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The energy level alignment at organic/inorganic (o/i) semiconductor interfaces is crucial for any light-emitting or -harvesting functionality. Essential is the access to both occupied and unoccupied electronic states directly at the interface, which is often deeply buried underneath thick organic films and challenging to characterize. We use several complementary experimental techniques to determine the electronic structure of p-quinquephenyl pyridine (5P-Py) adsorbed on ZnO(10-10). The parent anchoring group, pyridine, significantly lowers the work function by up to 2.9 eV and causes an occupied in-gap state (IGS) directly below the Fermi level $E_\text{F}$. Adsorption of upright-standing 5P-Py also leads to a strong work function reduction of up to 2.1 eV and to a similar IGS. The latter is then used as an initial state for the transient population of three normally unoccupied molecular levels through optical excitation and, due to its localization right at the o/i interface, provides interfacial sensitivity, even for thick 5P-Py films. We observe two final states above the vacuum level and one bound state at around 2 eV above $E_\text{F}$, which we attribute to the 5P-Py LUMO. By the separate study of anchoring group and organic dye combined with the exploitation of the occupied IGS for selective interfacial photoexcitation this work provides a new pathway for characterizing the electronic structure at buried o/i interfaces.

An intense radio flare on the dMe star AD Leo, observed with the Effelsberg radio telescope and spectrally resolved in a band of 480 MHz centred at 4.85 GHz is analysed. A lower limit of the brightness temperature of the totally right handed polarized emission is estimated as T_b ~ 5x10^10 K (with values T_b > ~3x10^13 K considered to be more probable), which requires a coherent radio emission process. In the interpretation we favour fundamental plasma radiation by mildly relativistic electrons trapped in a hot and dense coronal loop above electron cyclotron maser emission. This leads to densities and magnetic field strengths in the radio source of n ~ 2x10^11 cm^-3 and B ~ 800 G. Quasi-periodic pulsations during the decay phase of the event suggest a loop radius of r ~ 7x10^8 cm. A filamentary corona is implied in which the dense radio source is embedded in hot thin plasma with temperature T >= 2x10^7 K and density n_ext <= 10^-2 n. Runaway acceleration by sub-Dreicer electric fields in a magnetic loop is found to supply a sufficient number of energetic electrons., Comment: 12 pages, 8 figures, Astron.Astrophys. in press