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The electrochemical degradation of the Disperse Orange 29 azo dye in a filter-press flow cell using a Ti–Pt/β-PbO2as anode was investigated by experimental design for the variables current density, pH, [NaCl], and temperature. The electrochemical system was modeled by the charge required to attain 90% decolorization (Q90) and the chemical oxygen demand removal after 120min of electrolysis (COD120). The best conditions for Q90were neutral to slightly alkaline solutions with low values of [NaCl] (<1.0gL−1). On the other hand, slightly acidic to neutral conditions with higher values of [NaCl] (1.2–1.7gL−1) yielded the highest COD120values. These differences were ascribed to the possible formation of organochloride compounds that may lead to erroneous CODvalues. A total mass loss of only 0.1% was obtained during an accelerated life test of the Ti–Pt/PbO2anode. Low levels of [Pb2+] were attained in neutral to alkaline conditions