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Amorphous Al 2 O 3 coating was prepared on Ni-based single crystal superalloy via atomic layer deposition (ALD) for high temperature oxidation protection. The oxygen inward transport and outward-cation diffusion were hindered by amorphous Al 2 O 3 coating, and the coated alloy showed high oxidation resistance. The low oxygen partial pressure at the alloy/coating interface altered the alloy oxidation behavior, allowing the priority oxidation of protective Al and Cr elements. The oxidation process was controlled by the growth of Cr 2 O 3 and Al 2 O 3. The coating exhibited high spallation resistance. Degradation of the coating, the formation of NiAl 2 O 4 phase in amorphous Al 2 O 3 layer, was observed. • Amorphous Al 2 O 3 coating was proposed and prepared on Ni-based single crystal superalloy. • The amorphous Al 2 O 3 coating improved oxidation resistance and exhibited high adhesion. • The amorphous Al 2 O 3 coating altered the oxidation behavior of the alloy. • The effect mechanism of amorphous Al 2 O 3 coating on the alloy oxidation was discussed. [ABSTRACT FROM AUTHOR]

The oxidation behavior of a fourth-generation nickel-based single crystal superalloy with different heat treatments were studied at 1100 °C in air. The specimens were divided into three groups, one as-cast group, and two heat-treated groups: solution treated and fully heat treated. The elemental distribution is mainly affected by the solution temperature, the higher the solution temperature, the more uniform the distribution of elements. Heat treatment can effectively reduce the difference in oxidation behavior between dendritic region and interdendritic region. However, due to the inability to form a continuous Al 2 O 3 layer, the oxidation resistance of heat-treated specimens degrades. • The elements distribution will affect the oxidation behavior of superalloys. • The Al content of the region will affect the morphology of the internal Al 2 O 3 layer. • Heat treatment can reduce the oxidation difference between dendritic region and interdendritic region. • After heat treatment, the alloy is more prone to large-scale oxide spalling. [ABSTRACT FROM AUTHOR]