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4. ChemInform Abstract: Complexes with Functional Phosphines. Part 14. Coupling Reactions of MeO2CCCCO2Me with β‐Phosphino Ketonate Complexes Leading to Nickel, Palladium, and Platinum Alkenyl Complexes.

Author

BRAUNSTEIN, P., GOMES CARNEIRO, T. M., MATT, D., BALEGROUNE, F., and GRANDJEAN, D.

Abstract

The alkenyl complexes (III), (V), (VI) (X‐ray analysis; space group C2/c, Z=2), (VIII) and (IX), and (XII) are obtained by reactions of the phosphino enolate complexes (I), (IV), (VII) and (XI), respectively, with the acetylenedicarboxylate (II) according to the scheme.

Published
1989
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5. ChemInform Abstract: Synthesis and Structure of ((Ph3P)3Ir(μ3‐H)(μ‐H)2Ag2(OSO2CF3)(H2O))(CF3SO3), a Complex with a Bent Ag‐Ir‐Ag Chain.

Author

BRAUNSTEIN, P., GOMES CARNEIRO, T. M., MATT, D., TIRIPICCHIO, A., and TIRIPICCHIO CAMELLINI, M.

Abstract

In a first example of a double Ag+addition to a single metal center the reaction of two equiv. of the Ag salt (II) with the mer‐complex (I) yields the new complex (III), whose structure is determined by X‐rayanalysis (space group P21/n; Z=4).

Published
1987
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