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The amount of ice versus supercooled water in clouds is important for their radiative properties and role in climate feedbacks. Hence, knowledge of the concentration of ice-nucleating particles (INPs) is needed. Generally, the concentrations of INPs are found to be very low in remote marine locations allowing cloud water to persist in a supercooled state. We had expected the concentrations of INPs at the North Pole to be very low given the distance from open ocean and terrestrial sources coupled with effective wet scavenging processes. Here we show that during summer 2018 (August and September) high concentrations of biological INPs (active at >−20°C) were sporadically present at the North Pole. In fact, INP concentrations were sometimes as high as those recorded at mid-latitude locations strongly impacted by highly active biological INPs, in strong contrast to the Southern Ocean. Furthermore, using a balloon borne sampler we demonstrated that INP concentrations were often different at the surface versus higher in the boundary layer where clouds form. Back trajectory analysis suggests strong sources of INPs near the Russian coast, possibly associated with wind-driven sea spray production, whereas the pack ice, open leads, and the marginal ice zone were not sources of highly active INPs. These findings suggest that primary ice production, and therefore Arctic climate, is sensitive to transport from locations such as the Russian coast that are already experiencing marked climate change.

Among the different aerosol mineral particles that contribute to induce ice nucleation (IN) in the troposphere, feldspars have been identified as the most active. Nevertheless, which surface properties make some feldspars more efficient than others, i.e. able to induce IN at higher temperatures, is still unclear. In addition to that, surface properties of such materials can change as they are exposed to a variety of environmental conditions while traveling through the troposphere. Here, freezing temperature of water droplets deposited on feldspar minerals has been measured as a function of consecutive freeze-thaw cycles. We found an increase of the freezing temperature for the initial cycles followed by approximately constant freezing temperature for consecutive cycles. We call this a "history effect". This effect is more evident for samples aged in standard room conditions and it disappears if the sample is exposed to oxygen plasma. Oxygen plasma generates OH groups at the surface, facilitating IN and cleans the surface from organic contamination, unblocking pores at the surface, believed to be the most active IN sites on feldspars. A similar process is suggested to happen during the history effect, when consecutive freeze-thaw events unblock IN sites.