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Comets are small bodies thought to contain the most pristine material in the solar system. However, since their formation 4.5 Gy ago, they have been altered by different processes. While not exposed to much electromagnetic radiation, they experience intense particle radiation. Galactic cosmic rays and solar energetic particles have a broad spectrum of energies and interact with the cometary surface and subsurface; they are the main source of space weathering for a comet in the Kuiper Belt or in the Oort cloud; and also affect the ice prior to the comet agglomeration. While low energy particles interact only with the cometary surface, the most energetic ones deposit a significant amount of energy down to tens of meters. This interaction can modify the isotopic ratios in cometary ices and create secondary compounds through radiolysis, such as O2 and H2O2 (paper II: Maggiolo et al., 2020). In this paper, we model the energy deposition of energetic particles as a function of depth using a Geant4 application modified to account for the isotope creation process. We quantify the energy deposited in cometary nucleus by galactic cosmic rays and solar energetic particles. The consequences of the energy deposition on the isotopic and chemical composition of cometary ices and their implication on the interpretation of cometary observations, notably of 67P/Churyumov Gerasimenko by the ESA/Rosetta spacecraft, will be discussed in Paper II.

Solar wind charge-changing reactions are of paramount importance to the physico-chemistry of the atmosphere of a comet because they mass-load the solar wind through an effective conversion of fast, light solar wind ions into slow, heavy cometary ions. The ESA/Rosetta mission to comet 67P/Churyumov-Gerasimenko (67P) provided a unique opportunity to study charge-changing processes in situ. An extended analytical formalism describing solar wind charge-changing processes at comets along solar wind streamlines is presented. It is based on a thorough book-keeping of available charge-changing cross sections of hydrogen and helium particles in a water gas. After presenting a general 1D solution of charge exchange at comets, we study the theoretical dependence of charge-state distributions of (He$^{2+}$, He$^+$, He$^0$) and (H$^+$, H$^0$, H$^-$) on solar wind parameters at comet 67P. We show that double charge exchange for the He$^{2+}$-H$_2$O system plays an important role below a solar wind bulk speed of 200 km/s , resulting in the production of He energetic neutral atoms, whereas stripping reactions can in general be neglected. Retrievals of outgassing rates and solar wind upstream fluxes from local Rosetta measurements deep in the coma are discussed. Solar wind ion temperature effects at 400 km/s solar wind speed are well contained during the Rosetta mission. As the comet approaches perihelion, the model predicts a sharp decrease of solar wind ion fluxes by almost one order of magnitude at the location of Rosetta, forming in effect a solar wind ion cavity. This study is the second part of a series of three on solar wind charge-exchange and ionization processes at comets, with a specific application to comet 67P and the Rosetta mission., Comment: 17 pages, 10 figures