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Geochemical data of the Variscan gneisses derived from pre-Variscan intrusives and late-Variscan granitoids in the Pyrenees and the Catalan Coastal Ranges were obtained from two main sources: (1) individually mined from published articles and unpublished PhD theses (Autran et al., 1970; Guitard, 1970; Enrique, 1989; Soler and Enrique, 1989; Enrique, 1990; Soler, 1990; Gleizes, 1992; Debon et al., 1996; Arranz, 1997; Guitard et al., 1998b, 1998b; Roberts et al., 2000; Vilà et al., 2005; Casas et al., 2010; Navidad et al., 2010; Druguet et al., 2014; Laumonier et al., 2015; Navidad et al., 2018; Lemirre et al., 2019; Álvaro et al., 2021; Liesa et al., 2021; Casas et al., 2024), and (2) the GEOROC Database (Geochemistry of Rocks of the Oceans and Continents, Göttingen University, https://georoc.eu/; last access: 03/2024; Lehnert et al., 2000). Other Findable, Accessible, Interoperable, and Reusable (FAIR; Wilkinson et al., 2016) databases were searched using geographic and lithogeochemical constrains, yielding no results. The mined data were curated and classified based on the analysed rock types, ages, regional tectonic setting, and mode of occurrence in outcrop, resulting in more than 600 entries that are associated with up to 66 data fields. Associated with each entry are generic, descriptive and informative fields (Sample ID, Unit/Massif, Rock category, Rock details, Outcrop description, and References), major element oxide abundances (SiO2, Al2O3, FeOT, Fe2O3T, MnO, MgO, CaO, Na2O, K2O, TiO2, P2O5, and LOI), and trace element concentrations (Ag, As, Ba, Be, Bi, Co, Cr, Cs, Cu, Ga, Ge, Hf, In, Mo, Nb, Ni, Pb, Rb, Sb, Sc, Sn, Sr, Ta, Th, Tl, U, V, W, Y, Zn, Zr, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu). The resulting database, named NEIGRA (North-East Iberian GRAnitoids), represents the first Open-Access compilation of granite and orthogneiss geochemical data in the Pyrenees and the Catalan Coastal Ranges.

[EN] So far, the nature and evolution of the lower crust under central Spain have been constrained mainly on the basis of a heterogeneous suite of granulite xenoliths from the Spanish Central System (SCS). In recent years, ultramafic volcanics from the Calatrava Volcanic Field (CVF) have also provided deep-seated crustal xenoliths which have not been studied in detail. Our data, combining mineral, whole-rock and isotopic geochemistry with U–Pb–Hf isotope ratios in zircons from the CVF and SCS xenoliths, highlight the felsic composition of the lower crust under central Iberia. A number of the Calatrava xenoliths represents Variscan igneous protoliths, which are a minor population in the SCS, and were likely formed by crystallisation of intermediate and felsic melts in the lower crust during the Variscan orogeny (leucodiorite protolith age of 314 ± 3 Ma and leucogranite protolith age of 308 ± 2.5 Ma). U–Pb data of metamorphic zircons show that granulite-facies metamorphism mainly occurred from 299 to 285 Ma in both areas. These ages are slightly younger than those of granitic intrusions that could be genetically related to the granulitic residue, which points to a main role of U–Pb isotope resetting in lower crustal zircons during HT or UHT conditions. The zircon U–Pb–Hf isotopic ratios support the idea that the lower crust in central Iberia consists mainly of Ordovician–Neoproterozoic metaigneous and metasedimentary rocks associated with the Cadomian continental arc of northern Gondwana. These rocks provide evidence of mixing between juvenile magmas and an enriched crustal component, ultimately extracted from an Eburnean crust. Other more evolved components present in detrital zircons are likely related to recycling of Archean crust derived from North Africa cratonic terranes.

So far, the nature and evolution of the lower crust under central Spain have been constrained mainly on the basis of a heterogeneous suite of granulite xenoliths from the Spanish Central System (SCS). In recent years, ultramafic volcanics from the Calatrava Volcanic Field (CVF) have also provided deep-seated crustal xenoliths which have not been studied in detail. Our data, combining mineral, whole-rock and isotopic geochemistry with U–Pb–Hf isotope ratios in zircons from the CVF and SCS xenoliths, highlight the felsic composition of the lower crust under central Iberia. A number of the Calatrava xenoliths represents Variscan igneous protoliths, which are a minor population in the SCS, and were likely formed by crystallisation of intermediate and felsic melts in the lower crust during the Variscan orogeny (leucodiorite protolith age of 314 ± 3 Ma and leucogranite protolith age of 308 ± 2.5 Ma). U–Pb data of metamorphic zircons show that granulite-facies metamorphism mainly occurred from 299 to 285 Ma in both areas. These ages are slightly younger than those of granitic intrusions that could be genetically related to the granulitic residue, which points to a main role of U–Pb isotope resetting in lower crustal zircons during HT or UHT conditions. The zircon U–Pb–Hf isotopic ratios support the idea that the lower crust in central Iberia consists mainly of Ordovician–Neoproterozoic metaigneous and metasedimentary rocks associated with the Cadomian continental arc of northern Gondwana. These rocks provide evidence of mixing between juvenile magmas and an enriched crustal component, ultimately extracted from an Eburnean crust. Other more evolved components present in detrital zircons are likely related to recycling of Archean crust derived from North Africa cratonic terranes., Ministerio de Ciencia e Innovación (MICINN), LA-ICPMS laboratory at the University of Johannesburg, Depto. de Mineralogía y Petrología, Fac. de Ciencias Geológicas, TRUE, pub

The Palu Metamorphic Complex (PMC) is exposed in a late Cenozoic orogenic belt in NW Sulawesi, Indonesia. It is a composite terrane comprising a gneiss unit of Gondwana origin, a schist unit composed of meta-sediments deposited along the SE Sundaland margin in the Late Cretaceous and Early Tertiary, and one or more slivers of amphibolite with oceanic crust characteristics. The gneiss unit forms part of the West Sulawesi block underlying the northern and central sections of the Western Sulawesi Province. The presence of Late Triassic granitoids and recycled Proterozoic zircons in this unit combined with its isotopic signature suggests that the West Sulawesi block has its origin in the New Guinea margin from which it rifted in the late Mesozoic. It docked with Sundaland sometime during the Late Cretaceous. U–Th–Pb dating results for monazite suggest that another continental fragment may have collided with the Sundaland margin in the earliest Miocene. High-pressure (HP) and ultrahigh-pressure (UHP) rocks (granulite, peridotite, eclogite) are found as tectonic slices within the PMC, mostly along the Palu–Koro Fault Zone, a major strike-slip fault that cuts the complex. Mineralogical and textural features suggest that some of these rocks resided at depths of 60–120 km during a part of their histories. Thermochronological data (U–Th–Pb zircon and 40Ar/39Ar) from the metamorphic rocks indicate a latest Miocene to mid-Pliocene metamorphic event, which was accompanied by widespread granitoid magmatism and took place in an extensional tectonic setting. It caused recrystallization of, and new overgrowths on, pre-existing zircon crystals, and produced andalusite–cordierite–sillimanite–staurolite assemblages in pelitic protoliths, indicating HT–LP (Buchan-type) metamorphism. The PMC was exhumed as a core complex at moderate rates (c. 0.7–1.0 mm/yr) accompanied by rapid cooling in the Plio-Pleistocene. Some of the UHP rocks were transported to the surface at significantly higher

East Antarctica consists of a number of cratonic fragments that amalgamated along distinct orogenic belts in late Neoproterozoic to early Palaeozoic times. These mobile belts include the c. 640 to 500 Ma old East African-Antarctic Orogen (EAAO) and the Kuunga Orogen, which seem to converge in Dronning Maud Land in the Atlantic sector of Antarctica. The polymetamorphic basement of Dronning Maud Land is characterized by rocks with Grenville-age protolith ages of c. 1130 to 1000 Ma in the west and rocks with early Neoproterozoic protolith ages of c. 1000 to 900 Ma in the east. These two provinces are separated by the prominent Forster Magnetic Anomaly, which is therefore interpreted to represent a suture zone. Four joint AWI-BGR international expeditions within the WEGAS (West-East Gondwana Amalgamation and Separation) and GEA (Geodynamic Evolution of East Antarctica) programmes between 2010 and 2015 have provided new combined geological and geophysical data that reveal a complex crustal architecture between central Dronning Maud Land and Lützow-Holm-Bay. The magnetic anomaly pattern changes significantly east of the Forster Magnetic Anomaly with apparently no indication of Maud-type crust. Particularly, the GEA II campaign (2011-12) targeted a series of previously unvisited nunataks in the largely ice- covered Borchgrevink-Isen between central Dronning Maud Land and Sør Rondane from Urna and Sørsteinen in the west to Blåklettane and Bergekongen in the east. This region is characterized by NW-SE trending distinct linear magnetic anomalies. This pattern is referred to as the SE Dronning Maud Land Province and was previously interpreted as a fragment of potentially older cratonic crust south of an Ediacaran to Cambrian mobile belt that crops out in Sør Rondane. New SHRIMP/SIMS U-Pb zircon ages and geochemical analyses, however, indicate that this region consists of Rayner-age (c. 1000 to 900 Ma) juvenile arc and metasedimentary cover rocks, which were intensely reworke

The Palu Metamorphic Complex (PMC) is exposed in a late Cenozoic orogenic belt in NW Sulawesi, Indonesia. It is a composite terrane comprising a gneiss unit of Gondwana origin, a schist unit composed of meta-sediments deposited along the SE Sundaland margin in the Late Cretaceous and Early Tertiary, and one or more slivers of amphibolite with oceanic crust characteristics. The gneiss unit forms part of the West Sulawesi block underlying the northern and central sections of the Western Sulawesi Province. The presence of Late Triassic granitoids and recycled Proterozoic zircons in this unit combined with its isotopic signature suggests that the West Sulawesi block has its origin in the New Guinea margin from which it rifted in the late Mesozoic. It docked with Sundaland sometime during the Late Cretaceous. U-Th-Pb dating results for monazite suggest that another continental fragment may have collided with the Sundaland margin in the earliest Miocene. High-pressure (HP) and ultrahigh-pressure (UHP) rocks (granulite, peridotite, eclogite) are found as tectonic slices within the PMC, mostly along the Palu-Koro Fault Zone, a major strike-slip fault that cuts the complex. Mineralogical and textural features suggest that some of these rocks resided at depths of 60-120 km during a part of their histories. Thermochronological data (U-Th-Pb zircon and 40Ar/39Ar) from the metamorphic rocks indicate a latest Miocene to mid-Pliocene metamorphic event, which was accompanied by widespread granitoid magmatism and took place in an extensional tectonic setting. It caused recrystallization of, and new overgrowths on, pre-existing zircon crystals, and produced andalusite-cordierite-sillimanite-staurolite assemblages in pelitic protoliths, indicating HT-LP (Buchan-type) metamorphism. The PMC was exhumed as a core complex at moderate rates (c. 0.7-1.0 mm/yr) accompanied by rapid cooling in the Plio-Pleistocene. Some of the UHP rocks were transported to the surface at significantly higher

East Antarctica consists of a number of cratonic fragments that amalgamated along distinct orogenic belts in late Neoproterozoic to early Palaeozoic times. These mobile belts include the c. 640 to 500 Ma old East African-Antarctic Orogen (EAAO) and the Kuunga Orogen, which seem to converge in Dronning Maud Land in the Atlantic sector of Antarctica. The polymetamorphic basement of Dronning Maud Land is characterized by rocks with Grenville-age protolith ages of c. 1130 to 1000 Ma in the west and rocks with early Neoproterozoic protolith ages of c. 1000 to 900 Ma in the east. These two provinces are separated by the prominent Forster Magnetic Anomaly, which is therefore interpreted to represent a suture zone. Four joint AWI-BGR international expeditions within the WEGAS (West-East Gondwana Amalgamation and Separation) and GEA (Geodynamic Evolution of East Antarctica) programmes between 2010 and 2015 have provided new combined geological and geophysical data that reveal a complex crustal architecture between central Dronning Maud Land and Lützow-Holm-Bay. The magnetic anomaly pattern changes significantly east of the Forster Magnetic Anomaly with apparently no indication of Maud-type crust. Particularly, the GEA II campaign (2011-12) targeted a series of previously unvisited nunataks in the largely ice- covered Borchgrevink-Isen between central Dronning Maud Land and Sør Rondane from Urna and Sørsteinen in the west to Blåklettane and Bergekongen in the east. This region is characterized by NW-SE trending distinct linear magnetic anomalies. This pattern is referred to as the SE Dronning Maud Land Province and was previously interpreted as a fragment of potentially older cratonic crust south of an Ediacaran to Cambrian mobile belt that crops out in Sør Rondane. New SHRIMP/SIMS U-Pb zircon ages and geochemical analyses, however, indicate that this region consists of Rayner-age (c. 1000 to 900 Ma) juvenile arc and metasedimentary cover rocks, which were intensely reworke

During the international GEA-II expedition to Sør Rondane (East Antarctica), large aggregates of crystalline gypsum were found within blue-ice moraines on the south side of the Sør Rondane Mountains at an elevation of ca. 2000 m and ca. 250 km inland of the present coastline. Gypsum aggregates reach one meter in diameter with individual crystal length up to 20 cm. Apparently, the gypsum grows in-situ and as a result of sublimation of the blue ice on the gravel of the moraine. Individual cobbles and sand are incorporated into the gypsum aggregates. The gypsum does not show signs of transport. In thin section, the gypsum shows an irregular growth zoning and in part bent cleavage planes. Abundant primary fluid inclusions are present parallel to the growth zoning as well as parallel to cleavage plains. This type of gypsum formation is enigmatic and has never been described before. It might indicate an important and thus far unknown process, characterising a special way of interaction between the lithosphere and the cryosphere. Preliminary Sr-isotope data indicate relatively high values and suggest crustal affinities. A preliminary set of sulfate sulfur (δ34SSO4) and oxygen (δ18OSO4) isotope data reveals values ranging from +7.0 and +29.6 ‰ (δ34SSO4) and between -16.7 and +0.3 ‰ (δ18OSO4). Samples display a positive correlation between δ34S and δ18O. Thus, Sulfur isotope values are highly variable and offer different conclusions with respect to potential sulfate sources. None of the gypsum samples displays a sulfur isotopic composition reflecting a pure seawater sulfate (i.e. sea spray) origin. Two samples yielded δ34SSO4 values of +7.0 and +9.0 ‰, most others are distinctly more positive than modern seawater sulfate (i.e., above +21.0 ‰), with a maximum value of +29.6 ‰. In general, the sulfur isotope values more positive than modern seawater sulfate suggest bacterial sulfate reduction. The low δ34SSO4 values are comparable to values measured previously for continental

info:eu-repo/semantics/published

info:eu-repo/semantics/published

info:eu-repo/semantics/published

info:eu-repo/semantics/published

The Malino Metamorphic Complex (MMC) is located at the western end of the north arm of Sulawesi. It consists of mica schists and gneisses (derived from proximal turbidite and granitoid protoliths), with intercalations of greenschist, amphibolite, marble, and quartzite, forming an E-W elongated dome-like structure bounded on all sides by faults. The age of the MMC is constrained between Devonian and Early Carboniferous. This Paleozoic age, the presence of Archean and Proterozoic inherited zircons, and the isotopic signature of the mica schists and gneisses indicate that the terrane was derived from the New Guinea-Australian margin of Gondwana. Similarities with basement rocks in the Bird’s Head suggests a common origin. Greenschists forming a discontinuous selvage (metamorphic carapace) around the complex were derived from adjacent autochthonous Paleogene formations. The rocks of the MMC show a Barrovian-type progression from greenschist through epidote-amphibolite to amphibolite facies. P–T estimations suggest a depth of burial of up to 27–30 km. K/Ar and 40Ar/39Ar cooling ages of 23–11 Ma, and a 7 Ma age for unconformably overlying volcanic rocks, indicate that the complex was exhumed during the Miocene. Two tectonic scenarios are considered: 1. the continental fragment docked with Sulawesi during the Mesozoic and was exhumed as a metamorphic core complex during the Miocene; 2. it was subducted beneath the north arm during the late Oligocene and then rapidly returned back to the surface.

Unravelling the origin of different components contributing to subduction-related magmas is a prerequisite to understanding the sources and processes involved in their origins. Mafic, high-Ca subduction-related magmas from geographically-diverse areas (Indonesia, Solomon Islands, Kamchatka, Valu Fa Ridge) contain two populations of olivine crystals, of which only the high-Ca population (CaO = 0.3-0.5 wt.%) crystallized from the melt that dominantly contributed to the whole rock composition. Forsterite-rich (Fo90-94), low-Ca (CaO < 0.15 wt.%), high-Ni (NiO > 0.3 wt.%) olivine crystals, which constitute 16-37 vol.% of total olivine population, are generally interpreted as mantle or lithospheric xenocrysts. However, in these samples, the olivine shape and chemical zoning, the composition of included minerals (orthopyroxene, clinoenstatite and Cr-spinel) and presence of melt inclusions, are indications that these crystals are phenocrysts from a mafic magma with high silica and low calcium contents. The coexistence of contrasting magmas (mafic high-Ca silica-poor versus low-Ca silica-rich) within a number of arc systems and their mixing may not be a rare event, and should be taken into account when developing models of arc petrogenesis.