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Conductive metal-organic frameworks (c-MOFs) and ionic liquids (ILs) have emerged as auspicious combinations for high-performance supercapacitors. However, the nanoconfinement from c-MOFs and high viscosity of ILs slow down the charging process. This hindrance can, however, be resolved by adding solvent. Here, we performed constant-potential molecular simulations to scrutinize the solvent impact on charge storage and charging dynamics of MOF-IL-based supercapacitors. We find conditions for >100% enhancement in capacity and ~6 times increase in charging speed. These improvements were confirmed by synthesizing near-ideal c-MOFs and developing multiscale models linking molecular simulations to electrochemical measurements. Fundamentally, our findings elucidate that the solvent acts as an ionophobic agent to induce a substantial enhancement in charge storage, and as an ion traffic police to eliminate convoluted counterion and co-ion motion paths and create two distinct ion transport highways to accelerate charging dynamics. This work paves the way for the optimal design of MOF supercapacitors.

Chest X-rays (CXRs) are commonly utilized as a low-dose modality for lung screening. Nonetheless, the efficacy of CXRs is somewhat impeded, given that approximately 75% of the lung area overlaps with bone, which in turn hampers the detection and diagnosis of diseases. As a remedial measure, bone suppression techniques have been introduced. The current dual-energy subtraction imaging technique in the clinic requires costly equipment and subjects being exposed to high radiation. To circumvent these issues, deep learning-based image generation algorithms have been proposed. However, existing methods fall short in terms of producing high-quality images and capturing texture details, particularly with pulmonary vessels. To address these issues, this paper proposes a new bone suppression framework, termed BS-Diff, that comprises a conditional diffusion model equipped with a U-Net architecture and a simple enhancement module to incorporate an autoencoder. Our proposed network cannot only generate soft tissue images with a high bone suppression rate but also possesses the capability to capture fine image details. Additionally, we compiled the largest dataset since 2010, including data from 120 patients with high-definition, high-resolution paired CXRs and soft tissue images collected by our affiliated hospital. Extensive experiments, comparative analyses, ablation studies, and clinical evaluations indicate that the proposed BS-Diff outperforms several bone-suppression models across multiple metrics. Our code can be accessed at https://github.com/Benny0323/BS-Diff., Comment: 5 pages, 2 figures, accepted by IEEE ISBI 2024

Deep neural networks (DNNs) have been widely adopted in brain lesion detection and segmentation. However, locating small lesions in 2D MRI slices is challenging, and requires to balance between the granularity of 3D context aggregation and the computational complexity. In this paper, we propose a novel view-disentangled transformer to enhance the extraction of MRI features for more accurate tumour detection. First, the proposed transformer harvests long-range correlation among different positions in a 3D brain scan. Second, the transformer models a stack of slice features as multiple 2D views and enhance these features view-by-view, which approximately achieves the 3D correlation computing in an efficient way. Third, we deploy the proposed transformer module in a transformer backbone, which can effectively detect the 2D regions surrounding brain lesions. The experimental results show that our proposed view-disentangled transformer performs well for brain lesion detection on a challenging brain MRI dataset., Comment: International Symposium on Biomedical Imaging (ISBI) 2022, code: https://github.com/lhaof/ISBI-VDFormer

Automatic theorem proving with deep learning methods has attracted attentions recently. In this paper, we construct an automatic proof system for trigonometric identities. We define the normalized form of trigonometric identities, design a set of rules for the proof and put forward a method which can generate theoretically infinite trigonometric identities. Our goal is not only to complete the proof, but to complete the proof in as few steps as possible. For this reason, we design a model to learn proof data generated by random BFS (rBFS), and it is proved theoretically and experimentally that the model can outperform rBFS after a simple imitation learning. After further improvement through reinforcement learning, we get AutoTrig, which can give proof steps for identities in almost as short steps as BFS (theoretically shortest method), with a time cost of only one-thousandth. In addition, AutoTrig also beats Sympy, Matlab and human in the synthetic dataset, and performs well in many generalization tasks.

The pivotal role of magnetic anisotropy in stabilising two-dimensional (2D) magnetism has been widely accepted, however, direct correlation between magnetic anisotropy and long-range magnetic ordering in the 2D limit is yet to be explored. Here, using angle- and temperature-dependent tunnelling magnetoresistance, we report unprecedented metamagnetic phase transitions in atomically-thin CrOCl, triggered by magnetic easy-axis flipping instead of the conventional spin flop mechanism. Few-layer CrOCl tunnelling devices of various thicknesses consistently show an in-plane antiferromagnetic (AFM) ground state with the easy axis aligned along the Cr-O-Cr direction (b-axis). Strikingly, with the presence of a magnetic field perpendicular to the easy-axis (H||c), magnetization of CrOCl does not follow the prevalent spin rotation and saturation pattern, but rather exhibits an easy-axis flipping from the in-plane to out-of-plane directions. Such magnetic anisotropy controlled metamagnetic phase transitions are manifested by a drastic upturn in tun- nelling current, which shows anomalous shifts towards higher H when temperature increases. By 2D mapping of tunnelling currents as a function of both temperature and H, we determine a unique ferrimagnetic state with a superstructure periodicity of five unit cells after the field-induced metam- agnetic transitions. The feasibility to control 2D magnetism by manipulating magnetic anisotropy may open enormous opportunities in spin-based device applications., Comment: 7 pages, 4 figures

We report the observation of magnetoresistance (MR) originating from the orbital angular momentum transport (OAM) in a Permalloy (Py) / oxidized Cu (Cu*) heterostructure: the orbital Rashba-Edelstein magnetoresistance. The angular dependence of the MR depends on the relative angle between the induced OAM and the magnetization in a similar fashion as the spin Hall magnetoresistance (SMR). Despite the absence of elements with large spin-orbit coupling, we find a sizable MR ratio, which is in contrast to the conventional SMR which requires heavy elements. By varying the thickness of the Cu* layer, we confirm that the interface is responsible for the MR, suggesting that the orbital Rashba-Edelstein effect is responsible for the generation of the OAM. Through Py thickness-dependence studies, we find that the effective values for the spin diffusion and spin dephasing lengths of Py are significantly larger than the values measured in Py / Pt bilayers, approximately by the factor of 2 and 4, respectively. This implies that another mechanism beyond the conventional spin-based scenario is responsible for the MR observed in Py / Cu* structures originated in a sizeable transport of OAM. Our findings not only unambiguously demonstrate the current-induced torque without using any heavy element via the OAM channel but also provide an important clue towards the microscopic understanding of the role that OAM transport can play for magnetization dynamics., Comment: 11 pages,3 figures

Some one-loop diagrams with one and two external baryons/nucleons are revisited using covariant baryon propagators in chiral effective theory. We showed that it is enough to separate and subtract all the local terms that violate chiral power counting to recover chiral power counting, no need to introduce extra operations. The structures of leading chiral corrections and IR enhancement or threshold effects are 'stable' or persist as long as covariant propagators are employed for all particles., Comment: 9 pages, 11 figures, final version, accepted for publication in Nuclear Physics B

Denoising images contaminated by the mixture of additive white Gaussian noise (AWGN) and impulse noise (IN) is an essential but challenging problem. The presence of impulsive disturbances inevitably affects the distribution of noises and thus largely degrades the performance of traditional AWGN denoisers. Existing methods target to compensate the effects of IN by introducing a weighting matrix, which, however, is lack of proper priori and thus hard to be accurately estimated. To address this problem, we exploit the Pareto distribution as the priori of the weighting matrix, based on which an accurate and robust weight estimator is proposed for mixed noise removal. Particularly, a relatively small portion of pixels are assumed to be contaminated with IN, which should have weights with small values and then be penalized out. This phenomenon can be properly described by the Pareto distribution of type 1. Therefore, armed with the Pareto distribution, we formulate the problem of mixed noise removal in the Bayesian framework, where nonlocal self-similarity priori is further exploited by adopting nonlocal low rank approximation. Compared to existing methods, the proposed method can estimate the weighting matrix adaptively, accurately, and robust for different level of noises, thus can boost the denoising performance. Experimental results on widely used image datasets demonstrate the superiority of our proposed method to the state-of-the-arts.

Recently, the paradigm of unfolding iterative algorithms into finite-length feed-forward neural networks has achieved a great success in the area of sparse recovery. Benefit from available training data, the learned networks have achieved state-of-the-art performance in respect of both speed and accuracy. However, the structure behind sparsity, imposing constraint on the support of sparse signals, is often an essential prior knowledge but seldom considered in the existing networks. In this paper, we aim at bridging this gap. Specifically, exploiting the iterative reweighted $\ell_1$ minimization (IRL1) algorithm, we propose to learn the cluster structured sparsity (CSS) by rewegihting adaptively. In particular, we first unfold the Reweighted Iterative Shrinkage Algorithm (RwISTA) into an end-to-end trainable deep architecture termed as RW-LISTA. Then instead of the element-wise reweighting, the global and local reweighting manner are proposed for the cluster structured sparse learning. Numerical experiments further show the superiority of our algorithm against both classical algorithms and learning-based networks on different tasks.

Convolutional Sparse Coding (CSC) has been attracting more and more attention in recent years, for making full use of image global correlation to improve performance on various computer vision applications. However, very few studies focus on solving CSC based image Super-Resolution (SR) problem. As a consequence, there is no significant progress in this area over a period of time. In this paper, we exploit the natural connection between CSC and Convolutional Neural Networks (CNN) to address CSC based image SR. Specifically, Convolutional Iterative Soft Thresholding Algorithm (CISTA) is introduced to solve CSC problem and it can be implemented using CNN architectures. Then we develop a novel CSC based SR framework analogy to the traditional SC based SR methods. Two models inspired by this framework are proposed for pre-/post-upsampling SR, respectively. Compared with recent state-of-the-art SR methods, both of our proposed models show superior performance in terms of both quantitative and qualitative measurements., Comment: 10 pages, 12 figures, 3 tables

We propose a simple yet effective model for Single Image Super-Resolution (SISR), by combining the merits of Residual Learning and Convolutional Sparse Coding (RL-CSC). Our model is inspired by the Learned Iterative Shrinkage-Threshold Algorithm (LISTA). We extend LISTA to its convolutional version and build the main part of our model by strictly following the convolutional form, which improves the network's interpretability. Specifically, the convolutional sparse codings of input feature maps are learned in a recursive manner, and high-frequency information can be recovered from these CSCs. More importantly, residual learning is applied to alleviate the training difficulty when the network goes deeper. Extensive experiments on benchmark datasets demonstrate the effectiveness of our method. RL-CSC (30 layers) outperforms several recent state-of-the-arts, e.g., DRRN (52 layers) and MemNet (80 layers) in both accuracy and visual qualities. Codes and more results are available at https://github.com/axzml/RL-CSC., Comment: 10 pages, 8 figures, 4 tables