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Many advantages of photothermal sterilization make it very promising in the field of sterilization. Biomass micro-nanoparticles with photothermal properties are considered worthy of development as photothermal sterilization materials. Urushiol, the main component of natural sap from lacquer tree, was applied to react with green-vitriol by the adjusted the concentrations of ferrous ion through the chemical synthesis method to prepare a novel magnetic composite nanoparticle with Fe3O4as the central core wrapped by urushiol-Fe chelate polymer. Under 808 nm near-infrared irradiation (0.12 W cm−2), the Fe3O4@urushiol-Fe polymeric nanoparticles were rapidly heated up to a maximum temperature of 104.9 ℃, implying good photothermal conversion performance. The nanoparticles were applied for the effective inactivation of bacteria such as Escherichia coli and Staphylococcus aureus. The optimal dose and irradiation power for sterilization were 0.5 mg and 1 W cm−2, respectively. The composite nanoparticles exhibited good photothermal conversion stability even after multiple photothermal heating and photothermal sterilization. The biomass magnetic composite Fe3O4@urushiol-Fe polymer nanoparticles had the advantages of simple preparation, high efficiency of photothermal conversion, significant sterilization effect, and easy collection, which demonstrated a broad application prospect in the field of photothermal sterilization.

On the basis of salinity and organic geochemical analyses of mudstones, this paper analyzed the relationship between salinity and sedimentary facies of different strata; studied influences of salinity on organic matter richness, types, and thermal maturities of source rocks; and built the organic enrichment accumulation model for the Paleogene and Neogene saline lakes of the western Qaidam Basin. In the western Qaidam Basin, saline lake depocenters and high salinity areas migrated eastward, and chloride ion (Cl–) concentration of source rocks showed an increasing trend from the Paleocene to Pliocene. The relationship between organic matter content and salinity of the Paleocene and Pliocene source rocks shows a three-interval model: both TOC (total organic carbon) content and chloroform bitumen content have low values at the low salinity stage, first increase to the peak and then decrease to the lowest values at the medium salinity stage, and sustain the lowest values at the super saline stage because of the interaction between organic productivity and reduction–oxidation in the saline lake of the western Qaidam Basin. The relationship between organic matter type and salinity of these source rocks suggests that the kerogen increasingly corresponds to a sapropelic and planktonic origin with increasing salinity. The organic matter enrichment model of the Paleogene and Neogene saline lakes of the western Qaidam Basin showed that saline lakes had high productivity and reducing conditions favorable for organic matter accumulation and preservation at their middle evolution stage. Through improving their apparent activation energy, salinity slowed down thermal evolution of source rocks, making the Paleogene and Neogene source rocks at low maturity to the immature stage in the western Qaidam Basin.