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In this work, a novel fluoroaluminate red phosphor of Cs2NaAl3F12:Mn4+ with excellent color purity was fabricated via the introduction of Mn4+ in the octahedral center. The crystal and electronic structures, luminescence properties and optical performances were characterized and investigated in detail. The evidences showed that Cs2NaAl3F12:Mn4+ well-crystallized into a single phase with particulate morphology, and the non-equivalent occupation in Cs2NaAl3F12 resulted in sharp red emissions with improved color purity upon blue light illumination. For solid-state lighting, the optical parameters consisted of the "blue-yellow-red" contributions significantly improved to a high color-rendering index of 88.7 and a low color temperature of 3856 K, indicating the potential use of Cs2NaAl3F12:Mn4+ for warm white light-emitting diode applications. [ABSTRACT FROM AUTHOR]

In this work, we present a novel single-phase red phosphor of Cs 2 NaAlF 6 :Mn4+ with two Al3+ lattice sites, which shows two groups of vibrational phonon sidebands and ultra-intense zero phonon line (ZPL) under blue light illumination. The evidences have shown that the interesting spectral features originate from the non-equivalent occupation of Mn4+ for both Al3+ sites, which induces the neighboring cation vacancies surrounding Mn4+ and highly distorted [MnF 6 octahedral in the Cs 2 NaAlF 6 host. The luminescent behavior of double sites occupied by Mn4+ can absorb researchers' interest on novel red-emitting phosphors. Profiting from the photoluminescence (PL) features, superior color rendering index of R a = 90.3, R 9 = 81, and low correlated color temperature of T c = 3967 K are achieved from white light-emitting diode (LED) by using yellow Y 3 Al 5 O 12 :Ce3+ (YAG) and red Cs 2 NaAlF 6 :Mn4+ phosphors as blue light converters. These results suggest that Cs 2 NaAlF 6 :Mn4+ for phosphor has a stupendous potential for LED lighting. A novel red phosphor of Cs 2 NaAlF 6 :Mn4+ with unprecedented spectral features of double vibrational phonon sidebands and ultra-intense ZPL comparable to the sharpest v 6 peak under blue light excitation was obtained. The amazing spectral feature is originated from the non-equivalent occupation of Mn4+ for both Al3+ sites in CNAF host. Profiting from the extraordinary PL properties, excellent optical performance of CNAF:Mn as color converter is achieved, implying its potential application in white LED lighting or display devices. Image 1 • A novel red-emitting phosphor of Cs 2 NaAlF 6 :Mn4+ has been successfully synthesized. • The crystal structure of Cs 2 NaAlF 6 :Mn4+ has been confirmed. • The spectral feature with ultra-intense zero phonon line has been elucidated. • Double sites occupancy of Mn4+ in Cs 2 NaAlF 6 has been verified. [ABSTRACT FROM AUTHOR]

Searching for efficient Mn4+ red phosphors for white lighting and display backlighting has drawn great attention. In this work, an efficient Mn4+-doped fluoroscandate, Rb 2 KScF 6 :Mn4+, with short fluorescence lifetime is prepared via a facile co-precipitation method. It was found that the nonequivalent occupation of Mn4+ for Sc3+ leads to the identifications of sharp red emissions, enhanced zero-phonon line, high quantum efficiency and short fluorescence lifetime upon blue light excitation. Thanks to the luminescent properties, good optical parameters of high color rendering index, low correlated color temperature, and acceptable color gamut were achieved by coating the red Rb 2 KScF 6 :Mn4+ phosphor with yellow Y 3 Al 5 O 12 :Ce3+ or green β -SiAlON:Eu2+ phosphor in various white light-emitting diodes, demonstrating its potential role for white light illumination and backlight display applications. • The crystal and electronic structures were analyzed for a novel Rb 2 KScF 6 :Mn4+ phosphor. • The luminescent properties including an enhanced zero-phonon line and a short fluorescence lifetime were confirmed. • The optical behavior of the Rb 2 KScF 6 :Mn4+ phosphor in multiple white light-emitting diodes was elucidated. [ABSTRACT FROM AUTHOR]

A reddish-orange-emitting cationic iridium(III) complex [(dfppy) 2 Ir(EPTC)]PF 6 (dfppy: 2-(2,4-difluorophenyl)pyridine, EPTC: 9-ethyl-3-(3-(pyridin-2-yl)-1,2,4-triazin-5-yl)-9 H -carbazole) containing a carbazole-triazine bipolar unit was synthesized. The thermal decomposition temperature (T d) of the complex was 355 °C, its relative emission intensity at 100 °C was 78.6% of that at 20 °C, which was enough for it to be used in LEDs. Mainly due to the bipolar unit, [(dfppy) 2 Ir(EPTC)]PF 6 can efficiently absorb and be excited by blue light (λ em,max = 457 nm) of GaN chips. Excited by blue-emitting GaN chips, the complex can be used for fabricating reddish-orange LEDs, moreover, together with yellow-emitting Y 3 Al 5 O 12 :Ce3+ (YAG:Ce), neutral and warm white light-emitting diodes (WLEDs) can be obtained with good performances. When [(dfppy) 2 Ir(EPTC)]PF 6 was blended in silicone at 1.0, 1.5 and 2.0 wt% respectively, all together with YAG:Ce at 4.0 wt%, three efficient neutral WLEDs were obtained. Their correlate color temperatures (CCT) were 4874 K, 4312 K and 3665 K, color rendering indexes (CRI) were 80.2, 78.3 and 76.4, luminous efficiencies (η L) were 88.5 lm·W−1, 83.6 lm·W−1 and 67.4 lm·W−1, Commission International de I'Eclairage (CIE) values were (0.34, 0.32), (0.36, 0.33) and (0.38, 0.33) respectively. When blending concentration of [(dfppy) 2 Ir(EPTC)]PF 6 was increased to 2.5 wt% together with YAG:Ce still at 4.0 wt%, a warm WLED was obtained, its CCT was 3282, CRI was 73.9, η L was 63.0 lm·W−1, and CIE value was (0.40, 0.35). Image 1 • A reddish-orange-emitting cationic iridium(III) complex containing a carbazole-triazine bipolar unit.. • The complex can be efficiently excited by blue-emitting GaN chips mainly due to the effect of the bipolar unit. • Together with Y 3 Al 5 O 12 :Ce3+ as phosphors, neutral and warm white light-emitting diodes can be obtained with good performances. [ABSTRACT FROM AUTHOR]