1. Room-temperature synthesis of graphene quantum dots via electron-beam irradiation and their application in cell imaging.
- Author
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Wang, Liang, Li, Weitao, Wu, Bin, Li, Zhen, Pan, Dengyu, and Wu, Minghong
- Subjects
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HYDRAZINE derivatives , *ORGANIC compound derivatives , *CELL imaging , *GRAPHENE crystallography , *FLUORESCENCE microscopy - Abstract
We report a room-temperature strategy for the synthesis of single-crystalline fluorescent graphene quantum dots (GQDs) via electron-beam irradiation. The precursor contained high-activity nitro groups is easy to fusion GQDs with the method. Under optimized conditions (0.02 g 1,3,6-trinitropyrene, radiation dose of 400 kGy and 10 ml 0.5 mol/L hydrazine hydrate), the GQDs exhibit highly efficient fluorescence at 475 nm with a quantum yield of 32%. The PL maximum is well corresponded with the excitation wavelength. Moreover, the single-exponential fluorescence lifetime (4.86 ns) exhibited the intrinsic PL characteristic. The pH stability in neutral and alkaline solution, solid solubility and storage time stability of GQDs are satisfactory. Their application as a safety fluorescent probe for cell imaging is demonstrated. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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