1. High-Field Magnetization Study of Laves Phase (Gd,Y,Sm)Fe2-H
- Author
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Tereshina, Irina, Gorbunov, D. I., Karpenkov, Alexei, Doerr, M., Drulis, H., Granovski, Sergey, and Tereshina-Chitrova, Evgenia
- Abstract
The crystal structure and magnetic properties of the multicomponent Laves phase compounds (Gd
1- x Yx )0.8 Sm0.2 Fe2 Hz ( = 0, 0.2, 0.4, 0.6, 0.8, 1;$\boldsymbol{x}$ = 0 and 3.4) are investigated. These compounds crystallize into an MgCu$\boldsymbol{z}$ 2 type of structure. Hydrogenation does not change the crystal structure type but boosts the unit cell volume of (Gd,Y,Sm)Fe2 by ∼25%. Both parent and the hydrogen-charged ferrimagnetic compounds demonstrate magnetic compensation (mutual cancellation of magnetic moments of the individual magnetic sublattices). The exact compositions with zero magnetization state (compensated compositions) predicted using a three-sublattice model are in good agreement with the experiment. In the hydrides, the magnetic compensation takes place at a lower Y content as compared to the parent alloys. Pulsed magnetic fields reveal a distinctly different behavior of magnetization in the hydrides. With the increase of magnetic field, magnetization increases much faster in the hydrides as compared to the parent compounds.- Published
- 2022
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