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• A novel metric (DOC) for bidirectional low temperature networks (BLTNs). • DOC describes the balancing potential of heating and cooling demands in a district. • DOC helps to identify building clusters with complementary demand profiles. • Correlations between DOC and KPIs are elaborated based on 63 demand scenarios. • Performance comparison of BLTNs with state-of-the-art building energy systems. Bidirectional low temperature networks (BLTNs) are a promising technology to drive decarbonization of the heating and cooling sector. The energy efficiency of a BLTN strongly depends on the heating and cooling demands of the connected buildings and their simultaneity. In order to evaluate the efficiency of a BLTN, a novel metric, called Demand Overlap Coefficient (DOC), is presented in this paper. The DOC can be calculated for individual buildings or a district and describes which proportion of heating and cooling demands can be balanced inside buildings and between buildings. The DOC is calculated with time series for heating and cooling demands, taking special account of their simultaneity. For a real-world use case in Germany, it is shown that 25% of heating and cooling demands can be balanced in buildings and 45% can be balanced by the BLTN between buildings. The DOC is evaluated for 63 demand scenarios. Correlations show that for districts with a DOC larger than 0.45, BLTNs have lower annualized costs than a state-of-the-art heating and cooling system. BLTNs have higher exergy efficiencies for districts with DOCs larger than 0.3. With the derived correlations, the DOC serves as a practical metric in the planning process of BLTNs in order to identify and assemble building clusters with complementary demand profiles. [ABSTRACT FROM AUTHOR]