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Neutron reflectivity (NR) was used to study the sorption of Eu(III) by graphene oxide (GO) films exposed to ethanol solution of EuCl3. Most of the earlier sorption studies have been performed using GO dispersed in solution. In contrast, layered structure of GO films imposes limitations for penetration of ions between individual sheets. The analysis of NR data recorded before and after sorption under vacuum demonstrates an increase of GO film thickness due to sorption by 35–40%. The characterization of chemical state of Eu(III) sorbed by GO films by X-ray absorption near-edge structure (XANES) in high-energy resolution fluorescence detection (HERFD) method at the Eu L3 edge reveals that it remains the same as in anhydrous EuCl3. Analysis of all collected data including reference experiments with bulk GO samples allows to conclude that EuCl3 penetrates into GO interlayers with ethanol solution and remains trapped in interlayers after evaporation of ethanol. Sorption of EuCl3 results in nearly complete amorphization of film and likely formation of voids, thus making NR models based on specific volume of unit cell not valid for quantitative evaluation of Eu sorption. Limitations of NR method must be taken into account in future studies of sorption by thin films.

Swelling is the most fundamental property of graphite oxides (GO). Here, a structural study of Brodie graphite oxide (BGO) swelling in a set of long chain 1-alcohols (named C11 to C22 according to the number of carbons) performed using synchrotron radiation X-ray diffraction at elevated temperatures is reported. Even the longest of tested alcohols (C22) is found to intercalate BGO with enormous expansion of the interlayer distance from ≈6Å up to ≈63Å, the highest expansion of GO lattice ever reported. Swelling transitions from low temperature alpha-phase to high temperature beta-phase are found for BGO in all alcohols in the C11–C22 set. The transitions correspond to decrease of inter-layer distance correlating with the length of alcohol molecules, and change in their orientation from perpendicular to GO planes to layered parallel to GO (Type II transitions). These transitions are very different compared to BGO swelling transitions (Type I) found in smaller alcohols and related to insertion/de-insertion of additional layer of alcohol parallel to GO. Analysis of general trends in the whole set of 1-alcohols (C1 to C22) shows that the 1-alcohol chain length defines the type of swelling transition with Type I found for alcohols with C<10 and Type II for C>10.

Swelling is a property of hydrophilic layered materials, which enables the penetration of polar solvents into an interlayer space with expansion of the lattice. Here we report an irreversible swelling transition, which occurs in MXenes immersed in excess dimethyl sulfoxide (DMSO) upon heating at 362-370 K with an increase in the interlayer distance by 4.2 Å. The temperature dependence of MXene Ti3C2Tx swelling in several polar solvents was studied using synchrotron radiation X-ray diffraction. MXenes immersed in excess DMSO showed a step-like increase in the interlayer distance from 17.73 Å at 280 K to 22.34 Å above ∼362 K. The phase transformation corresponds to a transition from the MXene structure with one intercalated DMSO layer into a two-layer solvate phase. The transformation is irreversible and the expanded phase remains after cooling back to room temperature. A similar phase transformation was observed also for MXene immersed in a 2 : 1 H2O : DMSO solvent ratio but at a lower temperature. The structure of MXene in the mixed solvent below 328 K was affected by the interstratification of differently hydrated (H2O)/solvated (DMSO) layers. Above the temperature of the transformation, the water was expelled from MXene interlayers and the formation of a pure two-layer DMSO-MXene phase was found. No changes in the swelling state were observed for MXenes immersed in DMSO or methanol at temperatures below ambient down to 173 K. Notably, MXenes do not swell in 1-alcohols larger than ethanol at ambient temperature. Changing the interlayer distance of MXenes by simple temperature cycling can be useful in membrane applications, e.g. when a larger interlayer distance is required for the penetration of ions and molecules into membranes. Swelling is also very important in electrode materials since it allows penetration of the electrolyte ions into the interlayers of the MXene structure.

Earlier studies demonstrated that graphene oxide (GO) with large number of defects is favorable for the sorption of radionuclides. Here we report oxidation treatment which converts high surface area activated reduced graphene oxide (arGO) into a 3D analogue of defect-rich GO (dGO). Oxidation of arGO using ammonium persulfate results in oxidation corresponding to carbon to oxygen ratio C/O=3.3, similar to the oxidation state of graphene oxide while preserving high BET surface area of about 880 m2/g. Analysis of surface oxidized arGO shows high abundance of oxygen functional groups very similar to dGO and hydrophilic properties. The “3D graphene oxide” showed high sorption capacity for U(VI) removal in an extraordinary broad interval of pH. Notably, the surface oxidized carbon material has a rigid 3D structure with micropores accessible for penetration of radionuclide ions. Therefore, the bulk “3D GO” can be used as a sorbent directly without dispersing, the step required for GO to make its surface area accessible for pollutants

We first quantize the action proposed by Casalbuoni and Gomis in [Phys. Rev. D \textbf{90}, 026001 (2014)], an action that describes two massless relativistic scalar particles interacting via a conformally invariant potential. The spectrum is a continuum of massive states that may be interpreted as unparticles. We then obtain in a similar way the mass operator for a deformed action in which two terms are introduced that break the conformal symmetry: a mass term and an extra position-dependent coupling constant. A simple Ansatz for the latter leads to a mass operator with linear confinement in terms of an effective string tension $\sigma\,$. The quantized model is confining when $\sigma\neq0$ and its mass spectrum shows Regge trajectories. We propose a tensionless limit in which highly excited confined states reduce to (gapped) unparticles. Moreover, the low-lying confined bound states become massless in the latter limit as a sign of conformal symmetry restoration and the ratio between their masses and $\sqrt\sigma$ stays constant. The originality of our approach is that it applies to both confining and conformal phases via an effective interacting model., Comment: v2 to be published in Universe (MDPI)

Many industry applications require electronic circuits and systems to operate at high temperatures over 150 °C. Although planar microsupercapacitors (MSCs) have great potential for miniaturized on-chip integrated energy storage components, most of the present devices can only operate at low temperatures (<100 °C). In this work, we have demonstrated a facile process to fabricate activated graphene-based MSCs that can work at temperatures as high as 150 °C with high areal capacitance over 10 mF cm−2and good cycling performance. Remarkably, the devices exhibit no capacitance degradation during temperature cycling between 25 °C and 150 °C, thanks to the thermal stability of the active components., QC 20220425

We first quantize the action proposed by Casalbuoni and Gomis in [Phys. Rev. D \textbf{90}, 026001 (2014)], an action that describes two massless relativistic scalar particles interacting via a conformally invariant potential. The spectrum is a continuum of massive states that may be interpreted as unparticles. We then obtain in a similar way the mass operator for a deformed action in which two terms are introduced that break the conformal symmetry: a mass term and an extra position-dependent coupling constant. A simple Ansatz for the latter leads to a mass operator with linear confinement in terms of an effective string tension $\sigma\,$. The quantized model is confining when $\sigma\neq0$ and its mass spectrum shows Regge trajectories. We propose a tensionless limit in which highly excited confined states reduce to (gapped) unparticles. Moreover, the low-lying confined bound states become massless in the latter limit as a sign of conformal symmetry restoration and the ratio between their masses and $\sqrt\sigma$ stays constant. The originality of our approach is that it applies to both confining and conformal phases via an effective interacting model., Comment: v2 to be published in Universe (MDPI)

Many industry applications require electronic circuits and systems to operate at high temperatures over 150 °C. Although planar microsupercapacitors (MSCs) have great potential for miniaturized on-chip integrated energy storage components, most of the present devices can only operate at low temperatures (<100 °C). In this work, we have demonstrated a facile process to fabricate activated graphene-based MSCs that can work at temperatures as high as 150 °C with high areal capacitance over 10 mF cm−2and good cycling performance. Remarkably, the devices exhibit no capacitance degradation during temperature cycling between 25 °C and 150 °C, thanks to the thermal stability of the active components., QC 20220425

Many industry applications require electronic circuits and systems to operate at high temperatures over 150 °C. Although planar microsupercapacitors (MSCs) have great potential for miniaturized on-chip integrated energy storage components, most of the present devices can only operate at low temperatures (<100 °C). In this work, we have demonstrated a facile process to fabricate activated graphene-based MSCs that can work at temperatures as high as 150 °C with high areal capacitance over 10 mF cm−2and good cycling performance. Remarkably, the devices exhibit no capacitance degradation during temperature cycling between 25 °C and 150 °C, thanks to the thermal stability of the active components., QC 20220425

We first quantize the action proposed by Casalbuoni and Gomis in [Phys. Rev. D \textbf{90}, 026001 (2014)], an action that describes two massless relativistic scalar particles interacting via a conformally invariant potential. The spectrum is a continuum of massive states that may be interpreted as unparticles. We then obtain in a similar way the mass operator for a deformed action in which two terms are introduced that break the conformal symmetry: a mass term and an extra position-dependent coupling constant. A simple Ansatz for the latter leads to a mass operator with linear confinement in terms of an effective string tension $\sigma\,$. The quantized model is confining when $\sigma\neq0$ and its mass spectrum shows Regge trajectories. We propose a tensionless limit in which highly excited confined states reduce to (gapped) unparticles. Moreover, the low-lying confined bound states become massless in the latter limit as a sign of conformal symmetry restoration and the ratio between their masses and $\sqrt\sigma$ stays constant. The originality of our approach is that it applies to both confining and conformal phases via an effective interacting model., Comment: v2 to be published in Universe (MDPI)

Many industry applications require electronic circuits and systems to operate at high temperatures over 150 °C. Although planar microsupercapacitors (MSCs) have great potential for miniaturized on-chip integrated energy storage components, most of the present devices can only operate at low temperatures (<100 °C). In this work, we have demonstrated a facile process to fabricate activated graphene-based MSCs that can work at temperatures as high as 150 °C with high areal capacitance over 10 mF cm−2and good cycling performance. Remarkably, the devices exhibit no capacitance degradation during temperature cycling between 25 °C and 150 °C, thanks to the thermal stability of the active components., QC 20220425

Many industry applications require electronic circuits and systems to operate at high temperatures over 150 °C. Although planar microsupercapacitors (MSCs) have great potential for miniaturized on-chip integrated energy storage components, most of the present devices can only operate at low temperatures (<100 °C). In this work, we have demonstrated a facile process to fabricate activated graphene-based MSCs that can work at temperatures as high as 150 °C with high areal capacitance over 10 mF cm−2and good cycling performance. Remarkably, the devices exhibit no capacitance degradation during temperature cycling between 25 °C and 150 °C, thanks to the thermal stability of the active components., QC 20220425

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Voluntary human movements are stereotyped. When modeled in the framework of classical mechanics they are expected to minimize cost functions that may include energy, a natural candidate from a physiological point of view also. In time-changing environments, however, energy is no longer conserved-regardless of frictional energy dissipation-and it is therefore not the preferred candidate for any cost function able to describe the subsequent changes in motor strategies. Adiabatic invariants are known to be relevant observables in such systems, although they still need to be investigated in human motor control. We fill this gap and show that the theory of adiabatic invariants provides an accurate description of how human participants modify a voluntary, rhythmic, one-dimensional motion of the forearm in response to variable gravity (from 1 to 3g). Our findings suggest that adiabatic invariants may reveal generic hidden constraints ruling human motion in time-changing gravity.

Extremely defect graphene oxide (dGO) is proposed as an advanced sorbent for treatment of radioactive waste and con-taminated natural waters. dGO prepared using a modified Hummers oxidation procedure, starting from reduced graphene oxide (rGO) as a precursor, shows significantly higher sorption of U(VI), Am(III) and Eu(III) compared to standard gra-phene oxides (GO). Earlier studies revealed the mechanism of radionuclide sorption related to defects in GO sheets. There-fore, explosive thermal exfoliation of graphite oxide was used to prepare rGO with large number of defects and holes. De-fects and holes are additionally introduced by Hummers oxidation of rGO thus providing extremely defect-rich material. Analysis of characterization by XPS, TGA, FTIR shows that dGO oxygen functionalization is predominantly related to de-fects, such as flake edges and edge atoms of holes, whereas standard GO exhibits oxygen functional groups mostly on the planar surface. The high abundance of defects in dGO results in a 15-fold increase in sorption capacity of U(VI) compared to standard Hummers GO. The improved sorption capacity of dGO is related to abundant carboxylic groups attached hole edge atoms of GO flakes as revealed by synchrotron-based extended X-ray absorption fine structure (EXAFS) and high-energy resolution fluorescence detected X-Ray absorption near edge structure (HERFD-XANES) spectroscopy.

Extremely defect graphene oxide (dGO) is proposed as an advanced sorbent for treatment of radioactive waste and con-taminated natural waters. dGO prepared using a modified Hummers oxidation procedure, starting from reduced graphene oxide (rGO) as a precursor, shows significantly higher sorption of U(VI), Am(III) and Eu(III) compared to standard gra-phene oxides (GO). Earlier studies revealed the mechanism of radionuclide sorption related to defects in GO sheets. There-fore, explosive thermal exfoliation of graphite oxide was used to prepare rGO with large number of defects and holes. De-fects and holes are additionally introduced by Hummers oxidation of rGO thus providing extremely defect-rich material. Analysis of characterization by XPS, TGA, FTIR shows that dGO oxygen functionalization is predominantly related to de-fects, such as flake edges and edge atoms of holes, whereas standard GO exhibits oxygen functional groups mostly on the planar surface. The high abundance of defects in dGO results in a 15-fold increase in sorption capacity of U(VI) compared to standard Hummers GO. The improved sorption capacity of dGO is related to abundant carboxylic groups attached hole edge atoms of GO flakes as revealed by synchrotron-based extended X-ray absorption fine structure (EXAFS) and high-energy resolution fluorescence detected X-Ray absorption near edge structure (HERFD-XANES) spectroscopy.

The circumsporozoite (CS) protein covers the surface of the sporozoite of plasmodia. Its role in the development of the malaria parasite in mosquito vectors remains unknown. CS-epitope-containing proteins appear on undifferentiated oocysts on day 7 in Plasmodium berghei and on day 5 in P. gallinaceum as demonstrated by indirect fluorescence antibody tests using monoclonal antibodies directed against the CS-protein repeats. The three-dimensional distribution of the CS-epitope-containing proteins on oocysts was analyzed by confocal scanning laser microscopy. A strong antibody binding was found in patches around the oocysts of P. berghei and P. gallinaceum, and an accumulation of labeled proteins was found at the base of the oocysts of both species. In Western blots of infected midguts and salivary glands the antibodies recognized two peptides in the salivary glands but up to ten peptides in midgut extracts. The larger number of peptides recognized in midgut preparations might indicate breakdown products during the escape of the sporozoites from the oocyst and their migration on the midgut in the mosquito vector. The data indicate a possible involvement of the CS protein in an active migration process of the sporozoites in the mosquito vector.

Arguments are given that support the interpretation of the lattice QCD glueball and gluelump spectra in terms of bound states of massless constituent gluons with helicity-1. In this scheme, the mass hierarchy of the currently known gluelumps and glueballs is mainly due to the number of constituent gluons and can be understood within a simple flux tube model. It is also argued that the lattice QCD $0^{+-}$ glueball should be seen as a four-gluon bound state. The flux tube model allows for a parameter-free computation of its mass, which is in good agreement with lattice QCD., Comment: 3 figures, use of package youngtab

Arguments are given that support the interpretation of the lattice QCD glueball and gluelump spectra in terms of bound states of massless constituent gluons with helicity-1. In this scheme, the mass hierarchy of the currently known gluelumps and glueballs is mainly due to the number of constituent gluons and can be understood within a simple flux tube model. It is also argued that the lattice QCD $0^{+-}$ glueball should be seen as a four-gluon bound state. The flux tube model allows for a parameter-free computation of its mass, which is in good agreement with lattice QCD., Comment: 3 figures, use of package youngtab

Arguments are given that support the interpretation of the lattice QCD glueball and gluelump spectra in terms of bound states of massless constituent gluons with helicity-1. In this scheme, the mass hierarchy of the currently known gluelumps and glueballs is mainly due to the number of constituent gluons and can be understood within a simple flux tube model. It is also argued that the lattice QCD $0^{+-}$ glueball should be seen as a four-gluon bound state. The flux tube model allows for a parameter-free computation of its mass, which is in good agreement with lattice QCD., Comment: 3 figures, use of package youngtab

Arguments are given that support the interpretation of the lattice QCD glueball and gluelump spectra in terms of bound states of massless constituent gluons with helicity-1. In this scheme, the mass hierarchy of the currently known gluelumps and glueballs is mainly due to the number of constituent gluons and can be understood within a simple flux tube model. It is also argued that the lattice QCD $0^{+-}$ glueball should be seen as a four-gluon bound state. The flux tube model allows for a parameter-free computation of its mass, which is in good agreement with lattice QCD., Comment: 3 figures, use of package youngtab

In an attempt to bridge the gap between M-theory and braneworld phenomenology, we present various gravitational Lorentz-violating braneworlds which arise from p-brane systems. Lorentz invariance is still preserved locally on the braneworld. For certain p-brane intersections, the massless graviton is quasi-localized. This also results from an M5-brane in a C-field. In the case of a p-brane perturbed from extremality, the quasi-localized graviton is massive. For a braneworld arising from global AdS_5, gravitons travel faster when further in the bulk, thereby apparently traversing distances faster than light., Comment: 13 pages, 1 figure, LaTeX, references added, minor corrections and additions

In an attempt to bridge the gap between M-theory and braneworld phenomenology, we present various gravitational Lorentz-violating braneworlds which arise from p-brane systems. Lorentz invariance is still preserved locally on the braneworld. For certain p-brane intersections, the massless graviton is quasi-localized. This also results from an M5-brane in a C-field. In the case of a p-brane perturbed from extremality, the quasi-localized graviton is massive. For a braneworld arising from global AdS_5, gravitons travel faster when further in the bulk, thereby apparently traversing distances faster than light., Comment: 13 pages, 1 figure, LaTeX, references added, minor corrections and additions

In an attempt to bridge the gap between M-theory and braneworld phenomenology, we present various gravitational Lorentz-violating braneworlds which arise from p-brane systems. Lorentz invariance is still preserved locally on the braneworld. For certain p-brane intersections, the massless graviton is quasi-localized. This also results from an M5-brane in a C-field. In the case of a p-brane perturbed from extremality, the quasi-localized graviton is massive. For a braneworld arising from global AdS_5, gravitons travel faster when further in the bulk, thereby apparently traversing distances faster than light., Comment: 13 pages, 1 figure, LaTeX, references added, minor corrections and additions

In this paper, two things are done. (i) Using cohomological techniques, we explore the consistent deformations of linearized conformal gravity in 4 dimensions. We show that the only possibility involving no more than 4 derivatives of the metric (i.e., terms of the form $\partial^4 g_{\mu \nu}$, $\partial^3 g_{\mu \nu} \partial g_{\alpha \beta}$, $\partial^2 g_{\mu \nu} \partial^2g_{\alpha \beta}$, $\partial^2 g_{\mu \nu} \partial g_{\alpha \beta} \partial g_{\rho \sigma}$ or $\partial g_{\mu \nu} \partial g_{\alpha \beta} \partial g_{\rho \sigma} \partial g_{\gamma \delta}$ with coefficients that involve undifferentiated metric components - or terms with less derivatives) is given by the Weyl action $\int d^4x \sqrt{-g} W_{\a\b\g\d} W^{\a\b\g\d}$, in much the same way as the Einstein-Hilbert action describes the only consistent manner to make a Pauli-Fierz massless spin-2 field self-interact with no more than 2 derivatives. No a priori requirement of invariance under diffeomorphisms is imposed: this follows automatically from consistency. (ii) We then turn to "multi-Weyl graviton" theories. We show the impossibility to introduce cross-interactions between the different types of Weyl gravitons if one requests that the action reduces, in the free limit, to a sum of linearized Weyl actions. However, if different free limits are authorized, cross-couplings become possible. An explicit example is given. We discuss also how the results extend to other spacetime dimensions., Comment: This work was presented in part at the meeting of the Deutsche Physikalische Gesellschaft held in Bonn, 26-29 March 2001. To appear in Annalen der Physik

In this paper, two things are done. (i) Using cohomological techniques, we explore the consistent deformations of linearized conformal gravity in 4 dimensions. We show that the only possibility involving no more than 4 derivatives of the metric (i.e., terms of the form $\partial^4 g_{\mu \nu}$, $\partial^3 g_{\mu \nu} \partial g_{\alpha \beta}$, $\partial^2 g_{\mu \nu} \partial^2g_{\alpha \beta}$, $\partial^2 g_{\mu \nu} \partial g_{\alpha \beta} \partial g_{\rho \sigma}$ or $\partial g_{\mu \nu} \partial g_{\alpha \beta} \partial g_{\rho \sigma} \partial g_{\gamma \delta}$ with coefficients that involve undifferentiated metric components - or terms with less derivatives) is given by the Weyl action $\int d^4x \sqrt{-g} W_{\a\b\g\d} W^{\a\b\g\d}$, in much the same way as the Einstein-Hilbert action describes the only consistent manner to make a Pauli-Fierz massless spin-2 field self-interact with no more than 2 derivatives. No a priori requirement of invariance under diffeomorphisms is imposed: this follows automatically from consistency. (ii) We then turn to "multi-Weyl graviton" theories. We show the impossibility to introduce cross-interactions between the different types of Weyl gravitons if one requests that the action reduces, in the free limit, to a sum of linearized Weyl actions. However, if different free limits are authorized, cross-couplings become possible. An explicit example is given. We discuss also how the results extend to other spacetime dimensions., Comment: This work was presented in part at the meeting of the Deutsche Physikalische Gesellschaft held in Bonn, 26-29 March 2001. To appear in Annalen der Physik

The circumsporozoite (CS) protein covers the surface of the sporozoite of plasmodia. Its role in the development of the malaria parasite in mosquito vectors remains unknown. CS-epitope-containing proteins appear on undifferentiated oocysts on day 7 in Plasmodium berghei and on day 5 in P. gallinaceum as demonstrated by indirect fluorescence antibody tests using monoclonal antibodies directed against the CS-protein repeats. The three-dimensional distribution of the CS-epitope-containing proteins on oocysts was analyzed by confocal scanning laser microscopy. A strong antibody binding was found in patches around the oocysts of P. berghei and P. gallinaceum, and an accumulation of labeled proteins was found at the base of the oocysts of both species. In Western blots of infected midguts and salivary glands the antibodies recognized two peptides in the salivary glands but up to ten peptides in midgut extracts. The larger number of peptides recognized in midgut preparations might indicate breakdown products during the escape of the sporozoites from the oocyst and their migration on the midgut in the mosquito vector. The data indicate a possible involvement of the CS protein in an active migration process of the sporozoites in the mosquito vector.