Search

Substantial quantities of sediments are known to enter the deep lithosphere at subduction zones, but the extent to which sediments melt and the process involved in sediment contribution to the deep lithosphere are inadequately understood. Vigorous debate continues about whether the subducted sediment component is terrigenous or pelagic and transported as a hydrous melt, an aqueous fluid, or bulk sediment. In this contribution, we conduct an integrated study on a variety of deep-seated xenoliths in the Neogene Hannuoba basalts from the northern margin of the North China Craton. Among these xenoliths, clinopyroxenite xenoliths are compositionally and isotopically distinct. Mineral chemistry shows that the clinopyroxenite xenoliths come from a depth near the MOHO, rather than from the mantle as suggested previously. The clinopyroxenite xenoliths have extremely evolved Sr-Nd-Hf isotopic compositions and are interpreted to have a late Archean protolith age. The extremely low contents of Cr and Ni for the clinopyroxenite xenoliths preclude a magmatic origin. Instead, a metasomatic origin is suggested, which is strongly supported for the clinopyroxenites by the occurrence of hydrous minerals and high contents of large-ion-lithophile elements (K, Rb, Ba, Th and Sr) and light rare earth elements, as well as elevated δ18O (9.9–11.3‰) and light δ26Mg (−1.04‰ to −1.42‰) isotopic compositions. Furthermore, their high high-field-strength element (Nb, Ta, Zr and Hf) contents indicate that the metasomatic agent is a hydrous melt, rather than an aqueous fluid. The metasomatic melts are considered to be derived from a mixed source of sedimentary carbonates and ancient, felsic continental materials. A combination of zircon ages and oxygen isotope data for the clinopyroxenite xenoliths further restricts the timing of metasomatism to the late Paleozoic. Considering the regional tectonic setting, the sediments most likely came from the subducted Paleo-Asian oceanic slab. Thus the Hannuoba clinopyroxenite xenoliths provide direct evidence for melting of the subducted Paleo-Asian oceanic slab sediment and its interaction with the deep lithosphere. The data show that melting of subducted sediments can take place at a much shallower depth than commonly thought and place an independent constraint on future models of slab geotherms. [ABSTRACT FROM AUTHOR]

U–Pb zircon dating for 10 rock samples collected from the Archean Jiaobei terrain of the eastern block of the North China craton (NCC) yield three groups of ages: ∼2.9 Ga, ∼2.7 Ga and ∼2.5 Ga. Thirteen rock samples studied can be classified into a low Mg# (molecular Mg/(Mg + Fe)) (Mg# = 34–52) and a high Mg# group (Mg# = 52–61), respectively. The low Mg# rocks are typical Archean TTGs with emplacement ages of ∼2.9 Ga, ∼2.7 Ga and ∼2.5 Ga whereas the high Mg# rocks are Archean sanukitoids with age of ∼2.5 Ga. Despite having different ages, all the Jiaobei TTGs have zircon δ 18 O values between 5.6‰ and 6.3‰, essentially identical to those of the ∼2.7 Ga TTGs from adjourning Taishan area and Archean TTGs from other parts of the world. Magmatic zircons from the Jiaobei sanukitoids have δ 18 O values between 6.4‰ and 7.5‰, significantly higher than the Archean TTGs. The whole-rock Nd and the zircon Hf isotopic compositions indicate that the ∼2.9 Ga and ∼2.5 Ga TTGs and ∼2.5 Ga sanukitoids represent crustal growth at ∼2.9 Ga and ∼2.5 Ga in the Jiaobei terrain. Unlike the ∼2.7 Ga TTGs in the adjourning Taishan area that are considered to reflect juvenile crust, the Jiaobei ∼2.7 Ga TTGs, however, are most likely resulted from the reworking of the pre-existing ∼3.0 Ga crust. This is in contrast to the previous suggestion that ∼2.7 Ga is the most significant crust-forming episode and ∼2.5 Ga a period of crustal reworking in the Jiaobei terrain. The high Mg# and high contents of Cr, Ni, LREE and LILE of the ∼2.5 Ga Jiaobei sanukitoids, require a metasomatized peridotitic mantle source for their origin. The significant negative Zr and Hf anomalies and the elevated δ 18 O values of the ∼2.5 Ga sanukitoids, are inconsistent with a mantle source metasomatized solely by the TTG melts. Instead, we suggest that the Jiaobei sanukitoids could have originated from a mantle wedge metasomatized by a high δ 18 O component, most likely the slab-derived fluids. The similarity of multi-element patterns and the zircon δ 18 O values between the Jiaobei and Superior Province sanukitoids may imply similar processes involved to form sanukitoids in both Jiaobei and Superior Province terrains. [ABSTRACT FROM AUTHOR]

Paleogene potassium-rich volcanic rocks (PVRs) are widespread in the southeastern Tibetan Plateau, providing an opportunity to illustrate the architecture of the lithosphere and further constrain the development of the SE Plateau. Their petrogenesis, together with the geodynamic mechanism, remains in dispute. Mg isotopic compositions of the PVRs in western Yangtze Craton, along with new elemental and Sr-Nd-Pb isotopic data, are utilized to elucidate their petrogenesis and reveal the plausible metasomatic and genetic mechanisms. The PVRs give a compositional spectrum from basaltic trachyandesite to trachyte and are characterized by high large ion lithophile elements concentrations, negative anomalies in high field strength elements, and enriched Sr-Nd-Pb isotopes, suggesting an origin of enriched lithospheric mantle. The correlations among varying major oxides and fractional crystallization simulation results jointly reveal fractional crystallization of olivine and clinopyroxene in the magmatic process. The less-evolved PVRs present similar major oxide contents (e.g., Ti, Na, K) to those melts originated from carbonated peridotite + silicate sediment. Apart from enriched Sr-Nd-Pb isotopes, they also show high La/Yb ratios (11.73–58.95), low Ti/Ti* (0.08–0.71), Hf/Sm (mostly <0.70), and varying δ26Mg values (−0.13 to −0.36‰). Combined with the Sr-Nd-Mg isotope numerical simulations, it points out that the mantle source of the PVRs was replenished by a hybrid carbonate-silicic sediment, which was plausibly caused by the Neoproterozoic seafloor subduction. These volcanic rocks also present relatively high K 2 O (3.29–7.50 wt%) and K 2 O/Na 2 O ratios (1.00–2.85). Besides, varying elevated Rb/Sr and low Ba/Rb ratios, together with the La/Yb-Yb non-modal batch melting result, suggest that the enriched mantle source recorded by these PVRs is predominantly constituted by a hybrid phlogopite-bearing garnet-spinel lherzolite. Constrained by petrology studies and seismic tomography, the generation of the PVRs is proposed to be closely associated with the delamination of the thickened lithosphere and thereafter asthenosphere upwelling. • Paleogene K-rich volcanic rocks in the western Yangtze Craton are variably evolved. • These volcanic rocks are sourced from phlogopite-bearing garnet-spinel lherzolite. • Recorded mantle source was replenished by a hybrid carbonate-silicic sediment. [ABSTRACT FROM AUTHOR]

Cenozoic mantle-derived magmas are widespread on the Tibetan Plateau, and provide evidence for the evolution of deep mantle and its influence on the Plateau development. Miocene basalts in the Maguan area on the southeastern Plateau have high MgO (9.13–13.10 wt%) and Mg# (0.60–0.70) with high Ce/Pb (10.6–32.5) and Nb/U (43.7–52.9) ratios, similar to those of oceanic basalts. Distinct from Eocene-Oligocene mantle-derived potassic magmas in Western Yunnan and Cenozoic basic volcanic rocks in Tengchong, these Maguan basalts are characterized by high large ion lithophile elements (LILEs) concentrations, positive anomaly in high field strength elements (HFSEs) and depleted Sr Nd isotopes, consistent with the melt of an asthenospheric mantle origin. The high Ce/Pb and Nb/Y (1.80–2.68) ratios together with low Ba/Y and Ba/Th ratios indicate a significant input of slab-derived melt into the asthenospheric source. Besides, Hf/Hf* and Ti/Ti* ratios are significantly lower than those of ocean island basalt (OIB), which are proportional to the lighter δ26Mg (-0.6‰ to -0.4‰) values. Based on the results of experimental petrology, the Sr Mg isotope mixing model suggests that the asthenospheric mantle beneath the Maguan area had undergone the significant metasomatism of recycled carbonates prior to the late Miocene. The above petrological and geochemical understanding, together with the geophysical data, allows us to propose that the mantle metasomatism is most probably associated with the Neo-Tethys seafloor subduction, which is further testified by the decoupling between depleted Sr Nd isotopes and elevated LILE concentrations. • Miocene basalt in Maguan area, SW China was evolved without crustal contamination • The Maguan basalt is derived from metasomatized asthenospheric mantle • The mantle metasomatism was predominantly caused by deep recycled carbonates. [ABSTRACT FROM AUTHOR]

The lithospheric mantle should be depleted in base- and precious-metals as these elements are transferred to the crust during partial melting. However, some melt-depleted mantle peridotites are enriched in these ore-forming elements. This may reflect re-fertilization of the mantle lithosphere and/or sequestering of these elements by residual mantle phase(s). Both processes remain poorly understood because of the low abundances of incompatible elements in peridotite and the nugget-like distribution of digestion-resistant mantle phases that pose analytical challenges for conventional geochemical methods. Herein we report new major and trace element concentrations for a suite of mantle peridotite and pyroxenite samples from the Late Permian to Middle Triassic Nahlin ophiolite (Cache Creek terrane, British Columbia, Canada) using Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICPMS) analysis of nanoparticulate powders and olivine. Compatible to moderately incompatible element concentrations suggest that Nahlin ophiolite peridotites represent residues after ≥20% melt extraction. Pyroxenite dykes and replacive dunite bands are folded and closely intercalated with residual harzburgite. These field relationships, coupled with the presence of intergranular base metal sulphide, clinopyroxene and Cr-spinel at the microscale, point to percolating melts that variably re-fertilized melt-depleted mantle peridotite. Radiogenic Pb (206Pb/204Pb = 15.402–19.050; 207Pb/204Pb = 15.127–15.633; 208Pb/204Pb = 34.980–38.434; n = 45) and Os (187Os/188Os 0.1143–0.5745; n = 58) isotope compositions for a subset of melt-depleted peridotite samples further support metasomatic re-fertilization of these elements. Other ore-forming elements are also implicated in these metasomatic reactions because some melt-depleted peridotite samples are enriched relative to the primitive mantle, opposite to their expected behaviour during partial melting. New LA-ICPMS analysis of fresh olivine further demonstrates that a significant proportion of the highly incompatible element budget for the most melt-depleted rocks is either hosted by, and/or occurs as trapped inclusions within, the olivine-rich residues. Trapped phases from past melting and/or re-fertilization events are the preferred explanation for unradiogenic Pb isotope compositions and Paleozoic to Paleoproterozoic Re-depletion model ages, which predate the Nahlin ophiolite by over one billion years. [ABSTRACT FROM AUTHOR]