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On-line two-angle (15° and 90°) light scattering measurements with a gel permeation chromatography for linear and branched polystyrene in tetrahydrofuran (a good solvent) and in trans-decalin (a theta solvent) were made and compared with data from a multi-angle light scattering detector and literature values. Theoretically, weight-average molecular weight and the radius of gyration R_g can be determined accurately in the range where R_g^2k^2 is less than 1.2 (rod)~1.7 (random coil); here, k is the absolute value of the scattering vector for a right angle detector with the Berry square root method. Molecular weight dependence of the radius of gyration obtained from the two-angle light scattering detector for linear and branched polystyrenes under different thermodynamic conditions were measured and found to be almost the same as values measured with a multi-angle light scattering detector and literature values in the appropriate range of molecular weight.

On-line two-angle (15° and 90°) light scattering measurements with a gel permeation chromatography for linear and branched polystyrene in tetrahydrofuran (a good solvent) and in trans-decalin (a theta solvent) were made and compared with data from a multi-angle light scattering detector and literature values. Theoretically, weight-average molecular weight and the radius of gyration R_g can be determined accurately in the range where R_g^2k^2 is less than 1.2 (rod)~1.7 (random coil); here, k is the absolute value of the scattering vector for a right angle detector with the Berry square root method. Molecular weight dependence of the radius of gyration obtained from the two-angle light scattering detector for linear and branched polystyrenes under different thermodynamic conditions were measured and found to be almost the same as values measured with a multi-angle light scattering detector and literature values in the appropriate range of molecular weight.