1. Beta-phase transformation of polyvinylidene fluoride with supersonically sprayed ZnSnO3 cuboids for flexible piezoelectric nanogenerators.
- Author
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Joshi, Bhavana, Kim, Taegun, Lim, Woojin, Samuel, Edmund, Park, Chanwoo, Aldalbahi, Ali, El-Newehy, Mohamed, Lee, Hae-Seok, An, Seongpil, and Yoon, Sam S.
- Subjects
NANOGENERATORS ,POLYVINYLIDENE fluoride ,ELECTROMECHANICAL devices ,SHEARING force ,POWER density ,SHORT-circuit currents - Abstract
• Perovskite ZnSnO 3 cubes were synthesized hydrothermally. • The β -phase transformation was induced by the shear stress between ZnSnO 3 and PVDF. • A maximum piezo-potential of 41.5 V by the optimal case was achieved. • The maximum power density of 50.6 μW cm
−2 was acquired. Flexible self-powered electromechanical devices, such as piezoelectric nanogenerators (PENGs), which are used in wearable and implantable devices, are emerging as state-of-the-art clean energy sources. In this study, a scalable supersonic spraying technique was used to prepare flexible piezocomposite films of polyvinylidene fluoride (PVDF) and hydrothermally synthesized ZnSnO 3 (ZSO) cubes for PENGs. Raman spectra confirmed that the transformation of the α -phase of PVDF to its β -phase was induced by the shear stress generated between the ZSO particles and PVDF polymer during supersonic spraying. The optimized sample comprising 0.43 g of ZSO cubes and 1 g of PVDF produced a maximum piezopotential of 41.5 V and a short-circuit current, I sc , of 52.5 μA. A maximum power density of 50.6 μW cm−2 was obtained at a loading resistance of 0.4 MΩ, which matched the impedance of the PENG. Long-term tapping and bending cycles of N tap = 4200 and N bend = 600 yielded piezopotentials of 40.5 and 1.7 V, respectively. In addition, electrical poling for 2 h increased the piezopotential to 52 V owing to the alignment of the ferroelectric dipoles in the PVDF. [Display omitted] [ABSTRACT FROM AUTHOR]- Published
- 2024
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