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Arsenic (As) and antimony (Sb) are toxic metalloids widely distributed in coastal sediments, but are seldom studied for their geochemical baselines. In this study, sediment samples were collected from Jiaozhou Bay (JZB) to evaluate their baselines, contamination, and ecological risk. Results showed that the As and Sb concentrations were between 3.15 and 11.94 mg/kg and 0.20–0.61 mg/kg, respectively. Sc and Fe showed good performance in developing geochemical baseline functions for the metalloids. Organic matter content and clay had significant positive correlations with metalloid abundance in sediments (p < 0.01). In the JZB, As and Sb were not enriched in the sediments, with the enrichment factors below 1. Furthermore, the contamination degrees of As and Sb were low in the JZB. In addition, the ecological risks of As and Sb were relatively low in the JZB, with the risk index between 4.02 and 12.70 and 1.68–5.09, respectively. • Geochemical baseline functions of As and Sb were developed in a semi-enclosed bay. • Organic matter and clay were significantly relevant with metalloids in sediments. • As and Sb were not enriched in the sediments of the JZB. • The contamination degrees and risk levels of As and Sb were low in the JZB. [ABSTRACT FROM AUTHOR]

Potentially toxic element (PTE) contamination is a common environmental issue in offshore regions worldwide. Water and sediment samples were collected from the Yellow River downstream and adjacent Laizhou Bay to investigate the residues, sources, and ecological risks of 11 typical PTEs (As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Sc, V, and Zn). The results indicated that the concentrations of PTEs in the sediments decreased from the Yellow River Estuary to the inner Laizhou Bay under the long-term effect of the Yellow River input. Principal component analysis (PCA) identified three potential sources: natural origins, coastal anthropogenic activities (e.g., oil exploration and steel refining), and marine production (e.g., marine aquaculture and transportation). Among the PTEs, Cd was the most significant contaminant, with a contamination factor (CF) of 2.06 ± 0.78. Furthermore, Cd was the most sensitive factor used in evaluating the overall ecological risk using Monte Carlo analysis, with a contribution of up to 96%. Although the overall contamination and risk levels were low in the bay, a higher pollution load index (PLI) and risk index (RI) adjacent to the Yellow River Estuary indicated that the Yellow River remained the primary contributor to the PTEs contamination in the bay. [Display omitted] ● The Yellow River has contributed greatly to PTE accumulation in the Laizhou Bay. ● The sources of PTEs are natural origins, human activities, and marine production. ● A Monte Carlo–Hakanson model was developed to assess the ecological risk of PTEs. ● As a significant contaminant, Cd was the most sensitive factor in risk assessment. ● Generally, the pollution level and ecological risk of PTEs are low in the bay. [ABSTRACT FROM AUTHOR]

• Concentration of arsenic in multiple medium decreased from estuaries to bay. • Sedimentary particles were more capable of absorbing arsenic than suspended particulate sediment (SPS). • Effects of coastal environmental factors on arsenic allocation in different phases were evaluated. • Spatial patterns of arsenic in the bay and enrichment factors demonstrated its source and distribution. Under the gradients of salinity and redox, the transportation and distribution of dissolved, particulate, and sedimentary arsenic present differences from estuary to bay. Samples of water, suspended particulate sediment (SPS), and sediment from the Jiaozhou Bay were analyzed. The concentrations of arsenic decreased significantly from the estuaries toward the bay. The sedimentary arsenic mostly existed as hydrous oxide-bound and residual fractions and tended to be attached to smaller particles. Sedimentary particles were more capable of absorbing arsenic than SPS and the capacity increased from the estuaries toward the bay. The spatial distribution of arsenic was impacted by the residual currents, resulting in higher contents of dissolved arsenic in the eastern coastal zone and higher concentrations of sedimentary arsenic in the inner bay. In water, total phosphorus (TP), dissolved organic carbon (DOC), and alkalinity had significant positive correlations with the dissolved arsenic. In sediments, Fe oxides and sediment organic matter (SOM) would promote adsorption of arsenic. The significant correlation between non-residual fractions and enrichment factors of arsenic indicated that the sedimentary arsenic was more likely to originate from anthropogenic sources, mainly impacted by riverine transport from the eastern urban regions and agricultural production in the western farmland. [ABSTRACT FROM AUTHOR]