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This paper describes numerous siderite occurrences from Nb-Zr-REY-Ga-enriched beds of tuffaceous mudstone from the Yujingshan borehole, eastern Yunnan, southwestern China. The mineral phases in the samples were identified and characterized through macroscopic observation, XRD (X-ray diffraction) analysis, optical microscopy, and FE-SEM (field emission-scanning electron microscopy). The results show that the siderite occurs in the drill core from depths of 664.07 to 729.21 m, where its content varies from 15.1 to 65.7%, 31.3% on average. Modes of occurrence of authigenic siderite include irregular banded or massive aggregates, discrete fine particles, oolitic aggregates, and double or multi-ring ellipsoid-shaped or rhombohedral aggregates. The mineralogical association with quartz, anatase, ilmenite, chromite, and zircon with sharp-edged outlines, high-temperature cracks and/or corroded embayments, and REE-bearing minerals and geochemical characteristics such as Al 2 O 3 /TiO 2 between 3 and 8, less commonly 8–23.77, indicate that abundant siderite was produced by hydrothermal alteration of airborne volcaniclastic materials. The δ 13C PDB , δ 18O PDB , and δ 18O SMOW values of siderite in the argillized tuff range from −12.56 to −1.32‰, −8.98 to −5.88‰, and 21.60 to 24.80‰, respectively. In the δ 13C PDB - δ 18O SMOW diagram, plots of the studied siderite are distributed between the fields of marine carbonate rocks, sedimentary organic matter, and carbonates of hydrothermal ores. Some siderite from the upper part of the studied borehole is isotopically close to REY carbonates from the Abramovka lignite deposit, Far Eastern Russia, which precipitated from evolved basinal waters mixed with CO 2 from a mantle source. In summary, this indicates a hybrid origin for the studied siderite including carbonate dissolution, dehydroxylation of sedimentary organic matter, and hydrothermal activity. Furthermore, the paleosalinity (Z) and paleotemperature (T) of the ore-forming fluids were calculated based on the age-corrected stable carbon and oxygen isotopic data in the samples. The Z values range from 96.65 to 121.5‰, suggesting the formation of siderite under brackish-water conditions. The T values vary from 19.47 to 47.12 °C, with some sharp fluctuations that may be due to ash falls and/or hydrothermal injections. Overall, our data support the model for critical-metal Nb(Ta)-Zr(Hf)-REY-Ga enrichment in tuffaceous deposits of southwest China including a combination of volcanic activity and terrestrial organic-rich sedimentation under warm and humid conditions, followed by low-temperature alteration evolved from acidic leaching, which is responsible for the Nb-Zr-REY-Ga enrichment, and, subsequently, formation of authigenic siderite with associated quartz, sulfide minerals, and phosphate minerals under reducing neutral/weakly alkaline conditions. • Abundant siderite is documented in the clay-altered tuffaceous horizons. • Fe was primarily derived from airborne pyroclastics. • C and O were sourced from carbonate, organic matter, and hydrotherm. • C-O isotopes show that siderite was affected by seawater and hot fluids. • A genetic model of siderite in Nb-Zr-REY-Ga deposits has been proposed. [ABSTRACT FROM AUTHOR]

Integration of calcareous nannofossil data, δC and δO values, and carbonate contents of the lower Paleocene-upper Paleocene sequence that crops out at the Misheiti section, East Central Sinai, Egypt, were used to denote the Danian/Selandian (D/S) and Selandian/Thanetian (S/T) stage boundaries. The study interval belongs to the Dakhla and Tarawan formations. Four calcareous nannofossil zones (NP4, NP5, NP6, and NP7/8) were recognized. The base of the Selandian Stage is tentatively placed at the lowest occurrences (LOs) of taxa ascribable to the second radiation of fasciculiths (i.e., Lithoptychius janii). This level is marked by a sudden drop of δC and δO values and carbonate content. No distinctive lithological changes were observed across the D/S boundary at the study section. A hiatus at the NP5/NP6 zonal boundary is indicated by the condensation of zones NP5 and NP6. The base of the Thanetian is placed at the base of Zone NP7/8 at the lithological change observed in correspondence to the boundary between the Dakhla and Tarawan formations . The δC and δO values abruptly decrease slightly above the base of Zone NP7/8. No consistent variations in the carbonate contents were recorded within Zone NP6 or across the NP6/NP7/8 zonal boundary. [ABSTRACT FROM AUTHOR]

The Lower Triassic Kangan Formation, which is equivalent to the Upper Khuff, is the main reservoir for natural gas in SW Iran and the northern Persian Gulf. Investigations of this formation in Salman Field indicate that it is composed of 14 facies deposited in tidal flat, lagoon and oolitic barrier settings in the inner part of a carbonate ramp. Vertical variations of microfacies and gamma-ray log profiles show that this formation consists of three depositional sequences (KG3-KG1), each including of transgressive and high stand systems tract and each bounded above and below by type-two unconformities. Carbon and oxygen stable isotope profiles from a well-dated carbonate section were compared with the sedimentological data and results from the sequence stratigraphic study of the Kangan Formation, showing negative and positive peaks coinciding with sequence boundaries and maximum flooding surfaces Boundaries and Maximum Flooding Surfaces, respectively. [ABSTRACT FROM AUTHOR]