1. Analysis of The Removal Mechanism of Ferroalloy by Acidithiobacillus Ferrooxidans
- Author
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Weimin, Lin, Hui, Huang, and Fei, Ma
- Abstract
Bio-machining technology is widely recognized as an environmentally friendly processing method for metals removal. In order to reveal the removal mechanism of ferroalloy corroded by Acidithiobacillus Ferrooxidans, ferroalloy workpieces were prepared by mixing 50% the powder of Fe with Co, Ni and Cu, and they were sintered with vacuum hot-pressing, A set of material removal experiments were carried out by shaking the ferroalloy with the bacterial strain culture solution of Fe3+level at 5.5 g/L, and the material removal amount, surface morphology and roughness, and electrochemical characteristics of ferroalloy workpieces were determinated. The results showed that the Fe-based alloys containing Co, Ni, Cu, and Sn can be bio-machined, and the surface roughness of the ferroalloys significantly increased after machining. The material removal amount (MRA) of 8 hours of bio-machining ranked in the order of Fe50Co (42.3) >Fe50Cu (36.4) > Fe50Ni (21.6)>Fe50Sn (14.3). The MRA of each ferroalloy increased with the processing time, and the results could be fitted in a power function with machining time. In conclusion, the activity of the metal, the passivation on the alloy surface and the accelerated corrosion of the inert metal on the active metal were the three most important factors affecting MRA of ferroalloys. The additional reaction between Fe and newly generated metal ions by Fe3+, as well as the uneven reaction layer of workpieces was involved in the process of bio-machining.
- Published
- 2022
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