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The nanotubes were prepared by the dc arc-discharge method in helium and argon gas ambient under controlled pressure, and subsequently purified by oxidation in air. The room temperature electron spin resonance (ESR) spectra of purified carbon nanotubes prepared under different inert gases and their pressure were measured. The dependence of the ESR line shape, linewidth, g-value of the nanotubes on the inert gases and their pressures is found and discussed.