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Semiconductor nanowires have properties that make them potentially useful for applications in future electronic, photovoltaic, and optoelectronic devices. A powerful nanowire fabrication technique is the use of a nanoparticle as a preferential nucleation site, from which a nanowire grows. There has been significant progress in nanowire growth assisted by Au nanoparticles over the past 20 years. However, the high cost of gold and its incompatibility with silicon are obstacles to the industrial production of III–V nanowires. Therefore, significant efforts have been devoted to developing alternatives to Au-seeded nanowire growth. Although numerous metals and alloys are available, the development of alternatives to Au has been slow. The metal nanoparticles must have a high material quality and narrow size distribution, and their concentration must be controlled to enable precise experiments, and, in the future, high yields of identical devices.In the work described in this thesis, a spark discharge generator was used to synthesize and characterize a wide range of metal nanoparticles: Ag, Au, Bi, Co, Pb, Pd, Pt, Rh, and Sn, as well as three alloys: Ag25Au75, AgAu, and Ag75Au25. The nanoparticles were formed as an aerosol in an inert carrier gas of N2, and H2 was added to prevent the oxidation of base metals such as Bi, Co, and Sn. The nanoparticles were then either deposited on III–V substrates for nanowire growth using metal organic chemical vapor deposition, or used directly for gas- phase nanowire growth in an Aerotaxy reactor. The nanoparticle melting temperature is governed by its composition, primarily controlled by the choice of initial metal and the concentration of the group III material during nanowire growth. The nanoparticle composition was investigated after growth using transmission electron microscopy. For Pd-seeded GaAs or InAs a high group III content was found to be correlated with straight vertical nanowires, in contrast to kinked curly nanowires. Near

Reliable and affordable energy storage represents a bottleneck in a scenario where renewable energy sources become prominent on the energy market. With its high potential energy density and the natural abundance of the element, hydrogen gas is an attractive energy storage medium. But its gaseous nature, its high explosive potential and permeability of gaseous hydrogen through materials pose important limitations on its usability. In this thesis, Mg based nanomaterials with improved potential for applications as hydrogen stores are developed and analyzed. We have addressed the key issues of slow sorption kinetics, high stability and air sensitivity of MgH2 and provided viable solution directions to these challenges., Reactor Institute Delft, Applied Sciences

Reliable and affordable energy storage represents a bottleneck in a scenario where renewable energy sources become prominent on the energy market. With its high potential energy density and the natural abundance of the element, hydrogen gas is an attractive energy storage medium. But its gaseous nature, its high explosive potential and permeability of gaseous hydrogen through materials pose important limitations on its usability. In this thesis, Mg based nanomaterials with improved potential for applications as hydrogen stores are developed and analyzed. We have addressed the key issues of slow sorption kinetics, high stability and air sensitivity of MgH2 and provided viable solution directions to these challenges., Reactor Institute Delft, Applied Sciences

The growing interest during the past decades for mobile devices, like laptops, cellular phones, MP3 players, etc., is impressive. moreover, the concerns about climate changes have increased the worldwide interest for electrical and hybrid vehicles and intermittent sustainable energies, like solar and wind energy. These development have stimulated the research in electrical energy storage. With regard to the current state-of-the-art of advanced rechrgeable bateries, it is essential to develop better systems with larger energy densities, longer cycle life, improved safety, and lower costs. To date, Li-ion batteries are known as one of the best candidates to provide energy storage for these applications. However, electrical and hybrid vehicle requirements are not yet reached in terms of energy and power density and many improvements have to be achieved., DelftChemTech, Applied Sciences

The growing interest during the past decades for mobile devices, like laptops, cellular phones, MP3 players, etc., is impressive. moreover, the concerns about climate changes have increased the worldwide interest for electrical and hybrid vehicles and intermittent sustainable energies, like solar and wind energy. These development have stimulated the research in electrical energy storage. With regard to the current state-of-the-art of advanced rechrgeable bateries, it is essential to develop better systems with larger energy densities, longer cycle life, improved safety, and lower costs. To date, Li-ion batteries are known as one of the best candidates to provide energy storage for these applications. However, electrical and hybrid vehicle requirements are not yet reached in terms of energy and power density and many improvements have to be achieved., DelftChemTech, Applied Sciences