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This paper studies Chinese grape growers' time discounting and its implications for the adoption of technology that can reduce the negative effects of increasing precipitation. Using primary data collected in Xinjiang Province, we undertook a contingent valuation of rain covers that protect fruit from rain and estimated a discounted utility model using these data. Using a hierarchical Bayesian approach, we find that local grape growers discount the future very heavily, with a discount rate of 0.17 per year, which is almost four times higher than the Chinese market interest rate. Farmers also tend to underestimate the benefits of adopting covers, with their purchase decisions appearing to largely depend on their past actual losses rather than future anticipated losses. These findings have broader implications for policies promoting proactive adaptation in response to likely increased rainfall in the region. Targeting farmers who give lower weight to events far off in the future and understanding that many farmers may tend only to make adoption decisions that have strong short‐term benefits could improve the efficacy of climate policies that target agricultural technologies. [ABSTRACT FROM AUTHOR]

The development of environmentally friendly full‐inorganic luminescent materials with tunable emission properties and exceptional thermal stability is of paramount importance for applications in optoelectronic devices, solid‐state lighting, and anti‐counterfeiting technologies. In this study, a novel luminescent crystal based on calcium perovskites Cs2CaCl4·2H2O (CCCH) are explored using a hydrothermal method. Simultaneous co‐doping of CCCH with Sn2+ and Mn2+ yields the s‐p transition‐induced cyan light from Sn2+ and d‐d transition‐induced yellow light from Mn2+. It demonstrates effective energy transfer from self‐trapped exciton (STE) of matrix CCCH and s‐p transition of Sn2+ to Mn2+, synergizing composite white lights with tunable colors. Furthermore, the incorporation of Sn2+ into CCCH introduces a red shift from blue to cyan emission with a remarkable enhancement in luminescent intensity by a factor of 12 times. The crystal orbital Hamiltonian populations (─COHP) calculations revealed the crucial role of Mn2+ in lattice stability, as evidenced by the decomposition temperature exceeding 305 °C for CCCH:Sn2+,Mn2+ whereas 210 °C for undoped CCCH matrix. This research provides a comprehensive investigation of the luminescent properties of CCCH:Sn2+,Mn2+ crystal, holding significant promise for practical technological advancements in lighting and anti‐counterfeiting technologies. [ABSTRACT FROM AUTHOR]

Porous metal foams (e.g., Ni/Cu/Ti) are applied as catalyst supports extensively for water splitting due to their large specific area and excellent conductivity, however, intrinsic bubble congestion is unavoidable because of the irregular three‐dimensional (3D) networks, resulting in high polarization and degraded electrocatalytic performances. To boost the H2O decomposition kinetics, the immediate bubble removal and water supply sequential in the gas–liquid–solid interface is essential. Inspired by the high efficiency of water/nutrient transport in the capillaries plants, this work designs a graphene‐based capillary array with side holes as catalyst support to manage the bubble release and water supply via a Z‐axis controllable digital light processing (DLP) 3D printing technology. Like planting rice, a low‐cost, high‐active CoNi carbonate hydroxide (CoNiCH) is planted on support. A homemade cell can reach 10 mA cm−2 in 1.51 V, and be kept at 30 mA cm−2 for 60 h without noticeable degradation, surpassing most of the known cells. This research provides a promising avenue to design and prepare advanced catalysts in various fields, including energy applications, pollutant treatment, and chemical synthesis. [ABSTRACT FROM AUTHOR]

Combined photoelectron spectroscopic experiments and computational studies have been performed on Al3Hn− (n=1–9) clusters. Three modes of hydrogen bonding to the Al3 moiety have been observed: terminal, bridging, and capping. Among various hydrides, Al3H5− and Al3H8− clusters have highest HOMO‐LUMO gap and largest electron affinity, respectively. Our studies indicate that as the number of hydrogen atoms increase the presence of AlH2 groups, representing the tetrahedral coordination of the Al atom, which in turn led to the stoichiometric ring structure. [ABSTRACT FROM AUTHOR]

Zeolites with molecular dimension pores are widely used in petrochemical and fine-chemical industries. While traditional solvothermal syntheses suffer from environmental, safety, and efficiency issues, the newly developed solvent-free synthesis is limited by zeolite crystal aggregation. Herein, we report well-dispersed and faceted silicalite ZSM-5 zeolite crystals obtained using a solvent-free synthesis facilitated by graphene oxide (GO). The selective interactions between the GO sheets and different facets, which are confirmed by molecular dynamics simulations, result in oriented growth of the ZSM-5 crystals along the c-axis. More importantly, the incorporation of GO sheets into the ZSM-5 crystals leads to the formation of mesopores. Consequently, the faceted ZSM-5 crystals exhibit hierarchical pore structures. This synthetic method is superior to conventional approaches because of the features of the ZSM-5 zeolite. [ABSTRACT FROM AUTHOR]

Zeolites with molecular dimension pores are widely used in petrochemical and fine-chemical industries. While traditional solvothermal syntheses suffer from environmental, safety, and efficiency issues, the newly developed solvent-free synthesis is limited by zeolite crystal aggregation. Herein, we report well-dispersed and faceted silicalite ZSM-5 zeolite crystals obtained using a solvent-free synthesis facilitated by graphene oxide (GO). The selective interactions between the GO sheets and different facets, which are confirmed by molecular dynamics simulations, result in oriented growth of the ZSM-5 crystals along the c-axis. More importantly, the incorporation of GO sheets into the ZSM-5 crystals leads to the formation of mesopores. Consequently, the faceted ZSM-5 crystals exhibit hierarchical pore structures. This synthetic method is superior to conventional approaches because of the features of the ZSM-5 zeolite. [ABSTRACT FROM AUTHOR]