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Poly(ethylene dioxythiophene) with functional pendant groups bearing double bonds is synthesized and employed for the fabrication of electroactive hydrogels with advantageous characteristics: covalently cross-linked porous 3D scaffolds with notable swelling ratio, appropriate mechanical properties, electroactivity in physiological conditions, and suitability for proliferation and differentiation of C2C12 cells. This is a new approach for the fabrication of conductive engineered constructs.

Despite the recent interest in organic electrochemical transistors (OECTs) as chemical and biological sensors, little is known about the role that device architecture and materials parameters play in determining sensor performance. We use numerical modeling to establish design rules in two regimes of operation: We find that for operation as an ion-to-electron converter, the response of OECTs is maximized through the use of a gate electrode that is much larger than the channel or through the use of a nonpolarizable gate electrode. Improving the conductivity of the polymer and using a channel geometry that maximizes channel width and thickness, and minimizes channel length helps increase the response. For operation as an electrochemical sensor, the sensitivity is maximized in OECTs with gate electrodes that are smaller than their channels. The sensitivity can be improved by increasing the charge carrier mobility and the capacitance per unit area of the conducting polymer, and also its ability to be penetrated by ions from the electrolyte. A channel geometry that maximizes channel width and minimizes channel length also improves sensitivity. © 2010 Wiley Periodicals, Inc.

Despite the recent interest in organic electrochemical transistors (OECTs) as chemical and biological sensors, little is known about the role that device architecture and materials parameters play in determining sensor performance. We use numerical modeling to establish design rules in two regimes of operation: We find that for operation as an ion-to-electron converter, the response of OECTs is maximized through the use of a gate electrode that is much larger than the channel or through the use of a nonpolarizable gate electrode. Improving the conductivity of the polymer and using a channel geometry that maximizes channel width and thickness, and minimizes channel length helps increase the response. For operation as an electrochemical sensor, the sensitivity is maximized in OECTs with gate electrodes that are smaller than their channels. The sensitivity can be improved by increasing the charge carrier mobility and the capacitance per unit area of the conducting polymer, and also its ability to be penetrated by ions from the electrolyte. A channel geometry that maximizes channel width and minimizes channel length also improves sensitivity. © 2010 Wiley Periodicals, Inc.

We report on lighting panels based on ruthenium(II) tris-bipyridine complexes that can be sourced directly from a standard US outlet. With the aid of the ionic liquid 1-butyl-3-methylimidazolium, the conductivity of the light emitting layer was enhanced to achieve device operation at a 60 Hz frequency. Lighting panels were prepared using a cascaded architecture of several electroluminescent devices. This architecture sustains high input voltages, provides fault tolerance, and facilitates the fabrication of large area solid-state lighting panels. Scalability of the drive voltage, radiant flux, and external quantum efficiency is demonstrated for panels with up to N=36 devices. Direct outlet operation is achieved for panels with N=16, 24, and 36 devices. © 2006 American Institute of Physics.

We report on lighting panels based on ruthenium(II) tris-bipyridine complexes that can be sourced directly from a standard US outlet. With the aid of the ionic liquid 1-butyl-3-methylimidazolium, the conductivity of the light emitting layer was enhanced to achieve device operation at a 60 Hz frequency. Lighting panels were prepared using a cascaded architecture of several electroluminescent devices. This architecture sustains high input voltages, provides fault tolerance, and facilitates the fabrication of large area solid-state lighting panels. Scalability of the drive voltage, radiant flux, and external quantum efficiency is demonstrated for panels with up to N=36 devices. Direct outlet operation is achieved for panels with N=16, 24, and 36 devices. © 2006 American Institute of Physics.

The temporal evolution of the current, radiance and efficiency of electroluminescent devices with various electrodes was discussed. It was observed that the performance of the organic electroluminescent devices was dominated by the process of charge injection. Different top electrodes were found to inject holes with different efficiency. It was found that, under forward bias the device characteristics were independent of the electrodes used.

The temporal evolution of the current, radiance and efficiency of electroluminescent devices with various electrodes was discussed. It was observed that the performance of the organic electroluminescent devices was dominated by the process of charge injection. Different top electrodes were found to inject holes with different efficiency. It was found that, under forward bias the device characteristics were independent of the electrodes used.