1. Design and synthesis of broadband absorption covalent organic framework for efficient artificial photocatalytic amine coupling.
- Author
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Fang, Yuanding, Liu, Youxing, Huang, Haojie, Sun, Jianzhe, Hong, Jiaxing, Zhang, Fan, Wei, Xiaofang, Gao, Wenqiang, Shao, Mingchao, Guo, Yunlong, Tang, Qingxin, and Liu, Yunqi
- Subjects
SOLAR spectra ,THIOPHENES ,ABSORPTION ,PHOTOCATALYSTS ,IMINE derivatives ,ELECTROPHILES - Abstract
Developing highly active materials that efficiently utilize solar spectra is crucial for photocatalysis, but still remains a challenge. Here, we report a new donor-acceptor (D-A) covalent organic framework (COF) with a wide absorption range from 200 nm to 900 nm (ultraviolet-visible-near infrared light). We find that the thiophene functional group is accurately introduced into the electron acceptor units of TpDPP-Py (TpDPP: 5,5'-(2,5-bis(2-ethylhexyl)−3,6-dioxo-2,3,5,6-tetrahydropyrrolo [3,4-c]pyrrole-1,4-diyl)bis(thiophene-2-carbaldehyde), Py: 1,3,6,8-tetrakis(4-aminophenyl)pyrene) COFs not only significantly extends its spectral absorption capacity but also endows them with two-photon and three-photon absorption effects, greatly enhancing the utilization rate of sunlight. The selective coupling of benzylamine as the target reactant is used to assess the photocatalytic activity of TpDPP-Py COFs, showing high photocatalytic conversion of 99% and selectivity of 98% in 20 min. Additionally, the TpDPP-Py COFs also exhibit the universality of photocatalytic selective coupling of other imine derivatives with ~100% conversion efficiency. Overall, this work brings a significant strategy for developing COFs with a wide absorption range to enhance photocatalytic activity. Creating highly active materials that effectively harness solar spectra is essential for photocatalysis, though challenging. Here the authors introduce a novel donor-acceptor covalent organic framework with a broad absorption range of 200 nm to 900 nm, achieving efficient artificial photocatalytic amine coupling. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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