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The phenomenon of decoherence appears when the quantum behaviour of a microsystem is investigated. If the shielding of the considered microsystem from the macroscopic environment is not perfect, typical quantum features, such as the capability to exhibit quantum fringes, are suppressed as an unavoidable result of the interaction with the macroscopic background. Focusing on the centre of mass degrees of freedom of a massive test particle decoherence can typically be described in terms of random momentum transfers with the environment, thus naturally calling for a probabilistic standpoint. In this framework a general connection between the characteristic function of a Lévy process and loss of coherence of a massive quantum system interacting through momentum transfer events with an environment will be put into evidence, relying on Holevo’s characterization of quantum dynamical semigroups in the presence of translational invariance. The relationship with microphysical models and recent experiments on decoherence will also be considered. © 2007 American Institute of Physics [ABSTRACT FROM AUTHOR]