1. Electrode and electrolyte engineering for high energy density Li metal batteries
- Author
-
Wu, Zhaohui, Liu, Ping1, Wu, Zhaohui, Wu, Zhaohui, Liu, Ping1, and Wu, Zhaohui
- Abstract
The rechargeable Li ion batteries are approaching their energy density limitation, while the prosperous growth of electric vehicle market is demanding cheaper and more sustainable batteries with higher energy density.To meet this goal, new battery material is needed to replace the current battery cathode, namely the LiCoO2 and LiNixMnyCo1-x-yO2 (NMC), which both contains the increasingly expensive transition metal, cobalt. One way to limit the cobalt usage is to increase the nickel substitution, as Ni is cheaper and more abundant compared to Co. Additionally, high Ni NMC delivers more capacity than their low Ni counterparts. However, transition metal substituent introduced an unexpected problem, i.e., the 1st cycle capacity loss. With electrochemical characterization and synchrotron X-ray diffraction, we have identified the sluggish Li intercalation at the end of discharge is the root-cause of this problem, which provided guidance for future improvement on these materials. In addition to optimizing the NMC cathode material, designing new cathode chemistry is another promising approach. Sulfur is a good cathode candidate for next generation energy storage system, due to its high capacity (~1675 mAh cm-2, 8 times as high as NMC), low price, and abundance in earth’s crust. However, elemental sulfur cathode suffers from its insulating nature and polysulfide dissolution problem. Sulfurized polyacrylonitrile (SPAN) is a sulfur based conductive polymer, which prevents sulfur dissolution by forming covalent bonding with sulfur and provides electron pathway by the chemical backbone. Although SPAN typically shows extraordinary stable cycling performance due to its unique structure and high specific capacity (~700 mAh cm-2), the Li-SPAN batteries reported in literature are yet to satisfy the industry demand due to its low areal capacity and incompatibility with ether electrolyte, which is commonly used in Li metal batteries. We discovered that LiNO3 as an electrolyte additive
- Published
- 2022