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Cavitation is one of the main causes of deteriorating stability of bulb turbines. To enhance their stability, this study examines the effects of runner cavitation on draft tube pressure fluctuation and vibration in bulb turbine through experimental methods. With varying cavitation coefficients, a synchronous test system, including a high-speed camera, vibration acceleration sensors and pressure pulsation sensors, is applied to obtain cavitation images of the runner, vibration and internal fluid pressure pulsation data of the draft tube. The results show that the correlated component of pressure pulsation signals during the cavitation process is the synchronous pressure pulsation of 16fnWith the development of cavitation, the amplitude of synchronous pressure pulsation increases first and then decreases. Cavitation enhances the high-frequency vibration on the wall of runner chamber. The root mean square (rms) of the vertical vibration component IMF3, the horizontal vibration components IMF2, IMF4 are linearly negatively correlated with the cavitation coefficient. The associated component between cavitation-induced vibration and pressure pulsation signal is 16fnand its harmonics. In the process of cavitation, pressure pulsation plays a leading role in vibration.

An atom-economic protocol for the efficient and highly chemo- and stereoselective trans-hydroarylation of ynamides with hydroxyarenes catalyzed by B(C6F5)3has been developed. Use of readily available starting materials, low catalyst loading, mild reaction conditions, a broad substrate scope, ease of scale-up, and versatile functionalizations of the enamide products make this approach very practical and attractive.

The tip leakage flow formed by the tip clearance of a semi-open centrifugal pump adversely affects the energy performance and the energy waste. A T-shaped blade is proposed to be used to improve the energy characteristics. The internal flow field is simulated via the shear stress transport turbulence model to analyze the influence of the T-shaped blade on the performance of a centrifugal pump. It is shown that with the T-shaped blade, the hydraulic loss can be reduced, the Euler head can be increased, and the external characteristics can be improved. The maximum head and efficiency improvements are 3% and 1.6%, respectively. The relative flow angle near the tip clearance of the T-shaped blade decreases, and the strength of the backflow region is remarkably weakened. The area of the high entropy production region decreases, and the trend of the upstream diffusion is restrained under the design condition. The T-shaped blade can help to inhibit the diffusion of the high entropy production region to the hub under the low flow rate condition, but the entropy production and the mixing losses at the tip clearance are slightly increased. This research provides a new method for improving the energy performance of the semi-open centrifugal pump.

For nearly 60 years, significant research efforts have been focused on developing strategies for the cycloaddition of bicyclobutanes (BCBs). However, higher-order cycloaddition and catalytic asymmetric cycloaddition of BCBs have been long-standing formidable challenges. Here, we report Pd-catalyzed ligand-controlled, tunable cycloadditions for the divergent synthesis of bridged bicyclic frameworks. The dppb ligand facilitates the formal (5+3) cycloaddition of BCBs and vinyl oxiranes, yielding valuable eight-membered ethers with bridged bicyclic scaffolds in 100% regioselectivity. The Cy-DPEphos ligand promotes selective hetero-[2σ+2σ] cycloadditions to access pharmacologically important 2-oxabicyclo[3.1.1]heptane (O-BCHeps). Furthermore, the corresponding catalytic asymmetric synthesis of O-BCHeps with 94–99% ee has been achieved using chiral (S)-DTBM-Segphos, representing the first catalytic asymmetric cross-dimerization of two strained rings. The obtained O-BCHeps are promising bioisosteres for ortho-substituted benzenes.

A copper-catalyzed C–Si bond formation between N-halogenated amides and Si–B reagents is described. This oxidative coupling enables the silylation of C(sp3)–H bonds α to an amide nitrogen atom. The utility of the new method is demonstrated for sulfonamides, and N-chlorination with tBuOCl and C–H silylation employing CuSCN/4,4′-dimethoxy-2,2′-bipyridine as catalyst can be performed without purification of the N–Cl intermediate.

The strong interaction in a radial pump due to the relative movement between the impeller and the diffuser may excite not only strong pressure fluctuations but also velocity fluctuations. In this paper, the laser Doppler velocimetry (LDV) technique is successfully applied to measure the periodic flow field in a radial diffuser pump with low-specific speed, in order to investigate the velocity fluctuations caused by the impeller-diffuser interactions both in the impeller and diffuser regions. The velocity fluctuations in the impeller region are quantitatively examined at different radial positions, and the flow structure at the radial gap between two flow components is analyzed at different relative positions. In addition, the downstream effect on the diffuser flow is quantitatively and qualitatively assessed and compared with the turbulence effect.

The strong interaction in a radial pump due to the relative movement between the impeller and the diffuser may excite not only strong pressure fluctuations but also velocity fluctuations. In this paper, the laser Doppler velocimetry (LDV) technique is successfully applied to measure the periodic flow field in a radial diffuser pump with low-specific speed, in order to investigate the velocity fluctuations caused by the impeller-diffuser interactions both in the impeller and diffuser regions. The velocity fluctuations in the impeller region are quantitatively examined at different radial positions, and the flow structure at the radial gap between two flow components is analyzed at different relative positions. In addition, the downstream effect on the diffuser flow is quantitatively and qualitatively assessed and compared with the turbulence effect.

The comprehensive performance of the marine current turbine is an important issue in the ocean energy development. Its key is the performance of the hydrofoil, which is used to form the turbine blade. A multi-point optimization method of the hydrofoil is proposed in this paper. In this method, the Bezier curve is used to parameterize the hydrofoil. The geometrical parameters are used as variables while the lift-drag ratio and the cavitation performance of the hydrofoil are used as the objective functions. The Nsga-Ii algorithm is chosen as the optimization algorithm. In order to resolve the difficulty of this high-dimensional multi-objective optimization problem, the conception of the distance metric in the metric space is introduced to unify the lift-drag ratio and the cavitation performance under different working conditions. And then, the above optimization method is applied in the NACA63-815 hydrofoil’s optimal design under three typical conditions. Finally, the results from the performance comparison of the original and optimized hydrofoils obtained by using the CFD simulation are analyzed in detail. It is indicated that the optimized hydrofoils enjoy a better hydrodynamic performance than the original ones under the three conditions. The feasibility and the theoretical validity of this optimization method are confirmed by the results.

The comprehensive performance of the marine current turbine is an important issue in the ocean energy development. Its key is the performance of the hydrofoil, which is used to form the turbine blade. A multi-point optimization method of the hydrofoil is proposed in this paper. In this method, the Bezier curve is used to parameterize the hydrofoil. The geometrical parameters are used as variables while the lift-drag ratio and the cavitation performance of the hydrofoil are used as the objective functions. The NSGA-II algorithm is chosen as the optimization algorithm. In order to resolve the difficulty of this high-dimensional multi-objective optimi- zation problem, the conception of the distance metric in the metric space is introduced to unify the lift-drag ratio and the cavitation performance under different working conditions. And then, the above optimization method is applied in the NACA63-815 hydro- foil's optimal design under three typical conditions. Finally, the results from the performance comparison of the original and optimi- zed hydrofoils obtained by using the CFD simulation are analyzed in detail. It is indicated that the optimized hydrofoils enjoy a better hydrodynamic performance than the original ones under the three conditions. The feasibility and the theoretical validity of this optimization method are confirmed by the results.

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