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The idea of exploiting the inexhaustible solar energy-driven photocatalytic hydrogen evolution reaction (HER) to generate hydrogen energy, a sustainable clean energy source, to solve problems such as fossil fuel-induced greenhouse gas emissions is believed to be a feasible strategy. However, photocatalytic HER is inefficient due to insufficient light trapping capability and low charge separation efficiency of the single semiconductor material employed. Therefore, it remains a great challenge to achieve fast and efficient photocatalytic HER. In this work, a novel ternary Chl@Cu2O/Ti3C2Tx photocatalyst with an organic–inorganic heterojunction structure has been designed by employing a stepwise deposition process for efficient solar energy conversion to hydrogen. The results showed that the photocatalytic activity of Chl@Cu2O/Ti3C2Tx organic–inorganic heterojunction photocatalysts for HER was significantly improved compared with that of single Chl@Ti3C2Tx and Cu2O/Ti3C2Tx. The improvement of the photocatalytic performance of Chl@Cu2O/Ti3C2Tx compared to Chl@Ti3C2Tx and Cu2O/Ti3C2Tx is attributed to the construction of the Chl–Cu2O organic–inorganic heterojunction structure in Chl@Cu2O/Ti3C2Tx, which extends the absorption range of the spectra and dramatically enhances the separation efficiency of the photogenerated carriers in Chl@Cu2O/Ti3C2Tx composites. [ABSTRACT FROM AUTHOR]

The idea of exploiting the inexhaustible solar energy-driven photocatalytic hydrogen evolution reaction (HER) to generate hydrogen energy, a sustainable clean energy source, to solve problems such as fossil fuel-induced greenhouse gas emissions is believed to be a feasible strategy. However, photocatalytic HER is inefficient due to insufficient light trapping capability and low charge separation efficiency of the single semiconductor material employed. Therefore, it remains a great challenge to achieve fast and efficient photocatalytic HER. In this work, a novel ternary Chl@Cu2O/Ti3C2Tx photocatalyst with an organic–inorganic heterojunction structure has been designed by employing a stepwise deposition process for efficient solar energy conversion to hydrogen. The results showed that the photocatalytic activity of Chl@Cu2O/Ti3C2Tx organic–inorganic heterojunction photocatalysts for HER was significantly improved compared with that of single Chl@Ti3C2Tx and Cu2O/Ti3C2Tx. The improvement of the photocatalytic performance of Chl@Cu2O/Ti3C2Tx compared to Chl@Ti3C2Tx and Cu2O/Ti3C2Tx is attributed to the construction of the Chl–Cu2O organic–inorganic heterojunction structure in Chl@Cu2O/Ti3C2Tx, which extends the absorption range of the spectra and dramatically enhances the separation efficiency of the photogenerated carriers in Chl@Cu2O/Ti3C2Tx composites. [ABSTRACT FROM AUTHOR]

Hydrogen energy is an abundant, clean, sustainable and environmentally friendly renewable energy source. Therefore, the production of hydrogen by photocatalytically splitting water on semiconductors has been considered in recent years as a promising and sustainable strategy for converting solar energy into chemical energy to replace conventional energy sources and to solve the growing problem of environmental pollution and the global energy crisis. However, highly efficient solar-driven photocatalytic hydrogen production remains a huge challenge due to the poor visible light response of available photocatalytic materials and the low efficiency of separation and transfer of photogenerated electron-hole pairs. In the present work, organic heterojunction structures based on bacteriochlorophyll (BChl) and chlorophyll (Chl) molecules were introduced and used for solar-driven photocatalytic hydrogen production from water under visible light. Also, noble metal-free photocatalyst was successfully constructed on Ti 3 C 2 T x nanosheets by simple successive deposition of Chl and BChl, which was used for the photocatalytic splitting water to hydrogen evolution reaction (HER). The results show that the optimal BChl@Chl@Ti 3 C 2 T x composite has a high HER performance with 114 μmol/h/g cat , which is much higher than the BChl@Ti 3 C 2 T x and Chl@Ti 3 C 2 T x composites., (© 2022 Wiley-VCH GmbH.)