminia bismuth phosphate glass system.
- Author
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Ram, G. Chinna, Kumar, A. Suneel, Narendrudu, T., Suresh, S., and Rao, D. Krishna
- Subjects
ION emission ,LEAD ,OPTICAL spectra ,LIGHT absorption ,ABSORPTION spectra ,PHOSPHATE glass ,LEAD oxides - Abstract
By using the conventional melt quenching method, PbO−Al
2 O3 −Bi2 O3 −P2 O5 glasses doped with varying concentration of CoO were prepared and characterized. The optical absorption spectra of the glasses exhibited two principal absorption bands, one at 572 nm and the second one consisting of multiplets with the meta centre around1487 nm ascribed to the tetrahedrally coordinated Co2+ ions. Besides these, the spectra also exhibited two feeble bands around 532 and 633 nm which are the characteristics of octahedral coordinated Co2+ and Co3+ ions respectively. Photoluminescence spectra of the titled glasses have exhibited two emission bands at 640 and 868 nm due to tetrahedral Co2+ ions. FTIR spectra of the samples exhibited various vibrational bands due to phosphate, bismuth, PbO4 , PbO6 , AlO6 , AlO4 and CoIII -O vibrational units. The studies on the titled glasses have revealed that tetrahedrally coordinated Co2+ ions are found to increase as the content of CoO is gradually increased up to 0.8 mol%. As a result the degree of depolymerization of the glass network decreases which in turn enhances its rigidity with increasing the concentration of CoO upto 0.8mol%. [ABSTRACT FROM AUTHOR]- Published
- 2025
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