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An energy balance model is used to study the behavior of CO2 ice on Mars. The effect of the solar zenith angle dependence of albedo is to lengthen CO2 ice lifetimes at the poles. Hemispherical asymmetries in cloud and dust abundance could result in the survival of seasonal CO2 ice through summer in the south and not in the north, in agreement with observations. CO2 ice observed in the summertime polar cap in the south could be of recent origin, although a permanent CO2 polar cap cannot be ruled out.

An energy balance model of the seasonal polar caps on Mars is modified to include penetration of solar radiation into and through the ice. Penetration of solar radiation has no effect on subsurface temperature or total frost sublimation if seasonal ice overlies a dust surface. An effect is noted for seasonal ice which overlies the residual polar caps. For the case of an exposed water-ice residual polar cap, the temperature at depth is calculated to be up to several degrees warmer, and the calculated lifetime of seasonal CO2 frost is slightly lower when penetration of sunlight is properly treated in the model. For the case of a residual polar cap which is perennially covered by CO2 frost, the calculated lifetime of seasonal CO2 frost is very slightly increased as a result of sunlight penetration through the ice. Hence, penetration of sunlight into the ice helps to stabilize the observed dichotomy in the residual polar caps on Mars, although it is a small effect.

In addition to establishing that ozone constitutes a nonnegligible but only minor heat source in the Martian atmosphere, it is presently shown that the ozone abundance's hemispherical asymmetry is an improbable factor in the establishment of the polar caps' observed hemispherical asymmetry, since ozone absorbs less than 1 percent of the total solar flux incident on the polar caps. In the remaining hypothesized roles for Martian atmospheric ozone considered, namely those of cloud formation and snowfall, ozone heating remains nonnegligible but appears overstated by previous studies.

How ozone, clouds, and airborne dust affect CO2 ice formation and sublimation is examined to determine if they help explain the asymmetry in the residual polar caps. The radiative flux striking the surface is calculated for 57 solar and 10 IR wavelength intervals from 0 to 100 microns including the scatering, absorption, and emission by O3, CO2, clouds, and dust. UV absorption by H2O, O2, HO2, and H2O2 is also included, as is Rayleigh scattering. The discrete ordinate method of Stamnes et al. (1988) treats the emission, scattering, and absorption of monochromatic radiation.

Variation in the O3 abundance on Mars with changes in cloud opacities has been analyzed theoretically. Particular attention is given to the efficiency of reflectance spectroscopy for observing O3 abundances on Mars.