1. Polarity-Mediated Antisolvent Control Enables Efficient Lanthanide-Based near-Infrared Perovskite LEDs
- Author
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Pan, Jia-Lin, Shen, Wan-Shan, Li, Sheng-Nan, Zhang, Zhong-Da, Zhao, Feng, Duan, Hong-Wei, Wang, Ya-Kun, and Liao, Liang-Sheng
- Abstract
Alloying lanthanide ions (Yb3+) into perovskite quantum dots (Yb3+:CsPb(Cl1–xBrx)3) is an effective method to achieve efficient near-infrared (NIR) luminescence (>950 nm). Increasing the Yb3+alloying ratio in the perovskite matrix enhances the luminescence intensity of Yb3+emission at 990 nm. However, high Yb3+alloying (>15%) results in vacancy-induced inferior material stability. In this work, we developed a polarity-mediated antisolvent manipulation strategy to resolve the incompatibility between a high Yb3+alloying ratio and inferior stability of Yb3+:CsPb(Cl1–xBrx)3. Precise control of solution polarity enables increased uniformity of the perovskite matrix with fewer trap densities. Employing this strategy, we obtain Yb3+:CsPb(Cl1–xBrx)3with the highest Yb3+alloying ratio of 30.2% and a 2-fold higher electroluminescence intensity at 990 nm. We lever the engineered Yb3+:CsPb(Cl1–xBrx)3to fabricate NIR-LEDs, achieving a peak external quantum efficiency (EQE) of 8.5% at 990 nm: this represents the highest among perovskite NIR-LEDs with an emission wavelength above 950 nm.
- Published
- 2024
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