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Transitioning to a sustainable energy future necessitates innovative storage solutions for renewable energies, where hydrogen (H₂) emerges as a pivotal energy carrier for its low emission potential. This paper explores unlined rock caverns (URCs) as a promising alternative for underground hydrogen storage (UHS), overcoming the geographical and technical limitations of UHS methods like salt rock caverns and porous media. Drawing from the experiences of natural gas (NG) and compressed air energy storage (CAES) in URCs, we explore the viability of URCs for storing hydrogen at gigawatt-hour scales (>100 GWh). Despite challenges such as potential uplift failures (at a depth of approximately less than 1000 m) and hydrogen reactivity with storage materials at typical conditions (below temperatures of 100°C and pressures of 15 MPa), URCs present a flexible, scalable option closely allied with green hydrogen production from renewable sources. Our comprehensive review identifies critical design considerations, including hydraulic containment and the integrity of fracture sealing materials under UHS conditions. Addressing identified knowledge gaps, particularly around the design of hydraulic containment systems and the interaction of hydrogen with cavern materials, will be crucial for advancing URC technology. The paper underscores the need for further experimental and numerical studies to refine URC suitability for hydrogen storage, highlighting the role of URCs in enhancing the compatibility of renewable energy sources with the grid. • Detailed exploration of unlined rock cavern (URC) technology. • Analysis of URCs' potential for large-scale hydrogen storage. • Insights from historical use of URCs in compressed gas storage. • Examination of the opportunities and challenges in using URCs for hydrogen storage. [ABSTRACT FROM AUTHOR]

This paper addresses the urgent need for efficient hydrogen storage methods in the context of combating climate change and transitioning to sustainable energy sources. Among various storage options, LiBH 4 is highlighted for its high volumetric and gravimetric energy densities, critical factors in determining its suitability for energy applications. However, challenges arise due to its high thermolysis temperature, which poses difficulties, especially in applications like automotive use where high temperatures are required. The commercial viability of LiBH 4 remains a significant obstacle due to the nascent stage of chemical hydride technology and the absence of large-scale production facilities. Environmental concerns also loom large, as the production of LiBH 4 relies on extensive mining of lithium and boron, known for their environmental impact. Furthermore, the economic feasibility of LiBH 4 as a hydrogen storage medium is questioned, given the substantial portion of total expenses attributed to hydrogen costs, affecting all methods except those based on fossil fuels or electricity. Nevertheless, there is optimism that with technological advancements and improved infrastructure, the costs associated with LiBH 4 and hydrogen storage overall may decrease over time. In conclusion, while LiBH 4 presents promising energy density characteristics, its practical implementation faces challenges such as high production costs, environmental concerns, and technological limitations. Overcoming these obstacles is crucial for realizing a sustainable and carbon-free energy landscape driven by hydrogen. • LiBH 4 shows promise for high energy density storage but faces obstacles high production costs and environmental concerns. • A comprehensive decision matrix analysis showcases the strengths and weaknesses of various hydrogen storage options. • LiBH 4 may find applications in small-scale personal storage due to its safety and energy density. [ABSTRACT FROM AUTHOR]

Hydrogen energy, characterized by its high calorific value and sustainability, represents a secondary clean energy source. It is predominantly stored, transported, and utilized through pipeline networks. However, a comprehensive optimization approach for the design for the ground pipeline network of hydrogen storage is currently lacking. This paper embarks on a systematic exploration of the layout, station type and parameter design for the ground pipeline network of hydrogen storage. Addressing various application perspectives, the study constructs two distinct pipeline network structures: the Star-Star Global Optimization Model (SSGO-Model) and the Star-Tree Global Optimization Model (STGO-Model). Three cases are discussed under six different constraint scenarios. These scenarios focus on layout optimization, variable capacity layout optimization, and the overall optimization of layout and parameters. An overall optimization strategy is proposed to solve the models. A detailed analysis of the iteration process, layout schemes, station and pipeline constraints, investment, and flow parameters of the pipeline network in the optimization results is presented. Through systematic analysis, the correctness and effectiveness of the model are verified, demonstrating the variability of optimization results under different topological structures and constraint conditions. Moreover, when conducting integrated optimization, the total investment is minimized, proving its superiority. The findings demonstrate the applicability of these models in guiding the construction for the ground pipeline network of hydrogen storage, thereby fostering the advancement of hydrogen storage technology. Concurrently, this research contributes significantly to the development of hydrogen energy, offering strategic insights and practical solutions for its efficient deployment. • Integrated optimization model for hydrogen storage ground pipeline network. • The model considers layout, station type and parameter design. • Overall optimization strategy is proposed. • Three cases verify optimization model. [ABSTRACT FROM AUTHOR]

To address the pressing need for sustainable energy solutions, hydrogen has emerged as a "zero-emission" energy source with vast potential in diverse sectors like manufacturing, transportation, and electricity generation. However, the realization of a hydrogen economy hinges on the development of safe and stable technologies and materials for hydrogen storage and transport. This paper presents a comprehensive review of the latest advancements in hydrogen storage systems, with a particular focus on porous materials. Notably, porous carbon materials derived from biomass waste have garnered attention due to their exceptional qualities. These include abundant and easily accessible raw materials, simplified production processes, adjustable characteristics, cost-effectiveness, low mass density, high specific surface area and porosity, structural diversity, and sustainable regeneration. These attributes position them as promising candidates for further exploration in hydrogen storage devices, particularly for achieving high H2 uptake capacities. The feasibility of utilizing both plant- and animal-based biomass porous carbons is examined, encompassing activated porous carbons, heteroatom doped porous carbons, and their composites, as pivotal components for the development of porous carbon storage devices. The synthesis and characterization of each form, along with their respective hydrogen storage capacities, are highlighted. While each material exhibits promise, it is important to note that they do present certain technological drawbacks. Addressing these limitations through further research and development is crucial to unlocking their full potential for future applications in the burgeoning hydrogen economy. [Display omitted] • Unique features of Biomass-derived carbon materials for hydrogen storage capacity. • Critical overview and key lessons from non-biomass derived materials. • Carbon materials from organic waste bridge hydrogen storage to the future economy. • Biomass-based carbon materials are signalling a need for further investigation. [ABSTRACT FROM AUTHOR]

In this paper, certain issues envisaged in the framework of development of design methodology for intelligent autonomous distributed hybrid power complexes (ADHPC) with green hydrogen and energy storage, functioning in grid mode and in the mode of interaction with the global (national) grid (GN) have been solved. Depending on their energy deficit or surplus, relative to the global grid, ADHPCs can operate as a load or as an energy source, respectively, as follows: based on the analysis of the energy balance management process in the ADHPC, a reasonable choice of the structure of the system of accumulation and distribution of power flows (SADCF) was made from the point of view of increasing the reliability of its functioning and ensuring the physical feasibility of the energy balance management process in this structure, i.e. keeping the actual power consumption of the consumers close to the required rated power at each given time t. This is achieved by including a condenser connected to the SADCF system on its assembly and distribution bus and a storage system BS with double-level ((BS1, BS2), double-circuit ((BS1(1), BS1(2)), (BS2(1), BS2(2))) structure, whereby: BS1of the level 1 - to manage the capacity balance in the SADCF under normal ADHPC regime and the variation of green hydrogen and consumption capacities within their confidence intervals assessed at the design stage; BS2 of the level 2 - to coordinate ADHPC and GN modes of operation and to control, together with BS1 of the level 1, GN, diesel generator (DG), the power balance in the SADCF when the ADHPC fails and when RES and consumption power are outside their confidence intervals; alternating charge/discharge operation of the parallel circuits will extend the life of the BS system; – a comprehensive definition of optimal ADHPC system situational energy balance management task is formulated. [ABSTRACT FROM AUTHOR]

This paper investigates an innovative study on the performance of a hybrid condensing boiler-fuel cell micro-cogeneration system for single residential applications. It combines experimental and dynamic numerical investigations including renewable energy for green hydrogen production and solid storage. Basing on the hourly measurements for a typical winter day, a dynamic model was developed and validated against different home heating need. Highlighting the influence home energy needs on fuel cell operating mode, it shows that single homes with low energy demand led to reduce the fuel cell's yearly operation below 50 %. In low-energy homes, a reduction in fuel cell size led to an increase in yearly operation to 60-70 % and achieved a 55 % electrical coverage rate. The integration of metal hydride hydrogen solid storage, powered by renewable sources, is emphasized. This setup increases heat demand, influencing fuel cell operation. In winter season, fuel cell operated for an average of 611 h, compared to 61 h in summer. System efficiency averaged 91 % annually, peaked at 95 % in summer, and sustained 93 % when both FC and condensing boiler were switched on. [Display omitted] • Modeling of a hybrid Boiler-Fuel Cell MCHP system for residential energy management. • Calibration of the FC-MCHP model using experimental data from a real MCHP unit. • Electrical and thermal coverage of the FC-MCHP unit with green hydrogen production and storage under different scenarios. • Strategies for optimal hydrogen consumption in in residential application. • Impact of solid-state hydrogen storage on FC-MCHP consumption and thermal management. [ABSTRACT FROM AUTHOR]

As a clean, efficient and sustainable energy carrier, hydrogen energy has been accepted as one of the main directions of future energy development. In this paper, a hydrogenation station providing compressed hydrogen outside was adopted as the research object. Based on finite element method and virtual nozzle model, the influence of leakage of main equipment in hydrogenation station on the distribution of combustible hydrogen was investigated, including hydrogen storage tank group, tube trailer, compressor chamber and hydrogenator. The results showed that the shape and volume of the combustible hydrogen cloud generated by the leak were influenced by obstacles, hydrogen storage pressure, and wind velocity. The disturbance of external wind and the decrease in hydrogen storage pressure will have a positive impact on the reduction of leaked volume. The diffusion of combustible hydrogen clouds can be exacerbated by complex structure of obstacles, while partition wall in the adopted hydrogenation station model can limit the combustible hydrogen cloud in the process area. These conclusions can provide guidance and reference for the risk prevention measures of hydrogenation station. [ABSTRACT FROM AUTHOR]

The majority of research in the carbon-based nanomaterials (CNMs) field has concentrated on the classification and synthesis of CNMs, with relatively few studies focusing on CNMs' roles in photocatalytic hydrogen production. CNMs have proven their potential as an effective addition to the appeal of photocatalytic hydrogen evolution because of their superior chemical and physical properties. This paper explores the recent advancements in photocatalytic hydrogen (H 2) production utilizing CNMs. As evidenced in the literature, carbon quantum dot (CQD)-sensitized titanium dioxide (TiO 2) can demonstrate to have a photocatalytic hydrogen generation activity of 472 mol g−1 h−1 and 1458 mol g−1 h−1 without and with loading metal co-catalyst (Pt). The optimum catalyst, 0.4 CQD/CdS, contributes to the highest H 2 production rate of 309 mmol g−1 h−1 (apparent quantum yield of 32.6%), which is 1.5 times greater than that of bare CdS. This would significantly accelerate the hydrogen production process. There are still challenges to reaching maximum photocatalytic hydrogen production, including low hydrogen storage. The overall price of hydrogen produced via photocatalysis is also higher because of the energy needed to store the hydrogen. Even though the problem is not directly related to the usage of CNMs, this restriction generates uncertainty and limits commercial investment. Given the rising demand for energy and the trend toward green power, it is recommended that extensive industrial uses of photocatalytic hydrogen produced by employing CNMs be investigated for better and more sustainable energy frameworks. • Recent advances in photocatalytic H 2 production are investigated utilizing CNMs. • The optimum catalyst, 0.4 CQD/CdS can produce the highest H 2 at 309 mmol g−1 h−1. • CQD-sensitized TiO 2 can generate 1458 mol g−1 h−1 photocatalytic hydrogen with Pt. • Photocatalytic H 2 production using CNMs should be investigated for industrial use. [ABSTRACT FROM AUTHOR]

This paper discusses the technical and economic feasibility of a renewable energy-based system, aimed to replace the traditional diesel engines implemented on a pushed and pusher bulk carrier barge. This barge has a challenging navigational route in the Nile River from Alexandria to Aswan and vice versa. It is scheduled to complete 30 trips annually while carrying 850 tons/trip. The system is based on photovoltaic panels, and was selected with its excess energy to be stored primarily in the form of H 2 gas through electrolysis, and batteries (i.e. Power to Gas technology) to be later converted back to electrical energy through fuel cells. Hence, an operation algorithm was formulated to optimize the performance of the system by defining operating modes that use solar energy, hydrogen energy, batteries, or hybrid energy coming from multiple sources that result in an internal rate of return (IRR) of 15.1% and overall efficiency of 57.9%. This high efficiency is due to the nature of water current that flows from south to north of Egypt, therefore, causing a significant reduction in power demand in the trip from Aswan to Alexandria that requires 11,980 kW h, compared to the trip from Alexandria to Aswan that requires 21,064 kW h. • Zero emission solution combining solar energy, hydrogen generation and fuel cell propulsion for a barge in Nile River. • Preparation to achieve the 7th goal of sustainable development ensuring green propulsion in Nile River cargo transport. • Efficient use of natural resources, solar energy and water current from south to north of Egypt. • Integrating electrolizer, fuel cell, solar energy pv, batteries, and hydrogen storage to form an autonomous barge. [ABSTRACT FROM AUTHOR]

In renewable-based microgrids, intermittency caused by some energy sources highlights the important role of energy storage systems. Nowadays, hydrogen and thermal energy storage are expected to play key roles in grid-scale applications, for facilitating effective penetration of clean energy sources. This paper, through a multilevel control framework for the energy management of a renewable and reversible solid oxide based microgrid, develops medium level controls accounting for the dynamic behaviour of storage systems. The storage systems considered are a hydrogen storage tank and a thermal energy storage based on phase change material technology. In particular, the proposed algorithm is helpful in the microgrid design phase as well as for clearly assessing high-level energy management strategies, since dynamic and transient behaviours of tanks during both charging and discharging phases are validated. In this way, top-level energy management strategies can be further refined and optimized in addition to a techno-economic design being pursued, primarily through shrinking the initial sizes of storages and thereby achieving significantly lower initial capital costs. For the analyzed microgrid, its feasibility is demonstrated by reducing by as much as 40% the size of the hydrogen tank and by up to 20% the energy capacity of the thermal storage. Finally, the proposed medium level control in a multilevel algorithm framework for a hydrogen-based microgrid is also seen to be fruitful for avoiding waste energy, which can be beneficial against the background of distributed energy systems acting in virtual power plants. • An rSOC-microgrid relying on renewables and innovative storages (i.e., HST and PCM-TES). • Multilevel control strategy checking storages resiliency in terms of energy satisfaction. • HST and TES sub-models considering transient phases for charging and discharging. • Scenario analyses aimed at optimizing both energy and economic aspects of energy storages. [ABSTRACT FROM AUTHOR]

This paper introduces a Techno-Economic Assessment (TEA) on present and future scenarios of different energy storage technologies comprising hydrogen and batteries: Battery Energy Storage System (BESS), Hydrogen Energy Storage System (H 2 ESS), and Hybrid Energy Storage System (HESS). These three configurations were assessed for different time horizons: 2019, 2022 and 2030, under both on-grid and off-grid conditions. For 2030, a sensitivity analysis under different energy scenarios was performed, covering other trends in on-grid electric consumption and prices, CO 2 taxation and the evolution of hydrogen technology prices from 2019 until 2030. The selected case study is the Research Park Zellik (RPZ), a CO 2 -neutral sustainable Local Energy Community (LEC) in Zellik, Belgium. The software HOMER (Hybrid Optimisation Model for Electric Renewable) has been selected to design, model and optimise the defined case study. The results showed that BESS was the most competitive when the electric grid was available among the three possible storage options. Additionally, HESS was overall more competitive than H 2 ESS-only, regardless of the grid connection mode. Finally, as per HESS, hydrogen was proved to play a complementary role when combined with batteries, enhancing the flexibility of the microgrid and enabling deeper decarbonisation by reducing the electricity bought from the grid, increasing renewable energy production and balancing toward an island operating mode. • Assessment of hybrid energy storage systems for future energy scenarios. • Sensitivity analysis with different technical, economic, and environmental KPIs. • Analysis of the effects of the connection and capacity access to the electric grid. • Application to a real case study: a CO2-neutral Local Energy Community. [ABSTRACT FROM AUTHOR]

The ability to withstand and recover from disruptions is essential for seaport energy systems, and in light of the growing push for decarbonization, incorporating clean energy sources has become increasingly imperative to ensure resilience. This paper proposes a resilience enhancement planning strategy for a seaport multi‐energy system that integrates various energy modalities and sources, including heating, cooling, hydrogen, solar, and wind power. The planning strategy aims to ensure the reliable operation of the system during contingency events, such as power outages, equipment failures, or extreme weather incidents. The proposed optimization model is designed as a mixed‐integer nonlinear programming formulation, in which McCormick inequalities and other linearization techniques are utilized to tackle the model nonlinearities. The model allocates fuel cell electric trucks (FCETs), renewable energy sources, hydrogen refueling stations, and remote control switches such that the system resilience is enhanced while incorporating natural‐gas‐powered combined cooling, heating, and power system to minimize the operation and unserved demand costs. The model considers various factors such as the availability of renewable energy sources, the demand for heating, cooling, electricity, and hydrogen, the operation of remote control switches to help system reconfiguration, the travel behaviour of FCETs, and the power output of FCETs via vehicle‐to‐grid interface. The numerical results demonstrate that the proposed strategy can significantly improve the resilience of the seaport multi‐energy system and reduce the risk of service disruptions during contingency scenarios. [ABSTRACT FROM AUTHOR]

The paper emphasizes the significance of sustainable energy solutions centered around electric vehicles (EVs). This involves Electric Intelligent Parking Lots (IPLs) that are interconnected with Renewable Energy Sources (RES) and Hydrogen Storage Systems (HSS) to achieve both technical and environmental goals. The study introduces a probabilistic approach to managing HSS-based energy in IPLs, employing the Probabilistic Two-Point Estimate Method (TPEM) to consider variables like sun radiation, temperature, wind speed, and IPL load. The Honey Badger Algorithm (HBA) is employed for optimization, striving to minimize operational costs related to energy distribution while maximizing profits by exploring revenue opportunities within the IPL system. This strategy enhances energy management and intelligent EV charging in IPLs, improving efficiency and economic viability. The approach is tested in a standard IPL environment integrated with RES and load demand, showcasing its successful technical and financial outcomes. Results reveal a 7.8 % profit increase from renewable resources and an additional 4.89 % when uncertainties are factored in. Ultimately, the proposed energy management framework utilizing HSS and RES integration proves effective in achieving objectives, with the potential for greater profitability through renewable resource incorporation and uncertainty consideration. • Optimal energy management framework proposed for electric vehicle integration in intelligent parking lots. • Simulation of efficient charging and discharging strategy in an IPL for electric vehicles. • Impact of renewable sources integration (wind and solar) on IPL efficiency and revenue generation. • Uncertainty analysis of renewable sources and load demands in IPL using two-point estimation method. • Smart integration of renewable sources, hydrogen storage, and electric vehicle charging for optimal operation of IPL. [ABSTRACT FROM AUTHOR]

Hydrogen, as a clean energy source, has been widely used in the automotive industry. However, considering the difficulties of hydrogen storage and transportation, the in-situ production process has received increasing attention. In this paper, a hydrogen production system for dimethyl ether self-heating steam reforming is proposed, using a spiral tube reactor in which the oxidation of dimethyl ether occurs in the spiral tube, and the exothermic oxidation of dimethyl ether is used to provide heat for the dimethyl ether steam reforming hydrogen production reaction. A numerical model of the hydrogen production system for dimethyl ether self-heating reforming is developed, the model is simulated and analyzed, the accuracy of the model is verified through experiments, the influence of various parameters and on the system is analyzed, and the system is optimized. The results show that the proposed system can solve the problems of high energy consumption, low hydrogen yield and difficult reaction control faced by traditional autothermal reforming hydrogen production, and the system can achieve 87.79% dimethyl ether conversion rate, 84.94% hydrogen yield and 85.94% system thermal efficiency. [Display omitted] • Designed a self-heating hydrogen production reaction system for dimethyl ether reforming. • Derive the numerical model and control equation inside the reactor. • Effect of oxygen-to-ether ratio on reforming hydrogen production system is studied. • Effect of steam-to-ether Ratio on reforming hydrogen production system is studied. • Effect of reaction temperature on reforming hydrogen production system is studied. [ABSTRACT FROM AUTHOR]

Seaports are responsible for consuming a large amount of energy and producing a sizeable amount of environmental emissions. However, optimal coordination and cooperation present an opportunity to transform this challenge into an opportunity by enabling flexibility in their generation and load units. This paper introduces a coordination framework for exploiting flexibility across multiple ports. The proposed method fosters cooperation between ports in achieving lower environmental emissions while leveraging flexibility to increase their revenue. This platform allows ports to participate in providing flexibility for the energy grid through the introduction of a green port-to-grid concept while optimising their cooperation. Furthermore, the proximity to offshore wind farms is considered an opportunity for the ports to investigate their role in harnessing green hydrogen. The proposed method explores the hydrogen storage capability of ports as an opportunity for increasing the techno-economic benefits, particularly through coupling them with offshore wind farms. Compared to existing literature, the proposed method enjoys a comprehensive logistics-electric model for the ports, a novel coordination framework for multi-port flexibility, and the potentials of hydrogen storage for the ports. These unique features position this paper a valuable reference for research and industry by demonstrating realistic cooperation among ports in the energy network. The simulation results confirm the effectiveness of the proposed port flexibility coordination from both environmental and economic perspectives. • A comprehensive logistics-electric model for optimising port operation. • A multi-port coordination framework for investigating port cooperation. • Integrating multi-port flexibility into the whole energy system. • Highlighting the potentials of harnessing hydrogen. • Introducing the green port to grid concept. [ABSTRACT FROM AUTHOR]

In light of the recent developments in the green hydrogen industry, it is essential to investigate its compatibility and integration with existing electrical grids. This task becomes more challenging when considering its implementation in off-grid sites that solely rely on renewable energy. In cases where off-grid sites should provide electricity and hydrogen to a variety of consumers, it is compulsory to have electrical and hydrogen storage devices with long-term storage capabilities. Consequently, a precise programming technique is necessary to manage the storage and consumption of hydrogen and electricity. To investigate such a model, this paper presents a connected electricity-hydrogen grid in which all the required energy is supplied by solar and hydroelectric units. This off-grid system supplies the necessary energy for industrial and residential loads, electric vehicle charging stations, fuelcell car refueling stations, and natural gas pipelines. The power-to-hydrogen (P2H) and hydrogen-to-power (H2P) systems are used to facilitate energy flow between the electrical and hydrogen sectors. A daily-seasonal hydrogen storage is integrated as well. The proposed method contributes by integrating and improving the modeling, management, optimization, and operation of the daily-seasonal hydrogen storage and electrical storage. Its primary objective is to supply electricity and hydrogen to various consumers using solely renewable energy, even in the face of renewable energy fluctuations and outages. The model is mathematically expressed as a mixed integer linear optimization, implemented in GAMS software, and solved by the CPLEX solver. It aims at maximizing profit from selling electricity and hydrogen to the users. Results demonstrate that P2H and H2P units have a complementary operation with the solar system. When there is abundant solar energy, the P2H converts excess clean energy to green hydrogen and H2P operates when solar energy is not available. Seasonal storage also stores hydrogen from spring to autumn and discharges it in winter because of higher hydrogen prices in this season. Such an operation increases the annual profit by about 9%. When the hydroelectricity unit faces an outage in hours 8 to 13, the fuelcell uses the stored hydrogen and comes into operation to compensate hydropower outage. The net present value of profit amounts to $275,179 per year. The total hydrogen required is approximately 49,870 kg per year, with a total electricity requirement of 1190 MWh per year. The levelized revenue from hydrogen is achieved at around $4 per kilogram, while the levelized revenue from electricity is about $0.058 per kilowatt-hour. It is concluded that the integration of seasonal storage effectively reduces costs, boosts profits, and efficiently manages renewable energy fluctuations across different seasons. • Standalone multi-carrier energy system including electricity-hydrogen-gas is developed. • Hybrid renewable generation comprising solar and hydroelectricity is integrated. • Power to hydrogen is manipulated for connection between electricity and hydrogen. • Hourly, daily, and seasonal hydrogen storage systems are modeled. • Electric vehicle charging station and fuel cell vehicle refueling station are integrated. [ABSTRACT FROM AUTHOR]

[Display omitted] • Hybrid-green ammonia partially uses green hydrogen by electrolysis as feedstock. • Feeding green hydrogen to the Haber process lowers the reforming load and emissions. • The retrofitting allows decarbonization degrees up to −20 % without operative issues. • Renewable grid (I) vs. on-site photovoltaics (II) electric supply options were assessed. • The most competitive configuration is Option I in the USA and Option II in the EU. This paper analyzes the retrofitting of a conventional, "gray" ammonia plant for its partial decarbonization. Specifically, the retrofitting involves the hybridization of the process by providing a certain amount of green hydrogen (i.e. by water electrolysis) for the ammonia synthesis to reduce the demand for the original gray hydrogen route (i.e. by fossil-based steam reforming) and consequently reduce CO 2 emissions. As such green hydrogen is produced through an electrolyzer that consumes renewable electric energy, two design configurations are considered: (Option I) the supply of clean electricity from renewable sources; (Option II) the generation of clean electricity by an in-house photovoltaic power plant. Once having analyzed the advantages and limitations of the hybrid plant layouts, the ammonia production costs achieved by the three simulated plants (i.e. the reference "gray" plant and the two hybrid alternatives) are estimated by considering the United States (USA) and European Union (EU) market quotations in 2022 and previsions for 2030 and 2050. The main outcomes are that (i) hybrid-green ammonia proves to be a feasible, environmentally friendly retrofitting option for the ammonia production industry, showing production costs that are no more than 36 % higher than gray ammonia; and (ii) Option I achieves better cost-effectiveness than Option II in the USA, while the opposite happens in the EU. Specifically, the resulting 10 %-green-on-average hybrid-green ammonia production costs range between +0.3 % (EU-2022) and +30.8 % (USA-2022) for Option I , and between −1.3 % (EU-2022) and +35.3 % (USA-2022) for Option II , compared to the reference gray ammonia plant. (iii) Lastly, the projected (i.e. in 2030 and 2050) CO 2 avoidance costs associated with hybrid-green ammonia configurations exceed 400 USD/t CO2 in the USA and 500 USD/t CO2 in the EU. [ABSTRACT FROM AUTHOR]