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Ships are considered important contributors to air pollution and have seriously health impact globally. Although many researchers have carried out studies on emission factors (EFs) in recent years, studies covering various types of ships are rare and the chemical characteristics of particulate matter (PM) emitted by them are unclear. Due to the diversity of different national fleets, the current emission inventory in China established by citing foreign EFs will lead to inaccurate calculation results and generate large uncertainty. In this study, the EFs for ocean-going, harbour, offshore and inland vessels were measured by the portable emission measurement system (PEMS). The specific compositions of PM were analyzed, including carbonaceous components, water-soluble ions (WSI), elements, and polycyclic aromatic hydrocarbons (PAHs). Combined with localized EFs, the ship emission inventory of Qingdao Port was established based on Automatic Identification System (AIS) data. The results show nitrogen oxide (NOx) is the primary pollutant discharged by all ships, followed by sulfur dioxide (SO 2). The emissions of SO 2 and PM from inland and offshore vessels fueled with high sulfur fuel (HSF) are significantly higher than other ships. Carbonaceous components accounted for 43.4%–53.9% of the total mass of PM, WSI accounted for 9.8%–14.3%, and elements accounted for 16.5%–28.6%. Although the use of low sulfur fuel (LSF) has reduced the emission of V and Ni from ships, it could still be treated as tracer elements of ship emissions. The annual emissions of SO 2 , NO X , PM 2.5 , THC and CO from ships in Qingdao port in 2020 were 9728.5, 38503.9, 1424.9, 1331.5 and 2440.4 tons, respectively. The ship emission inventory established based on EPA-recommended EFs resulted in underestimating approximately 16.8% of ship pollutants, especially for SO 2 and PM. Ocean-going ships and offshore vessels are major emitters in the study waters. This study is hoped to provide a valuable reference for the further regulation and policy formulation of ship emissions in China. [Display omitted] • On-board measurements were carried out on typical ships by PEMS. • EFs for gas pollutants and particle components of various vessel types are provided. • Fuel types have a significant impact on the particulate fraction of ships. • It reveals the current emissions from Chinese ships may be underestimated. • Approximately 16.8% of ship emissions in Qingdao Port are undervalued in 2020. [ABSTRACT FROM AUTHOR]