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Owing to the limitation of traditional analytical methods, the coloration mechanism of copper red glaze has been disputed in the academic field for a long time, which mainly focuses on whether the color agent is metallic copper nanoparticles or cuprous oxide (Cu2O) nanoparticles. Based on Mie scattering theory, this work calculated the reflection spectra of nanoparticles uniformly dispersed in transparent glaze with different types, diameters and volume fractions, then discussed the differences between the reflection spectra of metallic copper and cuprous oxide as scatters, calculated the corresponding L*a*b* values, and compared them with the experimental results. This work provides a feasible and convenient method to distinguish these two coloration mechanisms., Comment: 26 pages, 8 figures