1. Achieving ultra-broadband electromagnetic absorption of Ag regulated hollow Ag/CuO@CuS through balancing conduction loss and impedance matching.
- Author
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Zhang, Siyuan, Tao, Jinlei, Sun, Rui, Hu, Shipeng, and Jiao, Jian
- Subjects
ELECTROMAGNETIC wave absorption ,IMPEDANCE matching ,ELECTROMAGNETIC waves ,SILVER nitrate ,ABSORPTION - Abstract
• A sliver regulation strategy is proposed to balance the conduction loss and impedance matching by constructing unique particle structure for the first time. • The introduction of Ag provides a perfect conductive network for individual particles and whole structure, and gives enough space to control the stacking of particle to obtain excellent impedance matching. • The RL min and f E of H-P-Ag/CuO@CuS reached −40 dB and 8.56 GHz (2.3 mm), respectively. Excellent impedance matching and high conduction loss are important factors for the preparation of high-performance electromagnetic wave (EMW) absorbing materials, but these two properties are often contradictory. In this work, three absorbers with unique hollow structures, H-Ag/CuO@CuS, H-O-Ag/CuO@CuS, and H-P-Ag/CuO@CuS, are designed and synthesized by adopting hollow CuO@CuS with double shell as carrier and silver nitrate as the structural regulator. The more voids coming from hollow structures, window-opened structures, and stacked pores improve the impedance matching of these absorbers, and the introduction of elemental Ag effectively regulates the conduction loss. Therefore, a balance between impedance matching and conduction loss is achieved to improve the reflection loss (RL) value and broadens the absorbing band of the absorbers. In comparison to H-Ag/CuO@CuS and H O-Ag/CuO@CuS (hollow structure with open window) in which elemental Ag is uniformly dispersed in the CuO layer, H-P-Ag/CuO@CuS exhibits more excellent EMW absorption performance due to more voids and an optimized conductive network arising from Ag/CuO pieces distributed between the hollow Ag/CuO@CuS particles and Ag distributed in the CuS layer. When the thickness is 2.3 mm, H-P-Ag/CuO@CuS provides an ultra-wide electromagnetic absorption band of 8.56 GHz (9.44–18 GHz), in which the RL < –10 dB and the minimum reflection loss of –41 dB. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2023
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